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Journal of Materials Engineering and Performance

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31.05.2022 | Technical Article

Investigation of Microstructural, Mechanical, Wear, and Corrosion Properties of Mg-Sb-La Alloys

verfasst von: Selma Özarslan

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 12/2022

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Abstract

The microstructural, mechanical, corrosion properties, and wear behaviors of as-cast Mg-Sb-based alloys with various La contents (0, 1, 2, and 4 wt.%) were investigated. The microstructural properties were analyzed by x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The tensile and microhardness tests were carried out to examine the mechanical properties. Corrosion properties were investigated in 3.5 wt.% NaCl using both electrochemical and immersion tests. Wear tests were carried out at three different loads of 10, 20 and 40 N and at three different sliding speeds of 0.3, 0.6 and 1.2 m/s. The results showed that the Mg-Sb alloy had α-Mg and Mg₃Sb₂ phases, and La₄Sb, LaSb and Mg₁₇La₂ phases were formed by the addition of La. The yield strength and hardness continuously increased along with the increasing La content, while tensile strength and ductility first increased and then decreased by the addition of 2 wt.% La. It was observed that the corrosion resistance improved by the addition of 1 wt.% La, and the addition of more La worsened the corrosion resistance, and the best wear rate was obtained by the addition of 1 wt.% La.

Vorheriger Artikel Corrosion Behaviors of S355 Steel under Simulated Tropical Marine Atmosphere Conditions

Nächster Artikel Optimization of Fused Deposition Modeling Process Parameters and Dynamic Mechanical Analysis of 3D Printed Polycarbonate/Acrylonitrile-Butadiene-Styrene Composite Loaded with Tetrabromobiphenol-A and Microcrystalline Cellulose

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W. Liu, B. Zhou, G. Wu, L. Zhang, X. Peng, and L. Cao, High Temperature Mechanical Behavior of Low-Pressure Sand-Cast Mg‐Gd‐Y‐Zr Magnesium Alloy, J. Magnes. Alloys, 2019, 7(4), p 597–604. https://doi.org/10.1016/j.jma.2019.07.006CrossRef

B.L. Mordike and T. Ebert, Magnesium: Properties—Applications—Potential, Mater. Sci. Eng. A, 2001, 302(1), p 37–45. https://doi.org/10.1016/S0921-5093(00)01351-4CrossRef

W. Hu, Q. Le, Z. Zhang, L. Bao, and J. Cui, Numerical Simulation of DC Casting of AZ31 Magnesium Slab at Different Casting Speeds, J. Magnes. Alloys, 2013, 1(1), p 88–93. https://doi.org/10.1016/j.jma.2013.02.010CrossRef

D. Mehra, M.M. Mahapatra, and S.P. Harsha, Processing of RZ5-10wt% TiC In-Situ Magnesium Matrix Composite, J. Magnes. Alloys, 2018, 6(1), p 100–105. https://doi.org/10.1016/j.jma.2018.01.002CrossRef

W. Liu, B. Zhou, G. Wu, L. Zhang, X. Peng, and L. Cao, High Temperature Mechanical Behavior of Low-Pressure Sand-Cast Mg-Gd-Y-Zr Magnesium Alloy, J. Magnes. Alloys, 2019, 7(4), p 597–604. https://doi.org/10.1016/j.jma.2019.07.006CrossRef

A. Baghani, H. Khalilpour, and S.M. MIRESMAEILI, Microstructural Evolution and Creep Properties of Mg-4sn Alloys by Addition of Calcium Up to 4 wt.%, Trans. Nonferrous Met. Soc. China, 2020, 30(4), p 896–904. https://doi.org/10.1016/S1003-6326(20)65263-3CrossRef

W. Liu, L. Jiang, L. Cao, J. Mei, G. Wu, S. Zhang, L. Xiao, S. Wang, and W. Ding, Fatigue Behavior and Plane-Strain Fracture Toughness of Sand-Cast Mg‐10Gd‐3Y‐0.5 Zr Magnesium Alloy, Mater. Des., 2014, 59, p 466–474. https://doi.org/10.1016/S1003-6326(20)65263-3CrossRef

W.L. Cheng, Q.W. Tian, H. Yu, H. Zhang, and B.S. You, Strengthening Mechanisms of Indirect-Extruded Mg‐Sn Based Alloys at Room Temperature, J. Magnes. Alloys, 2014, 2(4), p 299–304. https://doi.org/10.1016/j.jma.2014.11.003CrossRef

M. Yang, F. Pan, R. Cheng, and A. Tang, Effect of Mg‐10sr Master Alloy on Grain Refinement of AZ31 Magnesium Alloy, Mater. Sci. Eng., A, 2008, 491(1–2), p 440–445. https://doi.org/10.1016/j.msea.2008.02.017CrossRef

10.

