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Cellulose

Erschienen in:

28.03.2016 | Original Paper

Chemically peeling layers of cellulose nanocrystals by periodate and chlorite oxidation

verfasst von: Kevin Conley, M. A. Whitehead, Theo G. M. van de Ven

Erschienen in: Cellulose | Ausgabe 3/2016

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Abstract

Layers of cellulose nanocrystals are peeled off by controlled periodate and chlorite oxidation to produce nanocrystals with a tunable width. The chemical modification increases the solubility of the polymers at the crystal surface to the extent that they preferentially exist in solution and detach from the crystal. The number of layers removed is controlled by the degree of partial oxidation. The reaction occurs on the crystal surface and at the crystal ends, resulting in crystals which are both shorter and thinner, likely with dangling chains at each end. The crystallinity index is reduced with each layer removed.

Vorheriger Artikel Theoretical modeling of water vapor transport in cellulose-based materials

Nächster Artikel Assessment of endoglucanase activity by analyzing the degree of cellulose polymerization and high-throughput analysis by near-infrared spectroscopy

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Titel: Chemically peeling layers of cellulose nanocrystals by periodate and chlorite oxidation
verfasst von: Kevin Conley
M. A. Whitehead
Theo G. M. van de Ven
Publikationsdatum: 28.03.2016
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-016-0922-1

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