Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 10/2017

24.07.2017 | Original Contribution

Structured solvent effects on precipitation

Microscopically organized cerium oxalate particles

verfasst von: Marie Jehannin, Sophie Charton, Bruno Corso, Helmuth Möhwald, Hans Riegler, Thomas Zemb

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The synthesis of cerium oxalate, a reaction intermediate in the preparation of high performance ceramics, is studied in sessile droplets. We compare here the effect of alcoholic solvents with the usage of structured solvents, namely ultra-flexible microemulsions in the water-rich and oil-rich configurations. The nucleation and the growth of cerium oxalate particles are the result of local mixing by the Marangoni flow of droplets loaded with oxalic acid and cerium nitrate. The morphology of the particles is very different depending on the composition of the solvent and on the mixing process. We show that the variation of the particle morphology results from the difference of the structured solvent microphases during the precipitation process. When the precipitation occurs in a water continuous phase, usual needle-like oxalate particles precipitate. When the precipitate is formed in the dispersed phase of the emulsion, structured aggregates, as close-packed aggregates of needles, are compacted by microcapillarity effects.
Vorheriger Artikel Degradable thermosensitive injectable hydrogels with two-phase composite structure from aqueous solutions of poly(N-isopropylacrylamide-co-5,6-benzo-2-methylene-1,3-dioxepane)—poly(ethylene glycol) triblock copolymers and biopolymers
Nächster Artikel Functionalized acetoacetylated poly(vinyl alcohol) monoliths for enzyme immobilization: a phase separation method

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Fußnoten
1
The declared difference in strength of the light scattering for the WSL and the SSL patterns may not always appear clearly in the images shown in this publication, due to the limited range of contrast in the reproduction. However, in the direct optical microscopy investigations, it is quite pronounced and unambiguous.
 
2
the PF regime neither reflects the oxalic excess, OE, as suggested in our previous publication, nor does it follow the stoichiometric line.
 
3
The diol concentration in the ternary mixtures was slightly higher than in the previously investigated binary mixtures with only 50% diol [26]. Control experiments with binary solvents with 44.7% water and 55.3% 1,2-propanediol reveal similar periodic precipitation patterns as obtained previously for the slightly lower diol concentrations.
 
