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Cellulose

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01.08.2013 | Original Paper

Preparation of cellulose I nanowhiskers with a mildly acidic aqueous ionic liquid: reaction efficiency and whiskers attributes

verfasst von: Jia Mao, Anayancy Osorio-Madrazo, Marie-Pierre Laborie

Erschienen in: Cellulose | Ausgabe 4/2013

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Abstract

Cellulose I nanowhiskers were prepared in relatively high yield (48 ± 2 %) by single-stage hydrolysis of microcrystalline cellulose with an aqueous solution of 1-butyl-3-methylimidazolium hydrogen sulfate ([Bmim]HSO₄). This reaction occurred under mildly acidic reaction conditions with an [H⁺]/[AGU] ratio of 0.24 mol/mol, i.e., 2 orders of magnitude lower than with concentrated sulfuric acid. The nanowhiskers exhibited small width and width distribution and also smaller length than nanowhiskers obtained with concentrated acid. With a relatively low content of sulfur they also exhibited higher thermal stability than whiskers obtained with concentrated sulfuric acid. The lower solvating power of the aqueous ionic liquid compared to that of concentrated sulfuric acid likely contributes to the greater hydrolysis efficiency in the present system.

Vorheriger Artikel In situ polymerization and characterization of elastomeric polyurethane-cellulose nanocrystal nanocomposites. Cell response evaluation

Nächster Artikel Preparation of nanoscale cellulose materials with different morphologies by mechanical treatments and their characterization

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Titel: Preparation of cellulose I nanowhiskers with a mildly acidic aqueous ionic liquid: reaction efficiency and whiskers attributes
verfasst von: Jia Mao
Anayancy Osorio-Madrazo
Marie-Pierre Laborie
Publikationsdatum: 01.08.2013
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-013-9942-2

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