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16.10.2018 | Original Paper

Polypyrrole-coated cotton fabric decorated with silver nanoparticles for the catalytic removal of p-nitrophenol from water

verfasst von: Mohamad M. Ayad, Wael A. Amer, Sawsan Zaghlol, Nela Maráková, Jaroslav Stejskal

Erschienen in: Cellulose | Ausgabe 12/2018

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Abstract

The development of new catalytic transformations with easy separation and recyclability is essential in chemical synthesis. An efficient heterogeneous catalytic system composed of a conducting polymer, polypyrrole (PPy), deposited on cotton fabric support, and decorated with silver nanoparticles is described. Such ternary composites can be used in environmental issues, such as water-pollution treatment. The model reduction of p-nitrophenol to p-aminophenol with sodium borohydride was investigated by means of UV–visible spectroscopy. The reaction was catalyzed even by PPy alone and the catalytic effect was strongly enhanced by silver nanoparticles. It obeys the first-order kinetics. The catalytic effect increases with the catalyst dose due to increased number of catalytic sites. This also applies to the increased content of silver. The elevated temperature as well as the reduced polarity of the reaction medium have negative effect on the catalyst performance. The catalysts can be reused several times while maintaining good efficiency. The ternary composites are thus good candidates for the catalytic reductive removal of toxic compounds from water.

Vorheriger Artikel A heterogeneous binary solvent system for recyclable reactive dyeing of cotton fabrics

Nächster Artikel Magnetic hybrids synthesized from agroindustrial byproducts for highly efficient removal of total chromium from tannery effluent and catalytic reduction of 4-nitrophenol

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Titel: Polypyrrole-coated cotton fabric decorated with silver nanoparticles for the catalytic removal of p-nitrophenol from water
verfasst von: Mohamad M. Ayad
Wael A. Amer
Sawsan Zaghlol
Nela Maráková
Jaroslav Stejskal
Publikationsdatum: 16.10.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 12/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-2088-5

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