nach oben

Cellulose

Erschienen in:

06.09.2017 | Original Paper

Microwave-assisted facile synthesis of TEMPO-oxidized cellulose beads with high adsorption capacity for organic dyes

verfasst von: Fengcai Lin, Yuzhe You, Xuan Yang, Xin Jiang, Qilin Lu, Ting Wang, Biao Huang, Beili Lu

Erschienen in: Cellulose | Ausgabe 11/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A facile, green and efficient microwave-assisted method was developed to oxidize cellulose hydrogel beads with neutral 2,2,6,6-tetramethylpiperidinyl-1-oxyl radical (TEMPO)-mediated system. Resulting cellulose beads were investigated by scanning electron microscopy, solid-state ¹³C-NMR spectra, and X-ray diffraction. The patterns of ¹³C-NMR spectra indicated that the oxidation occurred only at C6 primary hydroxyl carbon, and the carboxyl groups amounted to 1.28 mmol/g in the cellulose beads. The TEMPO-oxidized cellulose beads showed highly porous structures consisting of nano-sized fibrils with retention of original spherical shapes, and the crystallinity index of the cellulose II almost unchanged after oxidation. The maximum adsorption capacity of rhodamine B, auramine O, malachite green and methylene blue on the TEMPO-oxidized cellulose beads was found to be 609, 537, 740 and 873 mg/g, respectively, and the adsorption process was well described by pseudo-second-order kinetics. In addition, desorption tests showed that TEMPO-oxidized cellulose beads could be regenerated by acid treatment and used repeatedly. Thus, TEMPO-oxidized cellulose beads prepared by microwave irradiation can be potentially used for the removal of organic dyes from industrial wastewater.

Vorheriger Artikel Bacterial cellulose/gelatin scaffold loaded with VEGF-silk fibroin nanoparticles for improving angiogenesis in tissue regeneration

Nächster Artikel Preparation, characterization and in-vitro evaluation of bacterial cellulose matrices for oral drug delivery

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Akira I, Tsuguyuki S, Hayaka F (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3:71–85CrossRef

Ali I (2012) New generation adsorbents for water treatment. Chem Rev 112:5073–5091CrossRef

Astrini N, Anah L, Haryadi HR (2015) Adsorption of heavy metal ion from aqueous solution by using cellulose based hydrogel composite. Macromol Symp 353:191–197CrossRef

Bayramoglu G, Altintas B, Arica MY (2012) Synthesis and characterization of magnetic beads containing aminated fibrous surfaces for removal of reactive green 19 dye: kinetics and thermodynamic parameters. J Chem Technol Biot 87:705–713CrossRef

Béatrice K, Philippe C (2002) Recent extraction techniques for natural products: microwave-assisted extraction and pressurised solvent extraction. Phytochem Anal 13:105–113CrossRef

Cai J, Kimura S, Wada M, Kuga S, Zhang L (2008) Cellulose aerogels from aqueous alkali hydroxide–urea solution. ChemSusChem 1:149–154CrossRef

Chang C, Zhang L (2011) Cellulose-based hydrogels: present status and application prospects. Carbohydr Polym 84:40–53CrossRef

Chang C, Duan B, Zhang L (2009) Fabrication and characterization of novel macroporous cellulose–alginate hydrogels. Polymer 50:5467–5473CrossRef

Chang C, Zhang L, Zhou J, Zhang L, Kennedy JF (2010) Structure and properties of hydrogels prepared from cellulose in NaOH/urea aqueous solutions. Carbohydr Polym 82:122–127CrossRef

Chen L, Berry RM, Tam KC (2014a) Synthesis of β-cyclodextrin-modified cellulose nanocrystals (CNCs)@Fe₃O₄@SiO₂ superparamagnetic nanorods. Acs Sustain Chem Eng 2:951–958CrossRef

Chen W, Li Q, Wang Y, Yi X, Zeng J, Yu H, Liu Y, Li J (2014b) Comparative study of aerogels obtained from differently prepared nanocellulose fibers. ChemSusChem 7:154–161CrossRef

Chen X, Zhou S, Zhang L, You T, Xu F (2016) Adsorption of heavy metals by graphene oxide/cellulose hydrogel prepared from NaOH/urea aqueous solution. Materials 9:582–596CrossRef

Ching TW, Haritos V, Tanksale A (2017) Microwave assisted conversion of microcrystalline cellulose into value added chemicals using dilute acid catalyst. Carbohydr Polym 157:1794–1800CrossRef

Gabhane J, William SPMP, Vaidya AN, Mahapatra K, Chakrabarti T (2011) Influence of heating source on the efficacy of lignocellulosic pretreatment—a cellulosic ethanol perspective. Biomass Bioenerg 35:96–102CrossRef

Gan S, Zakaria S, Chia CH, Kaco H, Padzil FN (2014) Synthesis of kenaf cellulose carbamate using microwave irradiation for preparation of cellulose membrane. Carbohydr Polym 106:160–165CrossRef

