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19.02.2018 | Original Paper

Freeze-drying of oxidized corn starch: electrochemical synthesis and characterization

verfasst von: Xugang Dang, Hui Chen, Yajuan Wang, Zhihua Shan

Erschienen in: Cellulose | Ausgabe 4/2018

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Abstract

Oxidized corn starch (OCS) was successfully synthesized by electrochemical oxidation in aqueous solution of sodium chloride, and freeze-drying technology was also used for the post-processing of the prepared OCS. The synthesized OCS solutions were analyzed by viscosity measurement and UV–vis spectroscopies. The OCS samples were characterized by the determination of amylose and amylopectin contents, carboxyl and carbonyl groups contents, FT-IR, XRD, SEM and ¹³C-NMR. The analyses revealed that the viscosity of OCS solutions decreased with increasing current. The determination and characterization results indicated that the amylopectin decreased gradually, while the carboxyl and carbonyl groups contents of OCS increased by electro-oxidation. The introduction of carboxyl and carbonyl groups promoted OCS hydration and swelling. After electro-oxidation, the crystallinity of the OCS decreased, and the surface formed a loose and porous structure. The electro-oxidation was able to selectively oxidize the hydroxyl groups of the C-2, C-3, and C-6 positions by adjusting the current.

Vorheriger Artikel Dependence of dissolution, dispersion, and aggregation characteristics of cationic polysaccharides made from euglenoid β-1,3-glucan on degree of substitution

Nächster Artikel High-yield production of 5-hydroxymethylfurfural from d-fructose, d-glucose, and cellulose by its in situ removal from the reaction system

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Titel: Freeze-drying of oxidized corn starch: electrochemical synthesis and characterization
verfasst von: Xugang Dang
Hui Chen
Yajuan Wang
Zhihua Shan
Publikationsdatum: 19.02.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1701-y

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