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Erschienen in: Polymer Bulletin 2/2012

01.01.2012 | Original Paper

Poly(N-hydroxymethyl acrylamide-co-acrylic acid) and poly(N-hydroxymethyl acrylamide-co-acrylamidoglycolic acid): synthesis, characterization, and metal ion removal properties

verfasst von: Bernabé L. Rivas, Iván M. Perič, Carla Muñoz, Renêe Alvear

Erschienen in: Polymer Bulletin | Ausgabe 2/2012

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Abstract

Macroreticular chelating resins containing carboxylic groups, poly(N-hydroxymethyl acrylamide-co-acrylic acid) P(HMA-co-AA) and poly(N-hydroxymethyl acrylamide-co-2-acrylamido glycolic acid) P(HMA-co-AGA) were synthesized by solution radical polymerization with ammonium persulfate as initiator and N,N′-methylene-bis-acrylamide as cross-linking reagent. The polymerization yield was 98.9 and 91.9% for P(HMA-co-AA) and P(HMA-co-AGA), respectively. The retention properties were studied under competitive and noncompetitive conditions by batch equilibrium procedure for the following metal ions: Cd(II), Cr(III), Zn(II), Pb(II), and Hg(II). The effects of pH, time, temperature, and initial ion concentration on adsorption were investigated. The resins showed a significant ability to retain Pb(II), greater than 79%, at pH 5.

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Metadaten
Titel
Poly(N-hydroxymethyl acrylamide-co-acrylic acid) and poly(N-hydroxymethyl acrylamide-co-acrylamidoglycolic acid): synthesis, characterization, and metal ion removal properties
verfasst von
Bernabé L. Rivas
Iván M. Perič
Carla Muñoz
Renêe Alvear
Publikationsdatum
01.01.2012
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 2/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0551-7

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