Gupta VK, Suhas (2009) Application of low-cost adsorbents for dye removal—a review. J Environ Manage 90:2313–2342CrossRef

Hirota M, Tamura N, Saito T, Isogai A (2009) Surface carboxylation of porous regenerated cellulose beads by 4-acetamide-TEMPO/NaClO/NaClO2 system. Cellulose 16:841–851CrossRef

Hokkanen S, Bhatnagar A, Sillanpää M (2016) A review on modification methods to cellulose-based adsorbents to improve adsorption capacity. Water Res 91:156–173CrossRef

Hu ZH, Wen ZY (2008) Enhancing enzymatic digestibility of switchgrass by microwave-assisted alkali pretreatment. Biochem Eng J 38:369–378CrossRef

Huang B, Lu Q, Tang L (2016) Research progress of nanocellulose manufacture and application. J For Eng 1:1–9

Isobe N, Chen X, Kim UJ, Kimura S, Wada M, Saito T, Isogai A (2013) TEMPO-oxidized cellulose hydrogel as a high-capacity and reusable heavy metal ion adsorbent. J Hazard Mater 260:195–201CrossRef

Isogai A, Kato Y (1998) Preparation of polyuronic acid from cellulose by TEMPO-mediated oxidation. Cellulose 5:153–164CrossRef

Jia N, Li SM, Zhu JF, Ma MG, Xu F, Wang B, Sun RC (2010) Microwave-assisted synthesis and characterization of cellulose-carbonated hydroxyapatite nanocomposites in NaOH–urea aqueous solution. Mater Lett 64:2223–2225CrossRef

Khandanlou R, Ngoh GC, Wen TC (2016) Feasibility study and structural analysis of cellulose isolated from rice husk: microwave irradiation, optimization, and treatment process scheme. Bioresour 11:5751–5766

Kim UJ, Kuga S, Wada M, Okano T, Konodo T (2000) Periodate oxidation of crystalline cellulose. Biomacromol 1:488–492CrossRef

Laisha GM, Sharkov VI (1974) The kinetics of oxidation of celluloses by nitrogen tetroxide as a characteristic of their supermolecular structure. Polym Sci USSR 16:1971–1978CrossRef

Lin C, Zhan H, Liu MH, Fu SY, Huang LH (2010) Rapid homogeneous preparation of cellulose graft copolymer in BMIMCL under microwave irradiation. J Appl Polym Sci 118:399–404CrossRef

Lin N, Bruzzese C, Dufresne A (2012) TEMPO-oxidized nanocellulose participating as crosslinking aid for alginate-based sponges. ACS Appl Mater Interfaces 4:4948–4959CrossRef

Liu Y, Hu H (2008) X-ray diffraction study of bamboo fibers treated with NaOH. Fibers Polym 9:735–739CrossRef

Liu L, Gao ZY, Su XP, Chen X, Jiang L, Yao JM (2015) Adsorption removal of dyes from single and binary solutions using a cellulose-based bioadsorbent. ACS Sustain Chem Eng 3:432–442CrossRef

Luo X, Zhang L (2009) High effective adsorption of organic dyes on magnetic cellulose beads entrapping activated carbon. J Hazard Mater 171:340–347CrossRef

Ma X, Liu X, Anderson DP, Chang PR (2015) Modification of porous starch for the adsorption of heavy metal ions from aqueous solution. Food Chem 181:133–139CrossRef

Melo JCP, Filho ECS, Santana SAA, Airoldi C (2011) Synthesized cellulose/succinic anhydride as an ion exchanger. Calorimetry of divalent cations in aqueous suspension. Thermochim Acta 524:29–34CrossRef

Nooy AEJD, Besemer AC, Bekkum HV (1995) Highly selective nitroxyl radical-mediated oxidation of primary alcohol groups in water-soluble glucans. Carbohydr Res 269:89–98CrossRef

Peng H, Chen H, Qu Y, Li H, Xu J (2014) Bioconversion of different sizes of microcrystalline cellulose pretreated by microwave irradiation with/without NaOH. Appl Energy 117:142–148CrossRef

Peng Q, Liu M, Zheng J, Zhou C (2015) Adsorption of dyes in aqueous solutions by chitosan–halloysite nanotubes composite hydrogel beads. Microporous Mesoporous Mater 201:190–201CrossRef

Razzaq T, Kappe CO (2008) On the energy efficiency of microwave-assisted organic reactions. ChemSusChem 1:123–132CrossRef

Saito T, Isogai A (2004) TEMPO-mediated oxidation of native cellulose. The effect of oxidation conditions on chemical and crystal structures of the water-insoluble fractions. Biomacromol 5:1983–1989CrossRef

Saito T, Shibata I, Isogai A, Suguri N, Sumikawa N (2005) Distribution of carboxylate groups introduced into cotton linters by the TEMPO-mediated oxidation. Carbohydr Polym 61:414–419CrossRef

Saito T, Okita Y, Nge TT, Sugiyama J, Isogai A (2006) TEMPO-mediated oxidation of native cellulose: microscopic analysis of fibrous fractions in the oxidized products. Carbohydr Polym 65:435–440CrossRef