X.P. Lin, Y. Kuo, L. Wang, J. Ye, C. Zhang, W. Li, and K.Y. Guo, Refinement and Strengthening Mechanism of Mg‐Zn‐Cu‐Zr‐Ca Alloy Solidified Under Extremely High Pressure, Trans. Nonferrous Met. Soc. China, 2021, 31(6), p 1587–1598. https://doi.org/10.1016/S1003-6326(21)65600-5CrossRef

11.

J.A. Yasi, L.G. Hector Jr., and D.R. Trinkle, First-Principles Data for Solid-Solution Strengthening of Magnesium: from Geometry and Chemistry to Properties, Acta Mater., 2010, 58(17), p 5704–5713. https://doi.org/10.1016/j.actamat.2010.06.045CrossRef

12.

H. Liu, Y. Chen, Y. Tang, S. Wei, and G. Niu, The Microstructure, Tensile Properties, and Creep Behavior of As-Cast Mg‐(1–10)% Sn Alloys, J. Alloys Compd., 2007, 440(1–2), p 122–126. https://doi.org/10.1016/j.jallcom.2006.09.024CrossRef

13.

H. Fu, J. Guo, W. Wu, B. Liu, and Q. Peng, High Pressure Aging Synthesis of a Hexagonal Mg₂Sn Strengthening Precipitate in Mg‐Sn Alloys, Mater. Lett., 2015, 157, p 172–175. https://doi.org/10.1016/j.matlet.2015.05.087CrossRef

14.

N. Stanford, J.R. TerBush, M. Setty, and M.R. Barnett, Grain Refinement of an Extruded Mg Alloy Via Na Microalloying, Metall. Mater. Trans. A, 2013, 44(6), p 2466–2469. https://doi.org/10.1007/s11661-013-1712-0CrossRef

15.

H.S. Brar, J. Wong, and M.V. Manuel, Investigation of the Mechanical and Degradation Properties of Mg‐Sr and Mg‐Zn‐Sr Alloys for Use as Potential Biodegradable Implant Materials, J. Mech. Behav. Biomed. Mater., 2012, 7, p 87–95. https://doi.org/10.1016/j.jmbbm.2011.07.018CrossRef

16.

S. Gavras, S.M. Zhu, J.F. Nie, M.A. Gibson, and M.A. Easton, On the Microstructural Factors Affecting Creep Resistance of Die-Cast Mg‐La-Rare Earth (Nd, Y or Gd) Alloys, Mater. Sci. Eng. A, 2016, 675, p 65–75. https://doi.org/10.1016/j.msea.2016.08.046CrossRef

17.

M. Paliwal and I.H. Jung, Thermodynamic Modeling of the Mg‐Bi and Mg‐Sb Binary Systems and Short-Range-Ordering Behavior of the Liquid Solutions, Calphad, 2009, 33(4), p 744–754. https://doi.org/10.1016/j.calphad.2009.10.002CrossRef

18.

R. Rajeshkumar, J. Jayaraj, A. Srinivasan, and U.T.S. Pillai, Investigation on the Microstructure, Mechanical Properties and Corrosion Behavior of Mg-Sb and Mg-Sb-Si Alloys, J. Alloys Compd., 2017, 691, p 81–88. https://doi.org/10.1016/j.jallcom.2016.08.219CrossRef

19.

F. Gao, S.L. Wang, C.P. Wang, and X.J. Liu, Thermodynamic Assessments of the Sb‐La and Sb‐Tb Systems, Calphad, 2012, 37, p 158–162. https://doi.org/10.1016/j.calphad.2012.01.002CrossRef

20.

R. Alizadeh and R. Mahmudi, Effect of Sb Additions on the Microstructural Stability and Mechanical Properties of Cast Mg‐4Zn Alloy, Mater. Sci. Eng. A, 2010, 527(20), p 5312–5317. https://doi.org/10.1016/j.msea.2010.05.029CrossRef

21.