Literatur
1.
Suber L, Sondi I, Matijevic E, Goia D (2005) Preparation and the mechanisms of formation of silver particles of different morphologies in homogeneous solutions. J Colloid Interface Sci 288:489–495CrossRef
2.
Y S, Xia Y (2002) Shape-controlled synthesis of gold and silver nanoparticles. Science 298:2176–2179CrossRef
3.
Manna L, Scher EC, Alivisatos AP (2000) Synthesis of soluble and processable rod-, arrow-, teardrop-, and tetrapod-shaped C d S e nanocrystals. J Amer Chem Soci 122:12, 700–12,706CrossRef
4.
Dirksen JA, Benjelloun S, Ring TA (1990) Modelling the precipitation of copper oxalate aggregates. Colloid and Polymer Science, pp 864–876
5.
Kawahashi N, Matijevic E (1991) Preparation of hollow spherical particles of yttrium compounds. Journal of Colloid and Interface Society, pp 103–110
6.
Garcia-Ruiz JM, Hyde ST, Carnerup AM, Christy AG, Van Kranendonk MJ, Welham NJ (2003) Self-assembled silica-carbonate structures and detection of ancient microfossils. Science 302:1194–1197
7.
Peng Y, Xu AW, Deng B, Antonietti M, Cölfen H (2006) Polymer-controlled crystallisation of zinc oxide hexagonal nanorings and disks. J Phys Chem B 110:2988–2993CrossRef
8.
Sand KK, Rodriguez-Blanco JD, Makovicky E, BL G, Stipp SLS (2012) Crystallization of C a C O 3 in water alcohol mixtures spherulitic growth, polymorph stabilization, and morphology change. Cristal Growth and Design, pp 842–853
9.
Lui W, Feng L, Zhang C, Yang H, Guo J, Liu X, Zhang X, Yang Y (2013) A facile hydrothermal synthesis of 3d flowerlike C e O 2 via a cerium oxalate precursor. Phys Sci Chem 1:6942–6948
10.
John MV, Ittyachen MA (1998) Studies on C e 2(C 2 O 4)3.n H 2 O crystals grown in hydro-silica gel. Bullet Mater Sci 21(5):387– 391CrossRef
11.
Validya S, Ahmed J, Ganguli AK (2008) Controlled synthesis of nanomaterials using reverse micelles. Defence Science Journal, pp 531–544
12.
Validya S, Ahmad T, Agarwal S, Ganguli AK (2007) Nanocrystalline oxalate/carbonate precursors of ce and zr and their decompositions to ceo 2 and zro 2 nanoparticles. Journal of Americain Ceramic Society, pp 863–869
13.
Bumajdad A, Eastoe J, Mathew A (2009) Cerium oxide nanoparticles prepared in self-assembled systems. Advances in Colloid and Interface Science, pp 56–66
14.
Schoettl S, Marcus J, Diat O, Touraud D, Kunz W, Zemb T, Horinek D (2014) Emergence of surfactant-free micelles from ternary solutions. Chem Sci 5(8):2949–2954CrossRef
15.
Kunz W, Holmberg K, Zemb T (2016) Hydrotropes. Current Opinion in Colloid and Interface Science, pp 99–107
16.
Robertson AE, Phan DH, Macaluso JE, Kuryakov VN, Jouravleva VE, Bertrand CE, Yudin IK, Anisimov MA (2016) Mesoscale solubilization and critical phenomena in binary and quasi-binary solutions of hydrotropes. Fluid Phase Equilibria, pp 243– 254
17.
Diat O, Klossek ML, Touraud D, Deme B, Grillo I, Kunz W, Zemb T (2013) Octanol-rich and water-rich domains in dynamic equilibrium in the pre-ouzo region of ternary systems containing a hydrotrope. Journal of applied Crystallography, pp 1665–1669
18.
Tanford C (1980) The Hydrophobic Effect: Formation of Micelles and biological Membranes. Wiley
19.
Khmelnitsky YH, van Hoek A, Veeger C, Visser AJWG (1989) Detergentless microemulsions as media for enzymatic reactions. spectroscopic and ultracentrifugation studies. J Phys Chem 93:872–878
20.
Zemb T, Klossek M, Lopian T, Marcus J, Schoetti S, Horinek D, Prevost S, Tourraud D, Diat O, Marcelja S, Kunz W (2016) How to explain microemulsions formed by solvent mixtures without conventional surfactants. Proc Natl Acad Sci 113:4260– 4265CrossRef
21.
Zemb T, Kunz W (2016) Weak aggregation: State of the art, expectations and open questions. Current Opinion in Colloid and Interface Science, pp 113–119
22.
Schoettl S, Marcus J, Diat O, Touraud D, Kunz W, Zemb T, Horinek D (2014) Emergence of surfactant-free micelles from ternary solutions. Chem Sci 5:2949–2954CrossRef
23.
Subramanian D, Boughter TB, Klauda JB, Hammouda B, Anisimov MA (2013) Mesoscale inhomogeneities in aqueous solutions of small amphiphilic molecules. Faraday Discussion, pp 217–238
24.
Lopian T, Schöttl S, Prèvost S, Pellet-Rostaing S, Horinek D, Kunz W, Zemb T (2016) Morphologies observed in ultraflexible microemulsions with and without the presence of a strong acid. ACS Cent Sci 2:467–475CrossRef
25.
Kononov LO (2015) Chemical reactivity and solution structure: on the way to a paradigm shift. The Royal Society of Chemistry pp pp 46,718–46,734
26.
Jehannin M, Charton S, Karpitschka S, Zemb T, Möhwald H, Riegler H (2015) Periodic precipitation patterns during coalescence of reacting sessile droplets. Langmuir 31:11,484– 11,490CrossRef
27.
