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02.01.2021 | Original Research

A robust and antibacterial superhydrophobic cotton fabric with sunlight-driven self-cleaning performance for oil/water separation

verfasst von: Hongyu Liu, Lin Yang, Yifei Zhan, Jianwu Lan, Jiaojiao Shang, Mi Zhou, Shaojian Lin

Erschienen in: Cellulose | Ausgabe 3/2021

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Abstract

In this work, a durable and sunlight-driven self-cleaning superhydrophobic cotton fabric was developed as a multifunctional oil/water separation material. First of all, Ag/AgCl was successfully deposited on the polydopamine modified cotton fabric surface by electrostatic adsorption, then the Ag/AgCl loaded fabric was coated by the polydimethylsiloxane (PDMS) via simple dip-coating method. The as-prepared cotton fabric (PDMS-Ag/AgCl@CF) presented the superhydrophobic property with water contact angle about 155°. Meanwhile, the prepared PDMS-Ag/AgCl@CF exhibited great tolerance and resistance to broad pH and various organic solvents, and it can also withstand 50 cycles of abrasion or 60 min of ultrasound treatment without an apparent decrease of superhydrophobicity, indicating its outstanding mechanical durability. As expected, this durable superhydrophobic fabric can availably separate various oil/water mixtures by gravity-driven force with high separation efficiency (over 97.8%), and it possessed good reusability. Additionally, the PDMS-Ag/AgCl@CF exhibited an outstanding self-cleaning performance under sunlight irradiation, due to visible light photocatalytic performance of Ag/AgCl. Finally, the resultant cotton fabric displayed good antibacterial activity. Therefore, in consideration of its prominent comprehensive performances, it is expected that the PDMS-Ag/AgCl@CF can be used as a promising material for oily water remediation.

Vorheriger Artikel Investigation on the equilibrium distribution of methanol in transformer oil-immersed cellulosic insulation

Nächster Artikel Fabrication and multifunctional properties of marigold-like nanostructured β-Ni(OH)2 coated cotton fabric

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Cao C, Ge M, Huang J et al (2016) Robust fluorine-free superhydrophobic PDMS-ormosil@fabrics for highly effective self-cleaning and efficient oil–water separation. J Mater Chem A 4:12179–12187. https://doi.org/10.1039/c6ta04420dCrossRef

Chen C, Ma W, Zhao J (2010) Semiconductor-mediated photodegradation of pollutants under visible-light irradiation. Chem Soc Rev 39:4206–4219. https://doi.org/10.1039/b921692hCrossRefPubMed

Chen J, Shen C, Yang S, Rana M, Ma P-C (2017) Acid and temperature dual-responsive cotton fabrics with polymer coating. Compos Commun 4:10–15. https://doi.org/10.1016/j.coco.2017.03.003CrossRef

Chen Z, Yu W, Du Z (2019) Study of electrothermal properties of silver nanowire/polydopamine/cotton-based nanocomposites. Cellulose 26:5995–6007. https://doi.org/10.1007/s10570-019-02506-wCrossRef

Chen S, Xie Y, Chinnappan A et al (2020a) A self-cleaning zwitterionic nano fibrous membrane for highly ef ficient oil-in-water separation. Sci Total Environ. https://doi.org/10.1016/j.scitotenv.2020.138876CrossRefPubMedPubMedCentral

Chen Y, Zhang L, Mei CT et al (2020b) Wood-inspired anisotropic cellulose nanofibril composite sponges for multifunctional applications. ACS Appl Mater Interfaces 12:35513–35522. https://doi.org/10.1021/acsami.0c10645CrossRefPubMed

Cheng Q-Y, Guan C-S, Li Y-D, Zhu J, Zeng J-B (2019) Robust and durable superhydrophobic cotton fabrics via a one-step solvothermal method for efficient oil/water separation. Cellulose 26:2861–2872. https://doi.org/10.1007/s10570-019-02267-6CrossRef

Cho YK, Park EJ, Kim D (2014) Removal of oil by gelation using hydrophobic silica nanoparticles. J Ind Eng Chem 20:1231–1235. https://doi.org/10.1016/j.jiec.2013.08.005CrossRef

