Skip to main content
Erschienen in: Journal of Materials Science 2/2015

01.01.2015 | Original Paper

Thermophysical investigations of exfoliated graphite nanoplatelets and active carbon in binary aqueous environments at different temperatures

verfasst von: Ion Ion, Florinela Sirbu, Alina Catrinel Ion

Erschienen in: Journal of Materials Science | Ausgabe 2/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Thermophysical investigations in binary liquid mixtures are important for many technological and environmental applications of exfoliated graphite nanostructures. The densities, speeds of sound, and refractive indices for the binary liquid mixture environments of water + exfoliated graphite nanoplatelets, and water + activated carbon have been measured versus composition, at different temperatures, at atmospheric pressure. The thermophysical properties such as the acoustic impedance, isentropic compressibility, specific refraction, space-filling factor, and relaxation strength have been evaluated over the composition range up to 100 kg m−3, based on the experimental data. The absolute average percentage deviations of the calculated thermophysical properties in both systems were computed. The obtained results are discussed and interpreted in terms of molecular interactions and structural changes of these carbon-based nanomaterials.

Graphical abstract

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Hu Z, Srinivasan M (2009) A simple method for developing mesoporosity in activated carbon. Micropor Mesopor Mater 43:267–275CrossRef Hu Z, Srinivasan M (2009) A simple method for developing mesoporosity in activated carbon. Micropor Mesopor Mater 43:267–275CrossRef
2.
Zurück zum Zitat Belyakova LD, Kiselev AV, Kovaleva NV (1968) Gas-chromotographic determination of isotherms and heats of adsorption of water, benzene and methanol vapours on graphitised carbon black. Rus J Phys Chem 42:1204–1208 Belyakova LD, Kiselev AV, Kovaleva NV (1968) Gas-chromotographic determination of isotherms and heats of adsorption of water, benzene and methanol vapours on graphitised carbon black. Rus J Phys Chem 42:1204–1208
3.
Zurück zum Zitat Van Nguyen T, Do DD, Nicholson D (2014) A new molecular model for water adsorption on graphitized carbon black. Carbon 66:629–636CrossRef Van Nguyen T, Do DD, Nicholson D (2014) A new molecular model for water adsorption on graphitized carbon black. Carbon 66:629–636CrossRef
4.
Zurück zum Zitat Striolo A, Chailvo AA, Cummings PT, Gubbins KE (2003) Water adsorption in carbon-slit nanopores. Langmuir 19:8583–8591CrossRef Striolo A, Chailvo AA, Cummings PT, Gubbins KE (2003) Water adsorption in carbon-slit nanopores. Langmuir 19:8583–8591CrossRef
5.
Zurück zum Zitat Liu JC, Monson PA (2005) Does water condense in carbon pores? Langmuir 21:10219–10225CrossRef Liu JC, Monson PA (2005) Does water condense in carbon pores? Langmuir 21:10219–10225CrossRef
6.
Zurück zum Zitat Nguyen TX, Bhatia SK (2011) How water adsorbs in hydrophobic nanospaces. J Phys Chem C 115:16606–16612CrossRef Nguyen TX, Bhatia SK (2011) How water adsorbs in hydrophobic nanospaces. J Phys Chem C 115:16606–16612CrossRef
7.
Zurück zum Zitat Birkett G, Do DD (2007) Simulation study of water adsorption on carbon black: the effect of graphite water interaction strength. J Phys Chem C 111:5735–5742CrossRef Birkett G, Do DD (2007) Simulation study of water adsorption on carbon black: the effect of graphite water interaction strength. J Phys Chem C 111:5735–5742CrossRef
8.
Zurück zum Zitat Liu JC, Monson PA (2006) Monte Carlo simulation study of water adsorption in activated carbon. Ind Eng Chem Res 45:5649–5656CrossRef Liu JC, Monson PA (2006) Monte Carlo simulation study of water adsorption in activated carbon. Ind Eng Chem Res 45:5649–5656CrossRef
9.
