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Polymer Bulletin
Erschienen in: Polymer Bulletin 9/2011

01.12.2011 | Original Paper

Enhanced interfacial interaction for effective reinforcement of poly(vinyl alcohol) nanocomposites at low loading of graphene

verfasst von: Xiaoya Yuan

Erschienen in: Polymer Bulletin | Ausgabe 9/2011

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Abstract

The graphene/poly(vinyl alcohol) (PVA) nancomposites with homogeneous dispersion of the nanosheet and enhanced nanofiller–matrix interfacial interaction were fabricated via water blending partially reduced graphene oxide and PVA. The nanocomposites were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetry. The graphene nanosheets were fully exfoliated in the PVA matrix and a new covalent linkage was formed between graphene and PVA matrix. Uncommon to conventional method, the enhanced interfacial adhesion resulted from covalent interaction and hydrogen bondings between graphene and PVA backbone. The mechanical and thermal properties of the nanocomposites were significantly improved at low graphene loadings. An 116% increase in tensile strength and a 19 °C improvement of onset thermal degradation temperature were achieved by the addition of only 0.8 wt% graphene.
Vorheriger Artikel Liquid-phase polymer-based retention and coupled electrocatalytic oxidation to remove Arsenic in the presence of competitive species
Nächster Artikel Poly(imide-amide)s and poly(imide-esters)s based on silarylene units containing (l)-alanine moiety: synthesis and characterization

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Metadaten
Titel
Enhanced interfacial interaction for effective reinforcement of poly(vinyl alcohol) nanocomposites at low loading of graphene
verfasst von
Xiaoya Yuan
Publikationsdatum
01.12.2011
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 9/2011
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0506-z

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