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Cellulose
Erschienen in: Cellulose 2/2017

22.11.2016 | Original Paper

Removal of methyl orange from aqueous solutions by adsorption on cellulose hydrogel assisted with Fe2O3 nanoparticles

verfasst von: Hao Zhang, Qian Luan, Hu Tang, Fenghong Huang, Mingming Zheng, Qianchun Deng, Xia Xiang, Chen Yang, Jie Shi, Chang Zheng, Qi Zhou

Erschienen in: Cellulose | Ausgabe 2/2017

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Abstract

Cellulose hydrogel, fabricated from cellulose solution in an LiOH/urea aqueous system at low temperature, was successfully applied for in situ synthesis of Fe2O3 nanoparticles to obtain hybrid magnetic nanomaterials. The microporous structure of cellulose hydrogel at wet state provided reaction chambers to synthesize the Fe2O3 nanoparticles. The structure and properties of the magnetic cellulose/Fe2O3 hydrogels were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, magnetic detection, thermal analysis, etc. The results revealed that the magnetic cellulose/Fe2O3 hydrogels exhibited efficient adsorption of methyl orange in the aqueous solution as a result of the microporous structure, large surface area, and affinity for organic dyes. The equilibrium process was described well by the Langmuir isotherm model, showing a monolayer adsorption. From kinetic experiments, the adsorption process followed the pseudo-second-order kinetic model, indicating that the overall rate of dye uptake could be controlled by external mass transfer at the beginning of adsorption, while intra-particle diffusion controlled the overall rate of adsorption at a later stage. This work provided an attractive adsorbent for removing hazardous materials from wastewater.
Vorheriger Artikel Multi-color light-emitting amphiphilic cellulose/conjugated polymers nanomicelles for tumor cell imaging
Nächster Artikel An ultra-antifouling polyethersulfone membrane embedded with cellulose nanocrystals for improved dye and salt removal from water

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Metadaten
Titel
Removal of methyl orange from aqueous solutions by adsorption on cellulose hydrogel assisted with Fe2O3 nanoparticles
verfasst von
Hao Zhang
Qian Luan
Hu Tang
Fenghong Huang
Mingming Zheng
Qianchun Deng
Xia Xiang
Chen Yang
Jie Shi
Chang Zheng
Qi Zhou
Publikationsdatum
22.11.2016
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 2/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-016-1129-1

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