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Erschienen in: Cellulose 4/2016

25.05.2016 | Original Paper

Fire retardant viscose fiber fabric produced by graft polymerization of phosphorus and nitrogen-containing monomer

verfasst von: Li-Huan Wang, Yuan-Lin Ren, Xiu-Li Wang, Jie-Yun Zhao, Yue Zhang, Qian Zeng, Ye-Tong Gu

Erschienen in: Cellulose | Ausgabe 4/2016

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Abstract

A kind of viscose fiber fabric with permanent flame retardancy has been prepared by grafting polymerization of phosphorus and nitrogen-containing monomer, i.e. 2,2-dimethyl-1,3-propanediol acrylamide methoxyl phosphate (DPAMP) onto viscose fiber fabric (VF-g-DPAMP). The effects of the initiator concentration, DPAMP concentration, temperature, pH and time on grafting polymerization were studied, and the structure of VF-g-DPAMP was determined with Fourier transform infrared spectrometry, X-ray photoelectron spectroscopy. The surface morphology of viscose fiber fabric and VF-g-DPAMP were studied by scanning electron microscope. The thermal property and fire retardant performance of VF-g-DPAMP were assessed by thermogravimetric analysis, limited oxygen index measurements and cone calorimeter test, respectively. The results show that DPAMP has been successfully grafted onto viscose fiber fabric, and VF-g-DPAMP has good char-forming ability and better fire retardancy. The pkHRR and THR of the grafted fabric decrease from 150 to 98 kW/m2 and 5.70 to 1.73 MJ/m2, respectively.

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Metadaten
Titel
Fire retardant viscose fiber fabric produced by graft polymerization of phosphorus and nitrogen-containing monomer
verfasst von
Li-Huan Wang
Yuan-Lin Ren
Xiu-Li Wang
Jie-Yun Zhao
Yue Zhang
Qian Zeng
Ye-Tong Gu
Publikationsdatum
25.05.2016
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 4/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-016-0970-6

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