Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 11/2018

24.03.2018

Synthesis and characterization of Zn-doped Mn3O4 thin films using successive ionic layer adsorption and reaction technique: Its structural, optical and wettability properties

verfasst von: Ozkan Bayram, Mehmet Emrah Ertargin, Erdal Igman, Harun Guney, Onder Simsek

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 11/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this study, it is aimed to obtain Zn doped Mn3O4 (manganese oxide) nanostructured thin films on the soda lime glass substrates by successive ionic layer adsorption and reaction technique. The tetragonal crystal structure of the all thin films was detected using XRD spectroscopy. The average crystallite size of undoped Mn3O4 thin films was calculated to be 29 nm and for Zn-doped thin films, this value decreased to 23 nm with increasing Zn concentration. Characteristic peaks for thin films were also confirmed by RAMAN spectroscopy. The morphological structures of zinc-doped manganese oxide nano-sheets thin films were revealed by SEM. Using UV–Vis spectroscopy, it was found that the optical band gap of Mn3O4 thin films decreased from 2.05 to 1.73 eV with Zn doping. It has also been understood from the wettability analyzes of thin films that all thin films have a hydrophilic character. From all these analyzes, it is thought that the Zn doped Mn3O4 thin films have the potential to be used in supercapacitor applications.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat O. Erlandsson et al., Electrochromic properties of manganese oxide (MnOx) thin films made by electron beam deposition. Phys. Status Solidi (a) 139(2), 451–457 (1993)CrossRef O. Erlandsson et al., Electrochromic properties of manganese oxide (MnOx) thin films made by electron beam deposition. Phys. Status Solidi (a) 139(2), 451–457 (1993)CrossRef
2.
Zurück zum Zitat B. Yao et al., Grain growth and void formation in dielectric-encapsulated Cu thin films. J. Mater. Res. 23(7), 2033–2039 (2008)CrossRef B. Yao et al., Grain growth and void formation in dielectric-encapsulated Cu thin films. J. Mater. Res. 23(7), 2033–2039 (2008)CrossRef
3.
Zurück zum Zitat G. An et al., Low-temperature synthesis of Mn3O4 nanoparticles loaded on multi-walled carbon nanotubes and their application in electrochemical capacitors. Nanotechnology 19(27), 275709 (2008)CrossRef G. An et al., Low-temperature synthesis of Mn3O4 nanoparticles loaded on multi-walled carbon nanotubes and their application in electrochemical capacitors. Nanotechnology 19(27), 275709 (2008)CrossRef
4.
Zurück zum Zitat W. Wei et al., Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chem. Soc. Rev. 40(3), 1697–1721 (2011)CrossRef W. Wei et al., Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chem. Soc. Rev. 40(3), 1697–1721 (2011)CrossRef
5.
Zurück zum Zitat H. Jiang et al., Hydrothermal synthesis of novel Mn3O4 nano-octahedrons with enhanced supercapacitors performances. Nanoscale 2(10), 2195–2198 (2010)CrossRef H. Jiang et al., Hydrothermal synthesis of novel Mn3O4 nano-octahedrons with enhanced supercapacitors performances. Nanoscale 2(10), 2195–2198 (2010)CrossRef
6.
Zurück zum Zitat D. Dubal et al., Chemical synthesis and characterization of Mn3O4 thin films for supercapacitor application. J. Alloys Compd. 497(1), 166–170 (2010)CrossRef D. Dubal et al., Chemical synthesis and characterization of Mn3O4 thin films for supercapacitor application. J. Alloys Compd. 497(1), 166–170 (2010)CrossRef
7.
Zurück zum Zitat D.P. Dubal, R. Holze, Self-assembly of stacked layers of Mn3O4 nanosheets using a scalable chemical strategy for enhanced, flexible, electrochemical energy storage. J. Power Sources 238, 274–282 (2013)CrossRef D.P. Dubal, R. Holze, Self-assembly of stacked layers of Mn3O4 nanosheets using a scalable chemical strategy for enhanced, flexible, electrochemical energy storage. J. Power Sources 238, 274–282 (2013)CrossRef
8.