Chu Z, Feng Y, Seeger S (2015) Oil/water separation with selective superantiwetting/superwetting surface materials. Angew Chem Int Ed 54:2328–2338. https://doi.org/10.1002/anie.201405785CrossRef

Dahiya R, Gottardi G, Laidani N (2015) PDMS residues-free micro/macrostructures on flexible substrates. Microelectron Eng 136:57–62. https://doi.org/10.1016/j.mee.2015.04.037CrossRef

Gao X, Xu L-P, Xue Z et al (2014) Dual-scaled porous nitrocellulose membranes with underwater superoleophobicity for highly efficient oil/water separation. Adv Mater 26:1771–1775. https://doi.org/10.1002/adma.201304487CrossRefPubMed

Gao S, Huang J, Li S et al (2017) Facile construction of robust fluorine-free superhydrophobic TiO₂@fabrics with excellent anti-fouling, water-oil separation and UV-protective properties. Mater Des 128:1–8. https://doi.org/10.1016/j.matdes.2017.04.091CrossRef

Gao S, Dong X, Huang J, Li S, Li Y, Chen Z, Lai Y (2018) Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil–water separation. Chem Eng J 333:621–629. https://doi.org/10.1016/j.cej.2017.10.006CrossRef

Ge J, Zong D, Jin Q, Yu J, Ding B (2018) Biomimetic and superwettable nanofibrous skins for highly efficient separation of oil-in-water emulsions. Adv Funct Mater. https://doi.org/10.1002/adfm.201705051CrossRef

Guan XM, Lin SJ, Lan JW et al (2019) Fabrication of Ag/AgCl/ZIF-8/TiO₂ decorated cotton fabric as a highly efficient photocatalyst for degradation of organic dyes under visible light. Cellulose 26:7437–7450. https://doi.org/10.1007/s10570-019-02621-8CrossRef

Guan XM, Zhan YF, Yang L et al (2020) Durable and recyclable Ag/AgCl/CeO₂ coated cotton fabrics with enhanced visible light photocatalytic performance for degradation of dyes. Cellulose 27:6383–6398. https://doi.org/10.1007/s10570-020-03241-3CrossRef

Gupta RK, Dunderdale GJ, England MW, Hozumi A (2017) Oil/water separation techniques: a review of recent progresses and future directions. J Mater Chem A 5:16025–16058. https://doi.org/10.1039/c7ta02070hCrossRef

Huang JY, Li SH, Ge MZ et al (2015) Robust superhydrophobic TiO₂@fabrics for UV shielding, self-cleaning and oil–water separation. J Mater Chem A 3:2825–2832. https://doi.org/10.1039/c4ta05332jCrossRef

Ismail NH, Salleh WNW, Ismail AF, Hasbullah H, Yusof N, Aziz F, Jaafar J (2020) Hydrophilic polymer-based membrane for oily wastewater treatment: a review. Sep Purif Technol. https://doi.org/10.1016/j.seppur.2019.116007CrossRef

Kamegawa T, Shimizu Y, Yamashita H (2012) Superhydrophobic surfaces with photocatalytic self-cleaning properties by nanocomposite coating of TiO₂ and polytetrafluoroethylene. Adv Mater 24:3697–3700. https://doi.org/10.1002/adma.201201037CrossRefPubMed

Kung CH, Zahiri B, Sow PK, Merida W (2018) On-demand oil–water separation via low-voltage wettability switching of core–shell structures on copper substrates. Appl Surf Sci 444:15–27. https://doi.org/10.1016/j.apsusc.2018.02.238CrossRef

Li J, Kang R, Tang X, She H, Yang Y, Zha F (2016) Superhydrophobic meshes that can repel hot water and strong corrosive liquids used for efficient gravity-driven oil/water separation. Nanoscale 8:7638–7645. https://doi.org/10.1039/c6nr01298aCrossRefPubMed

Li X, Cao M, Shan H, Tezer FH, Li B (2019) Facile and scalable fabrication of superhydrophobic and superoleophilic PDMS-co-PMHS coating on porous substrates for highly effective oil/water separation. Chem Eng J 358:1101–1113. https://doi.org/10.1016/j.cej.2018.10.097CrossRef

