nach oben

Erschienen in:

01.02.2013 | Original Paper

Novel electrospun luminescent nanofibers from cationic polyfluorene/cellulose acetate blend

verfasst von: Rebeca Vázquez-Guilló, Alex Calero, Artur J. M. Valente, Hugh D. Burrows, C. Reyes Mateo, Ricardo Mallavia

Erschienen in: Cellulose | Ausgabe 1/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

This work reports production of nanofibers of cellulose acetate (CA) via electrospinning (ES) technology. Optimal operating conditions to produce nanofibers have been found to involve CA solutions at 20 wt% concentration, flow rate 1.0 mL h⁻¹, a distance between needle tip-collector target of 15 cm and an applied voltage at 20 kV. Under these experimental conditions, nanofibers were produced by ES a solution containing a low concentration of a luminescent fluorene-based cationic conjugated polyelectrolyte. Electronic and optical microscopies were used to characterize their morphology and the diameter of fibers (over 260 nm). Composite fibers with excellent luminescence properties have been obtained and studied in the solid state. Potential applications in a sensing device for nitrobenzene have been tested.

Vorheriger Artikel The transparency and mechanical properties of cellulose acetate nanocomposites using cellulose nanowhiskers as fillers

Nächster Artikel Hydrophobic modification of cellulose nanocrystal via covalently grafting of castor oil

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Agarwal S, Wendorff JH, Greiner A (2008) Use of electrospinning technique for biomedical applications. Polymer 49:5603–5621. doi:https://doi.org/10.1016/j.polymer.2008.09.014 CrossRef

Cerqueira D, Valente AJM, Filho GR, Burrows HD (2009) Synthesis and properties of polyaniline–cellulose acetate blends: the use of sugarcane bagasse waste and the effect of the substitution degree. Carbohydr Polym 78:402–408. doi:https://doi.org/10.1016/j.carbpol.2009.04.016 CrossRef

Chen L, Bromberg L, Hatton TA, Rutledge GC (2008) Electrospun cellulose acetate fibers containing chlorohexidine as a bactericide. Polymer 49:1266–1275. doi:https://doi.org/10.1016/j.polymer.2008.01.003 CrossRef

Christoforou T, Doumanidis C (2010) Biodegradable cellulose acetate nanofiber fabrication via electrospinning. J Nanosci Nanotechnol 10:6226–6233. doi:https://doi.org/10.1166/jnn.2010.2585 CrossRef

Du P, Song L, Xiong J, Xi Z, Jin D, Wang L (2011) Preparation and the luminescent properties of Tb3+-doped Gd2O3 fluorescent nanofibers via electrospinning. Nanotechnology 22:035602/1–035602/5. doi:https://doi.org/10.1088/0957-4484/22/3/035602

Frey MW (2008) Electrospinning cellulose and cellulose derivatives. Polym Rev 48:378–391. doi:https://doi.org/10.1080/15583720802022281 CrossRef

Froehlich E, Mandeville JS, Jennings CJ, Sedaghat-Herati R, Tajmir-Riahi HA (2009) Dendrimers bind human serum albumin. J Phys Chem B 113:6986–6993. doi:https://doi.org/10.1021/jp9011119 CrossRef

Grimsdale AC, Chan KL, Martin RE, Jokisz PG, Holmes AB (2009) Synthesis of light-emitting conjugated polymers for applications in electroluminescent devices. Chem Rev 109:897–1091. doi:https://doi.org/10.1021/cr000013v CrossRef

Gupta P, Elkins C, Long TE, Wilkes GL (2005) Electrospinning of linear homopolymers of poly (methyl methacrylate): exploring relationships between fiber formation, viscosity, molecular weight and concentration in a good solvent. Polymer 46:4799–4810. doi:https://doi.org/10.1016/j.polymer.2005.04.021 CrossRef

Hou Z, Li G, Lian H, Lin J (2012) One-dimensional luminescent materials derived from the electrospinning process: preparation, characteristics and application. J Mater Chem 22:5254–5276. doi:https://doi.org/10.1039/C2JM15638E CrossRef

Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol 63:2223–2253. doi:https://doi.org/10.1016/S0266-3538(03)00178-7 CrossRef

Huang C, Soenen SJ, Van Gulck E, Vanham G, Rejman J, Van Calenbergh S, Vervaet C, Coenye T, Verstraelen H, Temmerman M, Demeester J, De Smedt SC (2012) Electrospun cellulose acetate phthalate fibers for semen induced anti-HIV vaginal drug delivery. Biomaterials 33:962–969. doi:https://doi.org/10.1016/j.biomaterials.2011.10.004 CrossRef

Kim D-H, Lu N, Ma R, Wang S (2011) Epidermal electronics. Science 333:838–843. doi:https://doi.org/10.1126/science.1206157 CrossRef

Liu B, Bazan GC (2004) Homogeneous fluorescence-based DNA detection with water-soluble conjugated polymers. Chem Mater 16:4467–4476. doi:https://doi.org/10.1021/cm049587x CrossRef

Liu HQ, Hsieh YL (2002) Ultrafine fibrous cellulose membranes from electrospinning of cellulose acetate. J Polym Sci Part B Polym Phys 40:2119–2129. doi:https://doi.org/10.1002/polb.10261 CrossRef

Liu R, Ye H, Xiong X, Liu H (2010) Fabrication of TiO2/ZnO composite nanofibers by electrospinning and their photocatalytic property. Mater Chem Phys 121:432–439. doi:https://doi.org/10.1016/j.matchemphys.2010.02.002 CrossRef

Ma Z, Ramakrishna S (2008) Electrospun regenerated cellulose nanofiber affinity membrane functionalized with protein A/G for IgG purification. J Membr Sci 319:23–28. doi:https://doi.org/10.1016/j.memsci.2008.03.045 CrossRef