G. Nayyeri, R. Mahmudi, and F. Salehi, The Microstructure, Creep Resistance, and High-Temperature Mechanical Properties of Mg-5Sn Alloy With Ca and Sb Additions, and Aging Treatment, Mater. Sci. Eng. A, 2010, 527(21–22), p 5353–5359. https://doi.org/10.1016/j.msea.2010.05.040CrossRef

22.

P. Kumar, A.K. Mondal, S.G. Chowdhury, G. Krishna, and A.K. Ray, Influence of Additions of Sb and/or Sr on Microstructure and Tensile Creep Behaviour of Squeeze-Cast AZ91D Mg Alloy, Mater. Sci. Eng. A, 2017, 683, p 37–45. https://doi.org/10.1016/j.msea.2016.12.006CrossRef

23.

G. Nayyeri and R. Mahmudi, Effects of Sb Additions on the Microstructure and Impression Creep Behavior of a Cast Mg‐5Sn Alloy, Mater. Sci. Eng. A, 2010, 527(3), p 669–678. https://doi.org/10.1016/j.msea.2009.08.056CrossRef

24.

T.B. Massalski, La–Sb (Lanthanum–Antimony), Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski Ed., ASM International, Materials Park, OH, 1990

25.

R. Vogel and H. Klose, Über die Zustandsbilder Cer-Lanthan, Lanthan-Antimon und Cer-Indium, Z. Metallkd., 1954, 45, p 633–638.

26.

M.N. Abdusalyamova, Phase Diagrams and Thermodynamic Properties of Rare Earth-Antimony Systems, J. Alloys Compd., 1993, 202(1–2), p L15–L20. https://doi.org/10.1016/0925-8388(93)90504-GCrossRef

27.

A.A. Nayeb-Hashemi and J.B. Clark, The Mg‐Sb (Magnesium-Antimony) System, Bull. Alloys Phase Diagrams, 1984, 5(6), p 579–584. https://doi.org/10.1007/s11669-010-9784-7CrossRef

28.

S. Virtanen, Biodegradable Mg and Mg alloys: corrosion and Biocompatibility, Mater. Sci. Eng. B, 2011, 176(20), p 1600–1608. https://doi.org/10.1016/j.mseb.2011.05.028CrossRef

29.

R. Uzwalkiran, S. Bontha, M.R. Ramesh, V.K. Balla, A. Srinivasan, and S.V. Kailas, Tailoring Surface Characteristics of Bioabsorbable Mg-Zn-Dy Alloy Using Friction stir Processing for Improved Wettability and Degradation Behavior, J. Market. Res.Technol., 2021 https://doi.org/10.1016/j.jmrt.2021.03.057CrossRef

30.

A. Yamamoto and S. Hiromoto, Effect of Inorganic Salts, Amino Acids and Proteins on the Degradation of Pure Magnesium in Vitro, Mater. Sci. Eng. C, 2009, 29(5), p 1559–1568. https://doi.org/10.1016/j.msec.2008.12.015CrossRef

31.

A. Bahmani, S. Arthanari, and K.S. Shin, Formulation of Corrosion Rate of Magnesium Alloys Using Microstructural Parameters, J. Magnes. Alloys, 2020, 8(1), p 134–149. https://doi.org/10.1016/j.jma.2019.12.001CrossRef

32.

G.R. Argade, S.K. Panigrahi, and R.S. Mishra, Effects of Grain Size on the Corrosion Resistance of Wrought Magnesium Alloys Containing Neodymium, Corros. Sci., 2012, 58, p 145–151. https://doi.org/10.1016/j.corsci.2012.01.021CrossRef

33.

E.V. Parfenov, O.B. Kulyasova, V.R. Mukaeva, B. Mingo, R.G. Farrakhov, Y.V. Cherneikina, A. Yerokhin, Y.F. Zheng, and R.Z. Valiev, Influence of Ultra-Fine Grain Structure on Corrosion Behaviour of Biodegradable Mg-1Ca Alloy, Corros. Sci., 2020, 163, 108303. https://doi.org/10.1016/j.corsci.2019.108303CrossRef

34.

S. Özarslan, H. Şevik, and İ Sorar, Microstructure Mechanical and Corrosion Properties of Novel Mg-Sn-Ce Alloys Produced by High Pressure Die Casting, Mater. Sci. Eng. C, 2019, 105, p 110064. https://doi.org/10.1016/j.msec.2019.110064CrossRef

35.

A.D. Südholz, N. Birbilis, C.J. Bettles, and M.A. Gibson, Corrosion Behaviour of Mg-Alloy AZ91E With Atypical Alloying Additions, J. Alloys Compd., 2009, 471(1–2), p 109–115. https://doi.org/10.1016/j.jallcom.2008.03.128CrossRef

36.

R. Jia, S. Yu, D. Li, T. Zhang, F. Wang, and C. Zhong, Study on the Effect of Mischmetal (La, Ce) on the Micro-Galvanic Corrosion of AZ91 Alloy Using Multiscale Methods, J. Alloys Compd., 2019, 778, p 427–438. https://doi.org/10.1016/j.jallcom.2018.11.030CrossRef

37.

A. Prasad, J. Jain, and N.N. Gosvami, Effect of Minor La Addition on Wear Behavior of Mg-10Dy Alloy, Wear, 2021, 486, 204121. https://doi.org/10.1016/j.wear.2021.204121CrossRef

38.

M.S. Chen, W.Q. Yuan, H.B. Li, and Z.H. Zou, New Insights on the Relationship Between Flow Stress Softening and Dynamic Recrystallization Behavior of Magnesium Alloy AZ31B, Mater. Charact., 2019, 147, p 173–183. https://doi.org/10.1016/j.matchar.2018.10.031CrossRef

39.

J. Dai, X. Zhang, Q. Yin, S. Ni, Z. Ba, and Z. Wang, Friction and Wear Behaviors of Biodegradable Mg-6Gd-0.5 Zn-0.4 Zr Alloy Under Simulated Body Fluid Condition, J. Magnes. Alloys, 2017, 5(4), p 448–453. https://doi.org/10.1016/j.jma.2017.11.002CrossRef

40.

A.J. López, P. Rodrigo, B. Torres, and J. Rams, Dry Sliding Wear Behaviour of ZE41A Magnesium Alloy, Wear, 2011, 271(11–12), p 2836–2844. https://doi.org/10.1016/j.wear.2011.05.043CrossRef

41.

J. Zhang, X. Zhang, Q. Liu, S. Yang, and Z. Wang, Effects of Load on Dry Sliding Wear Behavior of Mg‐Gd‐Zn‐Zr Alloys, J. Mater. Sci. Technol., 2017, 33(7), p 645–651. https://doi.org/10.1016/j.jmst.2016.11.014CrossRef

42.

X. Zhang, J. Dai, J. Zhang, and Y. Bai, Quantitative Evaluation of the Interaction Between Wear and Corrosion on Mg-3Gd-1Zn Alloy in Simulated Body Fluid, J. Mater. Eng. Perform., 2019, 28(1), p 355–362. https://doi.org/10.1007/s11665-018-3770-3CrossRef

43.

H. Chen and A.T. Alpas, Sliding Wear Map for the Magnesium Alloy Mg-9Al-0.9 Zn (AZ91), Wear, 2000, 246(1–2), p 106–116. https://doi.org/10.1016/S0043-1648(00)00495-6CrossRef

44.

C. Zheng, X. Wu, X. Zheng, H. Jin, and Y. Liu, Mechanical Properties and Wear Behavior of a Dissolvable Magnesium Alloy Used for Multistage Fracturing, Wear, 2021, 466, p 203559. https://doi.org/10.1016/j.wear.2020.203559CrossRef

45.

S. Banerjee, S. Poria, G. Sutradhar, and P. Sahoo, Dry Sliding Tribological Behavior of AZ31-WC Nano-Composites, J. Magnes. Alloys, 2019, 7(2), p 315–327. https://doi.org/10.1016/j.jma.2018.11.005CrossRef

46.

T. Thirugnanasambandham, J. Chandradass, and T.T.M. Kannan, Influence of load and Sliding Speed on Wear Behavior of AZ91E Magnesium Alloy Nanocomposite by Dry Sliding, Mater. Today Proceedings, 2021, 45, p 6553–6557. https://doi.org/10.1016/j.matpr.2020.11.459CrossRef

47.

B.M. Girish, B.M. Satish, S. Sarapure, D.R. Somashekar, and Basawaraj, Wear Behavior of Magnesium Alloy AZ91 Hybrid Composite Materials, Tribol. Trans., 2015, 58(3), p 481–489. https://doi.org/10.1080/10402004.2014.987858CrossRef

Titel: Investigation of Microstructural, Mechanical, Wear, and Corrosion Properties of Mg-Sb-La Alloys
verfasst von: Selma Özarslan
Publikationsdatum: 31.05.2022
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 12/2022
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-022-07037-3

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