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19.03.2016 | Original Paper

A comparative guide to controlled hydrophobization of cellulose nanocrystals via surface esterification

verfasst von: Shane X. Peng, Huibin Chang, Satish Kumar, Robert J. Moon, Jeffrey P. Youngblood

Erschienen in: Cellulose | Ausgabe 3/2016

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Abstract

Surface esterification methods of cellulose nanocrystals (CNC) using acid anhydrides, acid chlorides, acid catalyzed carboxylic acids, and 1′1-carbonyldiimidazole (CDI) activated carboxylic acids were evaluated with acetyl-, hexanoyl-, dodecanoyl-, oleoyl-, and methacryloyl-functionalization. Their grafting efficiency was investigated using Fourier-transform infrared spectroscopy and ¹³C solid state NMR spectroscopy. Acid anhydride and CDI were found to be the most applicable reagents to graft short and long chain aliphatic carbons, respectively. The preservation of structural morphology and crystallinity of grafted CNCs were confirmed using transmission electron microscopy and X-ray diffraction. The hydrophobicity of grafted CNCs was evaluated by dispersing them in organic solvents with different Hansen’s solubility parameters. The dispersibility of grafted CNCs in organic solvents was improved by using never-dried CNCs as source materials and keep CNCs wet in their washing solvents after grafting, thus increasing the solvency range to disperse CNCs.

Vorheriger Artikel Combining steam explosion with 1-ethyl-3-methylimidazlium acetate treatment of wood yields lignin-coated cellulose nanocrystals of high aspect ratio

Nächster Artikel UV-ozone patterning of micro-nano fibrillated cellulose (MNFC) with alkylsilane self-assembled monolayers

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Titel: A comparative guide to controlled hydrophobization of cellulose nanocrystals via surface esterification
verfasst von: Shane X. Peng
Huibin Chang
Satish Kumar
Robert J. Moon
Jeffrey P. Youngblood
Publikationsdatum: 19.03.2016
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-016-0912-3

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