Mallavia R, Martinez-Pérez D, Chmelka BF, Bazán GC (2004) Películas fluorescentes azules basadas en derivados de poli-2,7-fluorenofenilideno. Bol Soc Esp Ceram 43:327–330. doi:https://doi.org/10.3989/cyv.2004.v43.i2.532 CrossRef

Maretschek S, Greiner A, Kissel T (2008) Electrospun biodegradable nanofiber nonwovens for controlled release of proteins. J Control Release 127:180–187. doi:https://doi.org/10.1016/j.jconrel.2008.01.011 CrossRef

Martinez-Tome MJ, Esquembre R, Mallavia R, Mateo CR (2010) Formation of complexes between the conjugated polyelectrolyte poly{[9,9-bis(6’-N, N, N trimethylammonium) hexyl]fluorene-phenylene} bromide (HTMA-PFP) and human serum albumin. Biomacromolecules 11:1494–1501. doi:https://doi.org/10.1021/bm100123t CrossRef

Neher D (2001) Polyfluorene homopolymers: conjugated liquid-crystalline polymers for bright blue emission and polarized electroluminescence. Macromol Rapid Commun 22:1365–1385CrossRef

Puls J, Wilson SA, Holter D (2011) Degradation of cellulose acetate-based materials: a review. J Polym Environ 19:152–165. doi:https://doi.org/10.1007/s10924-010-0258-0 CrossRef

Ramakrishna S, Ma Z (2005) An introduction to electrospinning and nanofibers. Electrospinning process, 1st edn. World Scientific, Singapore, pp 90–154CrossRef

Rußler A, Sakakibara K, Rosenau T (2011) Cellulose as matrix component of conducting films cellulose as matrix component of conducting films. Cellulose 18:937–944. doi:https://doi.org/10.1007/s10570-011-9555-6 CrossRef

Schiffman JD, Schauer CL (2008) A review: electrospinning of Biopolymer nanofibers and their applications. Polym Rev 48:317–352. doi:https://doi.org/10.1080/15583720802022182 CrossRef

Stankus JJ, Freytes DO, Badylak SF, Wagner WR (2008) Hybrids nanofibrous scaffolds from electrospinning of a synthetic biodegradable elastomer and urinary bladder matrix. J Biomater Sci Polym 19:635–652. doi:https://doi.org/10.1163/156856208784089599 CrossRef

Tapia MJ, Montserín M, Valente AJM, Burrows HD, Mallavia R (2010) Binding of polynucleotides to conjugated polyelectrolytes and its applications in sensing. Adv Colloid Interface Sci 158:94–107. doi:https://doi.org/10.1016/j.cis.2009.09.001 CrossRef

Thomas SW, Joly GD, Swager TM (2007) Chemical sensors based on amplifying fluorescent conjugated polymers. Chem Rev 107:1339–1386. doi:https://doi.org/10.1021/cr0501339 CrossRef

Tungprapa S, Hangchud I, Supaphol P (2007) Release characteristics of four model drugs from drug-loaded electrospun cellulose acetate fibers mats. Polymer 48:5030–5041. doi:https://doi.org/10.1016/j.polymer.2007.06.061 CrossRef

Valente AJM, Burrows HD, Gomes JNPL, Pereira RFP, Cerqueira D, Jiménez A, Burgos N, Morán C, Mallavia R, Filho GR (2012) Cellulose acetate-poly{[9,9-bis(6’-N, N, N-tri-methylammonium)hexyl]fluorene-phenylene} bromide blends: preparation, characterization and transport properties. React Funct Polym 72:420–426. doi:https://doi.org/10.1016/j.reactfunctpolym.2012.03.014 CrossRef

Wang Y, Hsieh Y (2004) Enzyme immobilization to ultra-fine cellulose fibers via amphiphilic polyethylene glycol spacers. J Polym Sci Polym Chem 42:4289–4299. doi:https://doi.org/10.1002/pola.20271 CrossRef

Wang W, Li Y, Sun M, Zhou Ch, Zhang Y, Li Y, Yang Q (2012) Colorimetric and fluorescent nanofibrous film as a chemosensor for Hg2+ in aqueous solution prepared by electrospinning and host-guest interaction. Chem Commun 48:6040–6042. doi:https://doi.org/10.1039/C2CC17664E CrossRef

Yang Y, Fan X, Long Y, Su K, Zou D, Li N, Zhou J, Li K, Liu F (2009) A simple fabrication of electrospun nanofiber sensing materials based on fluorophore-doped polymer. J Mater Chem 19:7290–7295. doi:https://doi.org/10.1039/B908154B CrossRef

Yang Y, Turnbull GA, Samuel IDW (2010) Sensitive explosive vapor detection with polyfluorene lasers. Adv Funct Mater 20:2093–2097. doi:https://doi.org/10.1002/adfm.200901904 CrossRef

Titel: Novel electrospun luminescent nanofibers from cationic polyfluorene/cellulose acetate blend
verfasst von: Rebeca Vázquez-Guilló
Alex Calero
Artur J. M. Valente
Hugh D. Burrows
C. Reyes Mateo
Ricardo Mallavia
Publikationsdatum: 01.02.2013
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-012-9809-y

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 1/2013

Quantum mechanical modeling of the structures, energetics and spectral properties of Iα and Iβ cellulose

Moleular simulation of surface reorganization and wetting in crystalline cellulose I and II

Hemostatic efficacy and tissue reaction of oxidized regenerated cellulose hemostats

Thermomechanical and crystallization behavior of polylactide-based flax fiber biocomposites

Synthesis and characterization of cyanoethyl hemicelluloses and their hydrated products

Photo-attaching functional polymers to cellulose fibers for the design of chemically modified paper