Zurück zum Zitat Schedin F, Geim AK, Morozov SV, Hill EW, Blake P, Katsnelson MI, Novoselov KS (2007) Detection of individual gas molecules adsorbed on graphene. Nat Mater 6:652–655CrossRef Schedin F, Geim AK, Morozov SV, Hill EW, Blake P, Katsnelson MI, Novoselov KS (2007) Detection of individual gas molecules adsorbed on graphene. Nat Mater 6:652–655CrossRef
10.
11.
Zurück zum Zitat Slonczewski JC, Weiss PR (1958) Band structure of graphite. Phys Rev 109:272–279CrossRef Slonczewski JC, Weiss PR (1958) Band structure of graphite. Phys Rev 109:272–279CrossRef
12.
Zurück zum Zitat Park S, Ruoff RS (2009) Chemical methods for the production of graphenes. Nat Nanotechnol 4:217–224CrossRef Park S, Ruoff RS (2009) Chemical methods for the production of graphenes. Nat Nanotechnol 4:217–224CrossRef
13.
Zurück zum Zitat Konios D, Stylianakis MM, Stratakis E, Kymakis E (2014) Dispersion behavior of graphene oxide and reduced graphene oxide. J Colloid Interface Sci 430:102–112 Konios D, Stylianakis MM, Stratakis E, Kymakis E (2014) Dispersion behavior of graphene oxide and reduced graphene oxide. J Colloid Interface Sci 430:102–112
14.
Zurück zum Zitat Ion I, Sirbu F, Ion AC (2013) Density, refractive index, and ultrasound speed in mixtures of active carbon and exfoliated graphite nanoplatelets dispersed in N,N-dimethylformamide at temperatures from (293.15 to 318.15) K. J Chem Eng Data 58:1212–1222CrossRef Ion I, Sirbu F, Ion AC (2013) Density, refractive index, and ultrasound speed in mixtures of active carbon and exfoliated graphite nanoplatelets dispersed in N,N-dimethylformamide at temperatures from (293.15 to 318.15) K. J Chem Eng Data 58:1212–1222CrossRef
15.
Zurück zum Zitat Li X, Li L, Wang Y, Li H, Bian V (2013) Wetting and interfacial properties of water on the defective graphene. J Phys Chem C 117:14106–14112CrossRef Li X, Li L, Wang Y, Li H, Bian V (2013) Wetting and interfacial properties of water on the defective graphene. J Phys Chem C 117:14106–14112CrossRef
16.
Zurück zum Zitat Li H, Zeng XC (2012) Wetting and interfacial properties of water nanodroplets in contact with graphene and monolayer boron-nitride sheets. ACS Nano 6:2401–2409CrossRef Li H, Zeng XC (2012) Wetting and interfacial properties of water nanodroplets in contact with graphene and monolayer boron-nitride sheets. ACS Nano 6:2401–2409CrossRef
17.
Zurück zum Zitat Ion AC, Alpatova A, Ion I, Culetu A (2011) Study on phenol adsorption from aqueous solutions on exfoliated graphitic nanoplatelet. Mat Sci Eng B 176:588–595CrossRef Ion AC, Alpatova A, Ion I, Culetu A (2011) Study on phenol adsorption from aqueous solutions on exfoliated graphitic nanoplatelet. Mat Sci Eng B 176:588–595CrossRef
18.
Zurück zum Zitat Ion AC, Ion I, Culetu A (2011) Lead adsorption onto exfoliated graphitic nanoplatelets in aqueous solutions. Mat Sci Eng B 176:504–509CrossRef Ion AC, Ion I, Culetu A (2011) Lead adsorption onto exfoliated graphitic nanoplatelets in aqueous solutions. Mat Sci Eng B 176:504–509CrossRef
19.
Zurück zum Zitat Li X, Chen G (2009) Surface modified graphite nanosheets used as adsorbent to remove 1,2-dichlorobenzene from water. Mater Lett 63:930–932CrossRef Li X, Chen G (2009) Surface modified graphite nanosheets used as adsorbent to remove 1,2-dichlorobenzene from water. Mater Lett 63:930–932CrossRef
20.
Zurück zum Zitat Li Y, Du Q, Liu T, Sun J, Jiao Y, Xia Y, Xia L, Wang Z, Zhang W, Wang K, Zhu H, Wu D (2012) Equilibrium, kinetic and thermodynamic studies on the adsorption of phenol onto graphene. Mater Res Bull 47:1898–1904CrossRef Li Y, Du Q, Liu T, Sun J, Jiao Y, Xia Y, Xia L, Wang Z, Zhang W, Wang K, Zhu H, Wu D (2012) Equilibrium, kinetic and thermodynamic studies on the adsorption of phenol onto graphene. Mater Res Bull 47:1898–1904CrossRef
21.
Zurück zum Zitat Ding N, Lu X, Wu C-ML (2012) Nitrated tyrosine adsorption on metal-doped graphene: a DFT study. Comp Mater Sci 51:141–145CrossRef Ding N, Lu X, Wu C-ML (2012) Nitrated tyrosine adsorption on metal-doped graphene: a DFT study. Comp Mater Sci 51:141–145CrossRef