Karpitschka S, Riegler H (2010) Quantitative experimental study on the transition between fast and delayed coalescence of sessile droplets with different but completely miscible liquids. Langmuir 26:11,823–11,829CrossRef
28.
Karpitschka S, Riegler H (2012) Noncoalescence of sessile drops from different but miscible liquids: Hydrodynamic analysis of the twin drop contour as a self-stabilizing traveling wave. Phys Rev Lett 109:066,103CrossRef
29.
Karpitschka S, Riegler H (2014) Sharp transition between coalescence and non-coalescence of sessile drops. Journal of Fluid Mechanic, pp 734
30.
Karpitschka S, Hanske C, Fery A, Riegler H (2014) Coalescence and noncoalescence of sessile drops: Impact of surface forces. Langmuir 30:6826–6830CrossRef
31.
Matijević E, Hsu WP (1987) Preparation and properties of monodispersed colloidal particles of lanthanide compounds: I. gadolinium, europium, terbium, samarium, and cerium (iii). J Colloid Interface Sci 118(2):506–523CrossRef
32.
Cambedouzou J, Diat O (2012) Quantitative small-angle scattering on mesoporous silica powders:from morphological features to specific surface estimation. Journal of Applied Crystallography, pp 662–673
33.
Onuki A, Yabunaka S, Araki T, Okamoto R (2016) Structure formation due to antagonistic salts. Current Opinion in Colloid andamp; Interface Science, pp 59–64
34.
Marcus J, Touraud D, Prev́ost S, Diat O, Zemb T, Kunz W (2015) Influence of additives on the structure of surfactant-free microemulsions. Phys Chem Chem Phys pp 32,528–32,538
35.
Ollendorf W, Weigel F (1969) The crystal structure of some lanthanide oxalate decahydrates, ln2(c2o4)3Â10h2o, with ln = la, ce, pr, and nd. Inorg Nuclear Chem Lett 5:263–269CrossRef
36.
Mann S, Heywood BR, Rajam S, Birchall JD (1988) Modelling the precipitation of copper oxalate aggregates. Nature, pp 864– 876
37.
Rock ML, Tranchitella LJ, Pilato RS (1997) Control of calcium carbonate particle size and shape by precipitation from ctab/alcohol/hexadecane mixture. Colloid and Polymer Science, pp 893–896
38.
Yabunaka S, Okamoto R, Onuki A (2015) Hydrodynamics in bridging and aggregation of two colloidal particles in a near-critical binary mixture. Soft Matter 11(28):5738–5747CrossRef
39.
Bossler F, Koos E (2016) Structure of particle networks in capillary suspensions with wetting and nonwetting fluids. Langmuir, pp 1489–1501
40.
Rossetti D, Simons SJR (2003) A microscale investigation of liquid bridges in the spherical agglomeration process. Powder Technology, pp 49–55
41.
Chen Y, Wetzel T, Aranovich GL, Donohue MD (2006) Generalization of kelvin s equation for compressible liquids in nanoconfinement. Journal of Colloid and Interface Science, pp 45–51
42.
Gögelein C, Brinkmann M, Schröter M, Herminghaus S (2010) Controlling the formation of capillary bridges in binary liquid mixtures. Langmuir 26(22):17,184–17,189CrossRef
43.
Butt HJ (2009) Normal capillary forces. Adv Colloid Interface Sci 146(1):48–60CrossRef
44.
Olsson M, Joabsson F, Piculell L (2004) Particle-induced phase separation in quasi-binary polymer solutions. Langmuir 20(5):1605–1610CrossRef
45.
Olsson M, Joabsson F, Piculell L (2005) Particle-induced phase separation in mixed polymer solutions. Langmuir 21(4):1560–1567CrossRef
46.
Wennerström H, Thuresson K, Linse P, Freyssingeas E (1998) Long range attractive surface forces due to capillary-induced polymer incompatibility. Langmuir 14(20):5664–5666CrossRef
Metadaten
Titel
Structured solvent effects on precipitation
Microscopically organized cerium oxalate particles
verfasst von
Marie Jehannin
Sophie Charton
Bruno Corso
Helmuth Möhwald
Hans Riegler
Thomas Zemb
Publikationsdatum
24.07.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 10/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4153-2

Weitere Artikel der Ausgabe 10/2017

Colloid and Polymer Science 10/2017 Zur Ausgabe

Short Communication

On the similarity between the electrophoresis of a liquid drop and a spherical hydrophobic particle

Original Contribution

Radical polymerization of capillary bridges between micron-sized particles in liquid bulk phase as a low-temperature route to produce porous solid materials

Original Contribution

Preparation and characterization of antibacterial mesoporous sieves with N-halamine

Original Contribution

Magnetite/poly(D,L-lactide-co-glycolide) and hydroxyapatite/poly(D,L-lactide-co-glycolide) prepared by w/o/w emulsion technique for drug carrier: physical characteristic of composite nanoparticles

Original Contribution

Functionalized acetoacetylated poly(vinyl alcohol) monoliths for enzyme immobilization: a phase separation method

Original Contribution

Mechanochemical synthesis of chloroapatite and its characterization by powder X-ray diffractometory and attenuated total reflection-infrared spectroscopy

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise