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Tribology Letters

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01.06.2022 | Original Paper

Ionic Liquids Based on Chromotropic Acid: Excellent Lubricating Additives for Aqueous System

verfasst von: Peng Wang, Peng Gao, Lin Ma, Ping Wen, Yunyan Han, Rui Dong, Mingjin Fan

Erschienen in: Tribology Letters | Ausgabe 2/2022

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Abstract

In this paper, four ionic liquids based on chromotropate (CAILs) were prepared and applied to heighten the tribological performance of aqueous system on different metal friction contacts. Taking for the potential choice for water-based lubricating additive, CAILs exhibited excellent water solubility and corrosion resistance. Tribological results showed that the CAILs, especially the phenolic hydroxyl group decorated samples (TsnN₄₄₄₄ and TsnP₄₄₄₄), demonstrating extremely effective lubricating properties with the efficient friction and wear descent (69% and 83% for Fe, 47% and 94% for Cu, 74% and 69% for Al, respectively). Especially, the excellent load-carrying capacity was also presented with the highest P_B (833 N) and P_D (1568 N) values for TsnP₄₄₄₄. It is speculated that the CAIL molecular adsorption on the interface and further generation of tribochemical films are beneficial for their lubricating effects, resulting from the systematic discussion and analysis of CA, QCM, SEM, XPS, and FIB-TEM tests. However, TsN₄₄₄₄ and TsP₄₄₄₄ showed less effective lubricating performances and poor load-carrying capacities due to tribocorrosion of hydroxyl groups at the interface.

Graphical Abstract

Vorheriger Artikel Influences of Boundary Slip Coating on Elastohydrodynamically Lubricated Contacts

Nächster Artikel Non-monotonic Dynamics in the Onset of Frictional Slip

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Titel: Ionic Liquids Based on Chromotropic Acid: Excellent Lubricating Additives for Aqueous System
verfasst von: Peng Wang
Peng Gao
Lin Ma
Ping Wen
Yunyan Han
Rui Dong
Mingjin Fan
Publikationsdatum: 01.06.2022
Verlag: Springer US
Erschienen in: Tribology Letters / Ausgabe 2/2022
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI: https://doi.org/10.1007/s11249-022-01585-4

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