Lin Y-T, Ting Y-S, Chen B-Y, Cheng Y-W, Liu T-Y (2020) Bionic shark skin replica and zwitterionic polymer brushes functionalized PDMS membrane for anti-fouling and wound dressing applications. Surf Coat Technol. https://doi.org/10.1016/j.surfcoat.2020.125663CrossRef

Ma Q, Cheng H, Fane AG, Wang R, Zhang H (2016) Recent development of advanced materials with special wettability for selective oil/water separation. Small 12:2186–2202. https://doi.org/10.1002/smll.201503685CrossRefPubMed

Ma W, Zhang M, Liu Z, Kang M, Huang C, Fu G (2019) Fabrication of highly durable and robust superhydrophobic–superoleophilic nanofibrous membranes based on a fluorine-free system for efficient oil/water separation. J Membr Sci 570:303–313. https://doi.org/10.1016/j.memsci.2018.10.035CrossRef

Ma W, Ding Y, Zhang M, Gao S, Li Y, Huang C, Fu G (2020) Nature-inspired chemistry toward hierarchical superhydrophobic, antibacterial and biocompatible nanofibrous membranes for effective UV-shielding, self-cleaning and oil–water separation. J Hazard Mater. https://doi.org/10.1016/j.jhazmat.2019.121476CrossRefPubMed

Mai Z, Shu X, Li G, Chen D, Liu M, Xu W, Zhang H (2019) One-step fabrication of flexible, durable and fluorine-free superhydrophobic cotton fabrics for efficient oil/water separation. Cellulose 26:6349–6363. https://doi.org/10.1007/s10570-019-02515-9CrossRef

Qi Z, Wang K, Jiang Y et al (2019) Preparation and characterization of SnO₂-x/GO composite photocatalyst and its visible light photocatalytic activity for self-cleaning cotton fabrics. Cellulose 26:8919–8937. https://doi.org/10.1007/s10570-019-02662-zCrossRef

Ren Y, Li W, Cao Z et al (2020) Robust TiO₂ nanorods-SiO₂ core–shell coating with high-performance self-cleaning properties under visible light. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2020.145377CrossRef

Shi H, Zhou M, Song D et al (2014) Highly porous SnO₂/TiO₂ electrospun nanofibers with high photocatalytic activities. Ceram Int 40:10383–10393. https://doi.org/10.1016/j.ceramint.2014.02.124CrossRef

Strohmeier BR (1991) Evaluation of polymeric standard reference materials for monitoring the performance of X-ray photoelectron spectrometers. Appl Surf Sci 47:225–234. https://doi.org/10.1016/0169-4332(91)90036-jCrossRef

Tao M, Xue L, Liu F, Jiang L (2014) An intelligent superwetting PVDF membrane showing switchable transport performance for oil/water separation. Adv Mater 26:2943–2948. https://doi.org/10.1002/adma.201305112CrossRefPubMed

Wang M, Peng M, Weng Y-X, Li Y-D, Zeng J-B (2019) Toward durable and robust superhydrophobic cotton fabric through hydrothermal growth of ZnO for oil/water separation. Cellulose 26:8121–8133. https://doi.org/10.1007/s10570-019-02635-2CrossRef

Wang F, Chen L, Li H et al (2020) N-doped honeycomb-like porous carbon towards high-performance supercapacitor. Chin Chem Lett 31:1986–1990. https://doi.org/10.1016/j.cclet.2020.02.020CrossRef

Xu C, Feng R, Song F, Wang X-L, Wang Y-Z (2018) Desert beetle-inspired superhydrophilic/superhydrophobic patterned cellulose film with efficient water collection and antibacterial performance. ACS Sustain Chem Eng 6:14679–14684. https://doi.org/10.1021/acssuschemeng.8b03247CrossRef

Xue Z, Wang S, Lin L, Chen L, Liu M, Feng L, Jiang L (2011) A novel superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation. Adv Mater 23:4270–4273. https://doi.org/10.1002/adma.201102616CrossRefPubMed

Xue Z, Cao Y, Liu N, Feng L, Jiang L (2014) Special wettable materials for oil/water separation. J Mater Chem A 2:2445–2460. https://doi.org/10.1039/c3ta13397dCrossRef