Zurück zum Zitat J. Chen et al., The effect of Al doping on the morphology and optical property of ZnO nanostructures prepared by hydrothermal process. Appl. Surf. Sci. 255(7), 3959–3964 (2009)CrossRef J. Chen et al., The effect of Al doping on the morphology and optical property of ZnO nanostructures prepared by hydrothermal process. Appl. Surf. Sci. 255(7), 3959–3964 (2009)CrossRef
9.
Zurück zum Zitat A.E. Morales, M.H. Zaldivar, U. Pal, Indium doping in nanostructured ZnO through low-temperature hydrothermal process. Opt. Mater. 29(1), 100–104 (2006)CrossRef A.E. Morales, M.H. Zaldivar, U. Pal, Indium doping in nanostructured ZnO through low-temperature hydrothermal process. Opt. Mater. 29(1), 100–104 (2006)CrossRef
10.
Zurück zum Zitat A. Srivastava et al., Influence of Fe doping on nanostructures and photoluminescence of sol–gel derived ZnO. Mater. Chem. Phys. 114(1), 194–198 (2009)CrossRef A. Srivastava et al., Influence of Fe doping on nanostructures and photoluminescence of sol–gel derived ZnO. Mater. Chem. Phys. 114(1), 194–198 (2009)CrossRef
11.
Zurück zum Zitat M. Amara et al., Microstructural, optical and ethanol sensing properties of sprayed Li-doped Mn3O4 thin films. Mater. Res. Bull. 75, 217–223 (2016)CrossRef M. Amara et al., Microstructural, optical and ethanol sensing properties of sprayed Li-doped Mn3O4 thin films. Mater. Res. Bull. 75, 217–223 (2016)CrossRef
12.
Zurück zum Zitat I. Sheikhshoaie, S. Ramezanpour, M. Khatamian, Synthesis and characterization of thallium doped Mn3O4 as superior sunlight photocatalysts. J. Mol. Liq. 238, 248–253 (2017)CrossRef I. Sheikhshoaie, S. Ramezanpour, M. Khatamian, Synthesis and characterization of thallium doped Mn3O4 as superior sunlight photocatalysts. J. Mol. Liq. 238, 248–253 (2017)CrossRef
13.
Zurück zum Zitat S. Ramezanpour, I. Sheikhshoaie, M. Khatamian, Synthesis, characterization and photocatalytic properties of V-doped Mn3O4 nanoparticles as a visible light-activated photocatalyst. J. Mol. Liq. 231, 64–71 (2017)CrossRef S. Ramezanpour, I. Sheikhshoaie, M. Khatamian, Synthesis, characterization and photocatalytic properties of V-doped Mn3O4 nanoparticles as a visible light-activated photocatalyst. J. Mol. Liq. 231, 64–71 (2017)CrossRef
14.
Zurück zum Zitat O. Nilsen, H. Fjellvåg, A. Kjekshus, Growth of manganese oxide thin films by atomic layer deposition. Thin Solid Films 444(1), 44–51 (2003)CrossRef O. Nilsen, H. Fjellvåg, A. Kjekshus, Growth of manganese oxide thin films by atomic layer deposition. Thin Solid Films 444(1), 44–51 (2003)CrossRef
15.
Zurück zum Zitat L. Guo et al., Structural characteristic and magnetic properties of Mn oxide films grown by plasma-assisted MBE. J. Cryst. Growth 227, 955–959 (2001)CrossRef L. Guo et al., Structural characteristic and magnetic properties of Mn oxide films grown by plasma-assisted MBE. J. Cryst. Growth 227, 955–959 (2001)CrossRef
16.
