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13.09.2019 | Original Research

Synthesis of a formaldehyde-free flame retardant for cotton fabric

verfasst von: Peixiu Tian, Mingsheng Liu, Caiyan Wan, Guangxian Zhang, Fengxiu Zhang

Erschienen in: Cellulose | Ausgabe 18/2019

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Abstract

A flame retardant ammonium salt of diethylene glycol phosphonate (ADGP) is synthesized using low-cost materials (diethylene glycol, phosphoric acid, and urea). The flame retardant is grafted on the cotton fabrics via P–O–C covalent bonds. The structure of the flame retardant is characterized by nuclear magnetic resonance (NMR) and Fourier transform infrared (FT-IR). The combustion performance of the treated and untreated cotton fabrics is evaluated based on vertical flammability, limiting oxygen index (LOI), and cone calorimetry. As the concentration of the flame-retardant ADGP increased, the cotton fabric treated with 40% ADGP exhibited an LOI of 43.7% and superior fire resistance, whereas physiological comfort showed a decrease. Scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction were used to characterize the surface morphology, chemical composition, and crystal structure of the control and treated cotton fabrics. The thermal stability of the treated and untreated cotton fabrics is determined by thermogravimetric analysis. The results indicated that the treated cotton showed superior flame retardancy.

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Vorheriger Artikel Assessing wood pulp reactivity through its rheological behavior under dissolution

Nächster Artikel Cationic starch and polyacrylamides for alkenyl succinic anhydride (ASA) emulsification for sizing of cellulosic fibers

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Titel: Synthesis of a formaldehyde-free flame retardant for cotton fabric
verfasst von: Peixiu Tian
Mingsheng Liu
Caiyan Wan
Guangxian Zhang
Fengxiu Zhang
Publikationsdatum: 13.09.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 18/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02751-z

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