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01.04.2015 | Original Paper

Utilization of various lignocellulosic biomass for the production of nanocellulose: a comparative study

verfasst von: B. Deepa, Eldho Abraham, Nereida Cordeiro, Miran Mozetic, Aji P. Mathew, Kristiina Oksman, Marisa Faria, Sabu Thomas, Laly A. Pothan

Erschienen in: Cellulose | Ausgabe 2/2015

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Abstract

Nanocellulose was successfully extracted from five different lignocellulosic biomass sources viz. banana rachis, sisal, kapok, pineapple leaf and coir using a combination of chemical treatments such as alkaline treatment, bleaching and acid hydrolysis. The shape, size and surface properties of the nanocellulose generally depend on the source and hydrolysis conditions. A comparative study of the fundamental properties of raw material, bleached and nanocellulose was carried out by means of Fourier transform infrared spectroscopy, scanning electron microscopy, atomic force microscopy, transmission electron microscopy, birefringence, X-ray diffraction, inverse gas chromatography and thermogravimetric analysis. Through the characterization of the nanocellulose obtained from different sources, the isolated nanocellulose showed an average diameter in the range of 10–25 nm, high crystallinity, high thermal stability and a great potential to be used with acid coupling agents due to a predominantly basic surface. This work provides an insight into the effective utilization of a variety of plant biomass as a potential source for nanocellulose extraction.

Vorheriger Artikel Surface characteristics of cellulose nanoparticles grafted by surface-initiated ring-opening polymerization of ε-caprolactone

Nächster Artikel Self-assembled optically transparent cellulose nanofibril films: effect of nanofibril morphology and drying procedure

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Abdul Khalil HPS, Davoudpour Y, Islam MN, Mustapha A, Sudesh K, Dungani R, Jawaid M (2014) Production and modification of nanofibrillated cellulose using various mechanical processes: a rewiew. Carbohydr Polym 99:649–665CrossRef

Abraham E, Deepa B, Pothan LA, Jacob M, Thomas S, Anandjiwala R (2011) Extraction of nanocellulose fibrils from lignocellulosic fibers: a novel approach. Carbohydr Polym 86:1468–1475CrossRef

Alemdar A, Sain M (2008) Isolation and characterization of nanofibers from agricultural residues—wheat straw and soy hulls. Bioresour Technol 99:1664–1671CrossRef

Chakraborty A, Sain M, Kortschot M (2005) Cellulose microfibrils: a novel method of preparation using high shear refining and cryocrushing. Holzforschung 59:102–107CrossRef

Chen WS, Yu HP, Liu YX, Chen P, Zhang MX, Hai YF (2011) Individualization of cellulose nanofibers from wood using high-intensity ultrasonication combined with chemical pretreatments. Carbohydr Polym 83:1804–1811CrossRef

Chirayil CJ, Joy J, Mathew L, Mozetic M, Koetz J, Thomas S (2014) Isolation and characterization of cellulose nanofibrils from Helicteresisora plant. Ind Crop Prod 59:27–34CrossRef

Cordeiro N, Gouveia C, Moraes AGO, Amico SC (2011) Natural fibers characterization by inverse gas chromatography. Carbohydr Polym 84:110–117CrossRef

Cordeiro N, Mendonça C, Pothan LA, Varma A (2012) Monitoring surface properties evolution of thermochemically modified cellulose nanofibers from banana pseudo-stem. Carbohydr Polym 88:125–131CrossRef

Das K, Ray D, Bandyopadhyay NR, Sahoo S, Mohanty AK, Misra M (2011) Physicomechanical properties of the jute micro/nanofibril reinforced starch/polyvinyl alcohol biocomposite films. Compos Part B 42:376–381CrossRef

Deng H, Zhou X, Wang X, Zhang C, Ding B, Zhang Q, Du Y (2010) Layer-by layer structured polysaccharides film-coated cellulose nanofibrous mats for cell culture. Carbohydr Polym 80:475–480CrossRef

Eichhorn SJ (2011) Cellulose nanowhiskers: promising materials for advanced applications. Soft Matter 7:303–315CrossRef

Ferrer A, Filpponen I, Rodríguez A, Laine J, Rojas OJ (2012) Valorization of residual Empty Palm Fruit Bunch Fibers (EPFBF) by microfluidization: production of nanofibrillated cellulose and EPFBF nanopaper. Bioresour Technol 125:249–255CrossRef

Fortunati E, Puglia D, Monti M, Peponi L, Santulli C, Kenny JM, Torre L (2013) Extraction of cellulose nanocrystals from phormium tenax fibers. J Polym Environ 21:319–328CrossRef

Fukuzumi H, Saito T, Isogai A (2013) Influence of TEMPO-oxidized cellulose nanofibril length on film properties. Carbohydr Polym 93:172–177CrossRef

Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110:3479–3500CrossRef

Hossain KMZ, Hasan MS, Boyd D, Rudd CD, Ahmed I, Thielemans W (2014) Effect of cellulose nanowhiskers on surface morphology, mechanical properties, and cell adhesion of melt-drawn polylactic acid fibers. Biomacromolecules 15:1498–1506CrossRef

Isogai T, Saito T, Isogai A (2011) Wood cellulose nanofibrils prepared by TEMPO electro-mediated oxidation. Cellulose 18:421–431CrossRef