Zurück zum Zitat C.-C. Hu, C.-C. Wang, Nanostructures and capacitive characteristics of hydrous manganese oxide prepared by electrochemical deposition. J. Electrochem. Soc. 150(8), A1079–A1084 (2003)CrossRef C.-C. Hu, C.-C. Wang, Nanostructures and capacitive characteristics of hydrous manganese oxide prepared by electrochemical deposition. J. Electrochem. Soc. 150(8), A1079–A1084 (2003)CrossRef
17.
Zurück zum Zitat H.Y. Xu et al., Chemical bath deposition of hausmannite Mn3O4 thin films. Appl. Surf. Sci. 252(12), 4091–4096 (2006)CrossRef H.Y. Xu et al., Chemical bath deposition of hausmannite Mn3O4 thin films. Appl. Surf. Sci. 252(12), 4091–4096 (2006)CrossRef
18.
Zurück zum Zitat R. Bayón et al., Characterization of copper–manganese-oxide thin films deposited by dip-coating. Sol. Energy Mater. Sol. Cells 92(10), 1211–1216 (2008)CrossRef R. Bayón et al., Characterization of copper–manganese-oxide thin films deposited by dip-coating. Sol. Energy Mater. Sol. Cells 92(10), 1211–1216 (2008)CrossRef
19.
Zurück zum Zitat C.-Y. Chen et al., Hybrid manganese oxide films for supercapacitor application prepared by sol–gel technique. Thin Solid Films 518(5), 1557–1560 (2009)CrossRef C.-Y. Chen et al., Hybrid manganese oxide films for supercapacitor application prepared by sol–gel technique. Thin Solid Films 518(5), 1557–1560 (2009)CrossRef
20.
Zurück zum Zitat R. Bayón, G. San Vicente, Á Morales, Durability tests and up-scaling of selective absorbers based on copper–manganese oxide deposited by dip-coating. Sol. Energy Mater. Sol. Cells 94(6), 998–1004 (2010)CrossRef R. Bayón, G. San Vicente, Á Morales, Durability tests and up-scaling of selective absorbers based on copper–manganese oxide deposited by dip-coating. Sol. Energy Mater. Sol. Cells 94(6), 998–1004 (2010)CrossRef
21.
Zurück zum Zitat K. Chaudhari et al., Chemical synthesis and characterization of CdSe thin films deposited by SILAR technique for optoelectronic applications. J. Sci. 1(4), 476–481 (2016) K. Chaudhari et al., Chemical synthesis and characterization of CdSe thin films deposited by SILAR technique for optoelectronic applications. J. Sci. 1(4), 476–481 (2016)
22.
Zurück zum Zitat A. Jha, R. Thapa, K. Chattopadhyay, Structural transformation from Mn3O4 nanorods to nanoparticles and band gap tuning via Zn doping. Mater. Res. Bull. 47(3), 813–819 (2012)CrossRef A. Jha, R. Thapa, K. Chattopadhyay, Structural transformation from Mn3O4 nanorods to nanoparticles and band gap tuning via Zn doping. Mater. Res. Bull. 47(3), 813–819 (2012)CrossRef
23.
Zurück zum Zitat R. Dong et al., Enhanced supercapacitor performance of Mn3O4 nanocrystals by doping transition-metal ions. ACS Appl. Mater. Interfaces 5(19), 9508–9516 (2013)CrossRef R. Dong et al., Enhanced supercapacitor performance of Mn3O4 nanocrystals by doping transition-metal ions. ACS Appl. Mater. Interfaces 5(19), 9508–9516 (2013)CrossRef
24.
Zurück zum Zitat K.J. Kim, Y.R. Park, Sol–gel growth and structural and optical investigation of manganese-oxide thin films: structural transformation by Zn doping. J. Cryst. Growth 270(1), 162–167 (2004)CrossRef K.J. Kim, Y.R. Park, Sol–gel growth and structural and optical investigation of manganese-oxide thin films: structural transformation by Zn doping. J. Cryst. Growth 270(1), 162–167 (2004)CrossRef
25.
