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Rare Metals
Erschienen in: Rare Metals 12/2021

22.03.2021 | Original Article

Self-corrosion, electrochemical and discharge behavior of commercial purity Al anode via Mn modification in Al-air battery

verfasst von: Guo-Sheng Peng, Jun Huang, Yi-Cheng Gu, Guang-Sheng Song

Erschienen in: Rare Metals | Ausgabe 12/2021

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Abstract

The self-corrosion, electrochemical and discharge behavior of commercial purity Al anode via Mn modification in Al–air battery was studied by the hydrogen evolution, weight loss, electrical conductivity, electrochemical and discharge tests. Results show that the synergetic effects of the dissolved Mn and Mn-modifying Al3Fe intermetallic decrease the weight loss and inhibit the hydrogen evolution of commercial purity Al in NaOH solution when minor Mn is introduced. However, more Mn addition leads to the formation of Al6Mn intermetallic, which has little effect on the weight loss, but accelerates the hydrogen evolution. Mn introduction plays a positive role in activating Al anodes, resulting in a decrease in the anodic polarization and an increase in the discharge voltage. Among all the commercial purity Al–xMn anodes, 0.1 wt% Mn addition exhibits the best discharge efficiency for Al–air battery.

Graphical abstract

Vorheriger Artikel In situ formed three-dimensional (3D) lithium–boron (Li–B) alloy as a potential anode for next-generation lithium batteries
Nächster Artikel Structure stability, electronic property and voltage profile of LiFe1−nNnP1−mMmO4 olivine cathode material

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Metadaten
Titel
Self-corrosion, electrochemical and discharge behavior of commercial purity Al anode via Mn modification in Al-air battery
verfasst von
Guo-Sheng Peng
Jun Huang
Yi-Cheng Gu
Guang-Sheng Song
Publikationsdatum
22.03.2021
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 12/2021
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01687-9

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