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Cellulose

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04.07.2017 | Original Paper

Enzymatically hydrolyzed and TEMPO-oxidized cellulose nanofibers for the production of nanopapers: morphological, optical, thermal and mechanical properties

verfasst von: Quim Tarrés, Sami Boufi, Pere Mutjé, Marc Delgado-Aguilar

Erschienen in: Cellulose | Ausgabe 9/2017

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Abstract

In the present study, CNF prepared by TEMPO-mediated oxidation and enzymatic hydrolysis were used for the production of nanopapers using a papermaking-like route. Nanopapers were characterized in terms of tensile, thermal, optical and morphological properties. Those prepared from enzymatically hydrolyzed CNF were found to be weaker at tensile than those resulting from TEMPO-mediated oxidation, but with similar level of stiffness. Enzymatically obtained CNF presented lower transparency due to their higher diameter and lower fibrillation yield. Moreover, TEMPO-oxidized CNF presented lower onset of the thermal degradation temperature (230 °C) due to the presence of carboxylic groups. Overall, the influence of increasing the amount of enzyme during enzymatic hydrolysis and the amount of sodium hypochlorite during TEMPO-mediated oxidation was assessed as function of the ultimate properties of nanopapers.

Vorheriger Artikel Enzyme-assisted mechanical production of microfibrillated cellulose from Northern Bleached Softwood Kraft pulp

Nächster Artikel Swelling properties and generation of cellulose fines originating from bleached kraft pulp refined under different operating conditions

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Titel: Enzymatically hydrolyzed and TEMPO-oxidized cellulose nanofibers for the production of nanopapers: morphological, optical, thermal and mechanical properties
verfasst von: Quim Tarrés
Sami Boufi
Pere Mutjé
Marc Delgado-Aguilar
Publikationsdatum: 04.07.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 9/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1394-7

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