Zurück zum Zitat T. Larbi et al., Nickel content effect on the microstructural, optical and electrical properties of p-type Mn3O4 sprayed thin films. J. Alloys Compd. 626, 93–101 (2015)CrossRef T. Larbi et al., Nickel content effect on the microstructural, optical and electrical properties of p-type Mn3O4 sprayed thin films. J. Alloys Compd. 626, 93–101 (2015)CrossRef
26.
Zurück zum Zitat R. Ran et al., Oxygen storage capacity and structural properties of Ni-doped LaMnO3 perovskites. J. Alloys Compd. 577, 288–294 (2013)CrossRef R. Ran et al., Oxygen storage capacity and structural properties of Ni-doped LaMnO3 perovskites. J. Alloys Compd. 577, 288–294 (2013)CrossRef
27.
Zurück zum Zitat A.U. Ubale et al., Size-dependent structural, electrical and optical properties of nanostructured iron selenide thin films deposited by chemical bath deposition method. Solid State Sci. 16, 134–142 (2013)CrossRef A.U. Ubale et al., Size-dependent structural, electrical and optical properties of nanostructured iron selenide thin films deposited by chemical bath deposition method. Solid State Sci. 16, 134–142 (2013)CrossRef
28.
Zurück zum Zitat M. Ristić et al., Synthesis and long-term phase stability of Mn3O4 nanoparticles. J. Mol. Struct. 1044, 255–261 (2013)CrossRef M. Ristić et al., Synthesis and long-term phase stability of Mn3O4 nanoparticles. J. Mol. Struct. 1044, 255–261 (2013)CrossRef
29.
Zurück zum Zitat Z. Chen et al., Microstructural evolution of oxides and semiconductor thin films. Prog. Mater. Sci. 56(7), 901–1029 (2011)CrossRef Z. Chen et al., Microstructural evolution of oxides and semiconductor thin films. Prog. Mater. Sci. 56(7), 901–1029 (2011)CrossRef
30.
Zurück zum Zitat T. Larbi et al., A study of optothermal and AC impedance properties of Cr-doped Mn3O4 sprayed thin films. Mater. Res. Bull. 70, 254–262 (2015)CrossRef T. Larbi et al., A study of optothermal and AC impedance properties of Cr-doped Mn3O4 sprayed thin films. Mater. Res. Bull. 70, 254–262 (2015)CrossRef
31.
Zurück zum Zitat D. Dubal et al., A novel chemical synthesis of Mn3O4 thin film and its stepwise conversion into birnessite MnO2 during super capacitive studies. J. Electroanal. Chem. 647(1), 60–65 (2010)CrossRef D. Dubal et al., A novel chemical synthesis of Mn3O4 thin film and its stepwise conversion into birnessite MnO2 during super capacitive studies. J. Electroanal. Chem. 647(1), 60–65 (2010)CrossRef
32.
Zurück zum Zitat A.J. Nelson, J.G. Reynolds, J.W. Roos, Comprehensive characterization of engine deposits from fuel containing MMT®. Sci. Total Environ. 295(1), 183–205 (2002)CrossRef A.J. Nelson, J.G. Reynolds, J.W. Roos, Comprehensive characterization of engine deposits from fuel containing MMT®. Sci. Total Environ. 295(1), 183–205 (2002)CrossRef
33.
Zurück zum Zitat A. Ubale et al., Characterization of nanostructured Mn3O4 thin films grown by SILAR method at room temperature. Mater. Chem. Phys. 136(2), 1067–1072 (2012)CrossRef A. Ubale et al., Characterization of nanostructured Mn3O4 thin films grown by SILAR method at room temperature. Mater. Chem. Phys. 136(2), 1067–1072 (2012)CrossRef
34.
Zurück zum Zitat M. Belkhedkar, A. Ubale, Physical properties of nanostructured Mn3O4 thin films synthesized by SILAR method at room temperature for antibacterial application. J. Mol. Struct. 1068, 94–100 (2014)CrossRef M. Belkhedkar, A. Ubale, Physical properties of nanostructured Mn3O4 thin films synthesized by SILAR method at room temperature for antibacterial application. J. Mol. Struct. 1068, 94–100 (2014)CrossRef
35.