Saito T, Hirota M, Tamura N, Kimura S, Fukuzumi H, Heux L, Isogai A (2009) Individualization of nano-sized plant cellulose fibrils by direct surface carboxylation using TEMPO catalyst under neutral conditions. Biomacromol 10:1992–1996CrossRef

Shaveta Bansal N, Singh P (2014) F−/Cl− mediated microwave assisted breakdown of cellulose to glucose. Tetrahedron Lett 55:2467–2470CrossRef

Sun C, Huang Z, Wang J, Rao L, Zhang J, Yu J, Du J, Xu C (2016) Modification of microcrystalline cellulose with pyridone derivatives for removal of cationic dyes from aqueous solutions. Cellulose 23:2917–2927CrossRef

Tian D, Zhang X, Lu C, Yuan G, Zhang W, Zhou Z (2014) Solvent-free synthesis of carboxylate-functionalized cellulose from waste cotton fabrics for the removal of cationic dyes from aqueous solutions. Cellulose 21:473–484CrossRef

Türgay O, Ersöz G, Atalay S, Forss J, Welander U (2011) The treatment of azo dyes found in textile industry wastewater by anaerobic biological method and chemical oxidation. Sep Purif Technol 79:26–33CrossRef

Wang L, Li J (2013) Adsorption of C.I. Reactive Red 228 dye from aqueous solution by modified cellulose from flax shive: kinetics, equilibrium, and thermodynamics. Ind Crops Prod 42:153–158CrossRef

Wang YF, Gao BY, Yue QY, Wang Y, Yang ZL (2012) Removal of acid and direct dye by epichlorohydrin-dimethylamine: flocculation performance and floc aggregation properties. Bioresour Technol 113:265–271CrossRef

Wen Y, Wei B, Cheng D, An X, Ni Y (2016) Stability enhancement of nanofibrillated cellulose in electrolytes through grafting of 2-acrylamido-2-methylpropane sulfonic acid. Cellulose 24:1–8

Wu JS, Liu CH, Chu KH, Suen SY (2008) Removal of cationic dye methyl violet 2B from water by cation exchange membranes. J Membr Sci 309:239–245CrossRef

Xu Y, Xu Y, Yue X (2017) Changes of hydrogen bonding and aggregation structure of cellulose fiber due to microwave-assisted alkali treatment and its impacts on the application as fluff pulp. Cellulose 24:967–976CrossRef

Yao Q, Xie J, Liu J, Kang H, Liu Y (2014) Adsorption of lead ions using a modified lignin hydrogel. J Polym Res 21:465–481CrossRef

Yu M, Li J, Wang L (2016a) KOH-activated carbon aerogels derived from sodium carboxymethyl cellulose for high-performance supercapacitors and dye adsorption. Chem Eng J 310:300–306CrossRef

Yu S, Xiao Y, Wang G, Luo W, Li X, Liu Y (2016b) Preparation of flyash/chitosan composites and its application in the wastewater of wood dyeing. J For Eng 1:29–33

Zhang Y, Tang ZR, Fu X, Xu YJ (2010) TiO₂− graphene nanocomposites for gas-phase photocatalytic degradation of volatile aromatic pollutant: is TiO₂− graphene truly different from other TiO₂− carbon composite materials? ACS Nano 4:7303–7314CrossRef

Zhao D, Huang J, Zhong Y, Li K, Zhang L, Cai J (2016) High strength and high toughness double cross linked cellulose hydrogels: a new strategy using sequential chemical and physical cross linking. Adv Funct Mater 26:6279–6287CrossRef

Zhou Y, Zhang M, Hu X, Wang X, Niu J, Ma T (2013) Adsorption of cationic dyes on a cellulose-based multicarboxyl adsorbent. J Chem Eng Data 58:413–421CrossRef

Zhou Y, Wang X, Zhang M, Jin Q, Gao B, Ma T (2014) Removal of Pb(II) and malachite green from aqueous solution by modified cellulose. Cellulose 21:2797–2809CrossRef

Titel: Microwave-assisted facile synthesis of TEMPO-oxidized cellulose beads with high adsorption capacity for organic dyes
verfasst von: Fengcai Lin
Yuzhe You
Xuan Yang
Xin Jiang
Qilin Lu
Ting Wang
Biao Huang
Beili Lu
Publikationsdatum: 06.09.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 11/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1473-9

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 11/2017

Antimicrobial activity and controlled release of nanosilvers in bacterial cellulose composites films incorporated with montmorillonites

Cellulose laurate ester aerogel as a novel absorbing material for removing pollutants from organic wastewater

Molecular weight fractionation of high polydispersity native celluloses

Core–shell nanoparticles of carboxy methyl cellulose and compritol-PEG for antiretroviral drug delivery

Synthesis of carbon nanofibers via hydrothermal conversion of cellulose nanocrystals

Preparation and characterization of zinc oxide/TEMPO-oxidized cellulose nanofibril composite films