Yang J, Xu H, Zhang L, Zhong Y, Sui X, Mao Z (2017) Lasting superhydrophobicity and antibacterial activity of Cu nanoparticles immobilized on the surface of dopamine modified cotton fabrics. Surf Coat Technol 309:149–154. https://doi.org/10.1016/j.surfcoat.2016.11.058CrossRef

Yang M, Liu W, Jiang C, Xie Y, Shi H, Zhang F (2019a) Facile fabrication of robust fluorine-free superhydrophobic cellulosic fabric for self-cleaning, photocatalysis and UV shielding. Cellulose 26:8153–8164. https://doi.org/10.1007/s10570-019-02640-5CrossRef

Yang Y, Huang W, Guo Z et al (2019b) Robust fluorine-free colorful superhydrophobic PDMS/NH2-MIL-125(Ti)@cotton fabrics for improved ultraviolet resistance and efficient oil–water separation. Cellulose 26:9335–9348. https://doi.org/10.1007/s10570-019-02707-3CrossRef

Yuan D, Zhang T, Guo Q, Qiu F, Yang D, Ou Z (2018) Superhydrophobic hierarchical biomass carbon aerogel assembled with TiO₂ nanorods for selective immiscible oil/water mixture and emulsion separation. Ind Eng Chem Res 57:14758–14766. https://doi.org/10.1021/acs.iecr.8b03661CrossRef

Zeng X, Qian L, Yuan X et al (2017) Inspired by stenocara beetles: from water collection to high-efficiency water-in-oil emulsion separation. ACS Nano 11:760–769. https://doi.org/10.1021/acsnano.6b07182CrossRefPubMed

Zhan YF, Lan JW, Shang JJ et al (2020) Durable ZIF-8/Ag/AgCl/TiO₂ decorated PAN nanofibers with high visible light photocatalytic and antibacterial activities for degradation of dyes. J Alloys Compd. https://doi.org/10.1016/j.jallcom.2019.153579CrossRef

Zhang J, Seeger S (2011) Polyester materials with superwetting silicone nanofilaments for oil/water separation and selective oil absorption. Adv Funct Mater 21:4699–4704. https://doi.org/10.1002/adfm.201101090CrossRef

Zhang W, Shi Z, Zhang F, Liu X, Jin J, Jiang L (2013a) Superhydrophobic and superoleophilic PVDF membranes for effective separation of water-in-oil emulsions with high flux. Adv Mater 25:2071–2076. https://doi.org/10.1002/adma.201204520CrossRefPubMed

Zhang X, Li Z, Liu K, Jiang L (2013b) Bioinspired multifunctional foam with self-cleaning and oil/water separation. Adv Funct Mater 23:2881–2886. https://doi.org/10.1002/adfm.201202662CrossRef

Zhang W, Lu X, Xin Z, Zhou C (2015) A self-cleaning polybenzoxazine/TiO₂ surface with superhydrophobicity and superoleophilicity for oil/water separation. Nanoscale 7:19476–19483. https://doi.org/10.1039/c5nr06425bCrossRefPubMed

Zheng Y, Shu J, Wang Z (2015) AgCl@Ag composites with rough surfaces as bifunctional catalyst for the photooxidation and catalytic reduction of 4-nitrophenol. Mater Lett 158:339–342. https://doi.org/10.1016/j.matlet.2015.06.033CrossRef

Zhou C, Chen Z, Yang H, Hou K, Zeng X, Zheng Y, Cheng J (2017) Nature-inspired strategy toward superhydrophobic fabrics for versatile oil/water separation. ACS Appl Mater Interfaces 9:9184–9194. https://doi.org/10.1021/acsami.7b00412CrossRefPubMed

Zhu T, Li S, Huang J, Mihailiasa M, Lai Y (2017) Rational design of multi-layered superhydrophobic coating on cotton fabrics for UV shielding, self-cleaning and oil–water separation. Mater Des 134:342–351. https://doi.org/10.1016/j.matdes.2017.08.071CrossRef

Titel: A robust and antibacterial superhydrophobic cotton fabric with sunlight-driven self-cleaning performance for oil/water separation
verfasst von: Hongyu Liu
Lin Yang
Yifei Zhan
Jianwu Lan
Jiaojiao Shang
Mi Zhou
Shaojian Lin
Publikationsdatum: 02.01.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03585-w

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