Zurück zum Zitat J. Pankove, Optical Processes in Semiconductors, vol 92 (Prentice-Hall, New Jersey, 1971) J. Pankove, Optical Processes in Semiconductors, vol 92 (Prentice-Hall, New Jersey, 1971)
36.
Zurück zum Zitat L. Kuang et al., Hydrothermal synthesis and metal ions doping effects of single-crystal Mn3O4. Mater. Res. Bull. 48(9), 3122–3128 (2013)CrossRef L. Kuang et al., Hydrothermal synthesis and metal ions doping effects of single-crystal Mn3O4. Mater. Res. Bull. 48(9), 3122–3128 (2013)CrossRef
37.
Zurück zum Zitat J. Bico, U. Thiele, D. Quéré, Wetting of textured surfaces. Colloids Surf. A 206(1), 41–46 (2002)CrossRef J. Bico, U. Thiele, D. Quéré, Wetting of textured surfaces. Colloids Surf. A 206(1), 41–46 (2002)CrossRef
38.
Zurück zum Zitat B. Bhushan, Y.C. Jung, Wetting study of patterned surfaces for superhydrophobicity. Ultramicroscopy 107(10), 1033–1041 (2007)CrossRef B. Bhushan, Y.C. Jung, Wetting study of patterned surfaces for superhydrophobicity. Ultramicroscopy 107(10), 1033–1041 (2007)CrossRef
39.
Zurück zum Zitat S.S. Latthe et al., Superhydrophobic silica films by sol–gel co-precursor method. Appl. Surf. Sci. 256(1), 217–222 (2009)CrossRef S.S. Latthe et al., Superhydrophobic silica films by sol–gel co-precursor method. Appl. Surf. Sci. 256(1), 217–222 (2009)CrossRef
40.
Zurück zum Zitat D. Dubal et al., A novel chemical synthesis of interlocked cubes of hausmannite Mn3O4 thin films for supercapacitor application. J. Alloy. Compd. 484(1), 218–221 (2009)CrossRef D. Dubal et al., A novel chemical synthesis of interlocked cubes of hausmannite Mn3O4 thin films for supercapacitor application. J. Alloy. Compd. 484(1), 218–221 (2009)CrossRef
41.
Zurück zum Zitat M. Minakshi et al., Lithium insertion into manganese dioxide electrode in MnO2/Zn aqueous battery: part II. Comparison of the behavior of EMD and battery grade MnO2 in Zn|MnO2| aqueous LiOH electrolyte. J. Power Sources 138(1), 319–322 (2004)CrossRef M. Minakshi et al., Lithium insertion into manganese dioxide electrode in MnO2/Zn aqueous battery: part II. Comparison of the behavior of EMD and battery grade MnO2 in Zn|MnO2| aqueous LiOH electrolyte. J. Power Sources 138(1), 319–322 (2004)CrossRef
42.
Zurück zum Zitat J. Schmitt, H.-C. Flemming, FTIR-spectroscopy in microbial and material analysis. Int. Biodeterior. Biodegrad. 41(1), 1–11 (1998)CrossRef J. Schmitt, H.-C. Flemming, FTIR-spectroscopy in microbial and material analysis. Int. Biodeterior. Biodegrad. 41(1), 1–11 (1998)CrossRef
Metadaten
Titel
Synthesis and characterization of Zn-doped Mn3O4 thin films using successive ionic layer adsorption and reaction technique: Its structural, optical and wettability properties
verfasst von
Ozkan Bayram
Mehmet Emrah Ertargin
Erdal Igman
Harun Guney
Onder Simsek
Publikationsdatum
24.03.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 11/2018
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-018-8980-9

Weitere Artikel der Ausgabe 11/2018

Journal of Materials Science: Materials in Electronics 11/2018 Zur Ausgabe

Neuer Inhalt