Jiang F, Hsieh Y-L (2013) Chemically and mechanically isolated nanocellulose and their self-assembled structures. Carbohydr Polym 95:32–40CrossRef

Jiang F, Han S, Hsieh Y-L (2013) Controlled defibrillation of rice straw cellulose and self-assembly of cellulose nanofibrils into highly crystalline fibrous materials. RSC Adv 3:12366–12375CrossRef

Kaushik A, Singh M (2011) Isolation and characterization of cellulose nanofibrils from wheat straw using steam explosion coupled with high shear homogenization. Carbohydr Res 346:76–85CrossRef

Kengkhetkit N, Amornsakchai T (2014) A new approach to “Greening” plastic composites using pineapple leaf waste for performance and cost effectiveness. Mater Des 55:292–299CrossRef

Klemm D, Kramer F, Moritz S, Lindstrom T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50:5438–5466CrossRef

Kumar A, Negi YS, Choudhary V, Bhardwaj NK (2014) Characterization of cellulose nanocrystals produced by acid-hydrolysis from sugarcane bagasse as agro-waste. J Mater Phys Chem 2:1–8

Lin J, Tian F, Zhao N, Li X, Bian F, Wang J (2014) Cellulose nanofibrils aerogels generated from jute fibers. Carbohydr Polym 109:35–43CrossRef

Maiti S, Jayaramudu J, Das K, Reddy SM, Sadiku R, Ray SS, Liu D (2013) Preparation and characterization of nano-cellulose with new shape from different precursor. Carbohyd Polym 98:562–567CrossRef

Mandal A, Chakrabarty D (2011) Isolation of nanocellulose from waste sugarcane bagasse (SCB) and its characterization. Carbohydr Polym 86:1291–1299CrossRef

Mathew AP, Oksman K, Karim Z, Liu P, Khan SA, Naseri N (2014) Process scale up and characterization of wood cellulose nanocrystals hydrolysed using bioethanol pilot plant. Ind Crop Prod 58:212–219CrossRef

Missoum K, Belgacem M, Bras J (2013) Nanofibrillated cellulose surface modification: a review. Materials 6:1745–1766CrossRef

Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40:3941–3994CrossRef

Moran JI, Alvarez VA, Cyras VP, Vazquez A (2008) Extraction of cellulose and preparation of nanocellulose from sisal fibers. Cellulose 15:149–159CrossRef

Nakagaito AN, Yano H (2004) The effect of morphological changes from pulp fiber towards nano-scale fibrillated cellulose on the mechanical properties of high strength plant fiber based composites. Appl Phys A Mater 78:547–552CrossRef

Nishiyama Y, Sugiyama J, Chanzy H, Langan P (2003) Crystal structure and hydrogen bonding system in cellulose Iα from synchrotron X-ray and neutron fiber diffraction. J Am Chem Soc 125:14300–14306CrossRef

Panthapulakkal S, Sain M (2012) Preparation and characterization of cellulose nanofibril films from wood fiber and their thermoplastic polycarbonate composites. Int J Polym Sci 2012:1–6CrossRef

Sacui IA, Nieuwendaal RC, Burnett DJ, Stranick SJ, Jorfi M, Weder C, Foster EJ, Olsson RT, Gilman JW (2014) Comparison of the properties of cellulose nanocrystals and cellulose nanofibrils isolated from bacteria, tunicate, and wood processed using acid, enzymatic, mechanical, and oxidative methods. ACS Appl Mater Interfaces 6:6127–6138CrossRef

Sain M, Panthapulakkal S (2006) Bioprocess preparation of wheat straw fibers and their characterization. Ind Crop Prod 23:1–8CrossRef

Saito T, Uematsu T, Kimura S, Enomae T, Isogai A (2011) Self-aligned integration of native cellulose nanofibrils towards producing diverse bulk materials. Soft Matter 7:8804–8809CrossRef

Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef

Silvério HA, Flauzino Neto WP, Dantas NO, Pasquini D (2013) Extraction and characterization of cellulose nanocrystals from corncob for application as reinforcing agent in nanocomposites. Ind Crop Prod 44:427–436CrossRef

Stenstad P, Andresen M, Tanem BS, Stenius P (2008) Chemical surface modification of microfibrillated cellulose. Cellulose 15:35–45CrossRef

Wang QQ, Zhu JY, Gleisner R, Kuster TA, Baxa U, McNeil SE (2012) Morphological development of cellulose fbrils of a bleached eucalyptus pulp by mechanical fibrillation. Cellulose 19:1631–1643CrossRef

Wicklein B, Salazar-Alvarez G (2013) Functional hybrids based on biogenic nanofibrils and inorganic nanomaterials. J Mater Chem A 1:5469–5478CrossRef

Xu X, Liu F, Jiang L, Zhu JY, Haagenson D, Wiesenborn DP (2013) Cellulose nanocrystals vs cellulose nanofibrils: a comparative study on their microstructures and effects as polymer reinforcing agents. ACS Appl Mater Interfaces 5:2999–3009CrossRef

Titel: Utilization of various lignocellulosic biomass for the production of nanocellulose: a comparative study
verfasst von: B. Deepa
Eldho Abraham
Nereida Cordeiro
Miran Mozetic
Aji P. Mathew
Kristiina Oksman
Marisa Faria
Sabu Thomas
Laly A. Pothan
Publikationsdatum: 01.04.2015
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2015
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-015-0554-x

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