22.
Zurück zum Zitat Iulian O, Sirbu F (2005) Prediction of the volumetric properties for aqueous NaCl–KBr and NaCl–CaCl2 mixtures. Rev Roum Chim 50:1027–1034 Iulian O, Sirbu F (2005) Prediction of the volumetric properties for aqueous NaCl–KBr and NaCl–CaCl2 mixtures. Rev Roum Chim 50:1027–1034
23.
Zurück zum Zitat Iulian O, Sirbu F, Stoicescu C (2008) Density and apparent molar volume prediction in some ternary electrolyte solutions. Rev Roum Chim 53:1125–1129 Iulian O, Sirbu F, Stoicescu C (2008) Density and apparent molar volume prediction in some ternary electrolyte solutions. Rev Roum Chim 53:1125–1129
24.
Zurück zum Zitat Stoicescu C, Iulian O, Sirbu F (2008) Liquid + liquid equilibrium data for the ternary mixtures of 1-propanol + water with 1-butanol, 1-hexanol, 1-octanol, or 1-decanol at 294.15 K. Rev Roum Chim 53:1117–1123 Stoicescu C, Iulian O, Sirbu F (2008) Liquid + liquid equilibrium data for the ternary mixtures of 1-propanol + water with 1-butanol, 1-hexanol, 1-octanol, or 1-decanol at 294.15 K. Rev Roum Chim 53:1117–1123
25.
Zurück zum Zitat Sirbu F, Iulian O (2010) Activity coefficients from cell potential measurements in the NaCl + glycine + water ternary system at (298.2, 308.2, and 318.2) K. J Chem Eng Data 55:3853–3858CrossRef Sirbu F, Iulian O (2010) Activity coefficients from cell potential measurements in the NaCl + glycine + water ternary system at (298.2, 308.2, and 318.2) K. J Chem Eng Data 55:3853–3858CrossRef
26.
Zurück zum Zitat Sirbu F, Iulian O, Ion AC, Ion I (2011) Activity coefficients of electrolytes in the NaCl + Na2SO4 + H2O ternary system from potential difference measurements at (298.15, 303.15, and 308.15) K. J Chem Eng Data 56:4935–4943CrossRef Sirbu F, Iulian O, Ion AC, Ion I (2011) Activity coefficients of electrolytes in the NaCl + Na2SO4 + H2O ternary system from potential difference measurements at (298.15, 303.15, and 308.15) K. J Chem Eng Data 56:4935–4943CrossRef
27.
Zurück zum Zitat Roy MN, Chanda R, Ghosh G (2009) Molar volumes viscosity, and isentropic compressibility of some primary monoalkanols in aqueous N,N-dimethylformamide solutions. Russ J Phys Chem A 83:1331–1341CrossRef Roy MN, Chanda R, Ghosh G (2009) Molar volumes viscosity, and isentropic compressibility of some primary monoalkanols in aqueous N,N-dimethylformamide solutions. Russ J Phys Chem A 83:1331–1341CrossRef
28.
Zurück zum Zitat Resa JM, Gonzalez C, Goenaga JM, Iglesias M (2007) Influence of temperature on ultrasonic velocity measurements of ethanol + water + 1-propanol mixtures. J Therm Anal Calorim 87:237–245CrossRef Resa JM, Gonzalez C, Goenaga JM, Iglesias M (2007) Influence of temperature on ultrasonic velocity measurements of ethanol + water + 1-propanol mixtures. J Therm Anal Calorim 87:237–245CrossRef
29.
Zurück zum Zitat Toumi A, Bouanz M (2008) Volumetric and refractive index properties of isobutyric acid–water binary mixtures at temperatures ranging from 300.15 to 313.15 K. J Mol Liq 139:55–60CrossRef Toumi A, Bouanz M (2008) Volumetric and refractive index properties of isobutyric acid–water binary mixtures at temperatures ranging from 300.15 to 313.15 K. J Mol Liq 139:55–60CrossRef
30.
Zurück zum Zitat Sinha A, Roy MN (2006) Studies of viscous antagonism, excess molar volume and isentropic compressibility in aqueous mixed solvent systems at different temperatures. Phys Chem Liq 44:303–314CrossRef Sinha A, Roy MN (2006) Studies of viscous antagonism, excess molar volume and isentropic compressibility in aqueous mixed solvent systems at different temperatures. Phys Chem Liq 44:303–314CrossRef
31.
Zurück zum Zitat Wagner W, Pruss A (2002) The IAPWS Industrial Formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use. J Phys Chem Ref Data 31:387–535CrossRef Wagner W, Pruss A (2002) The IAPWS Industrial Formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use. J Phys Chem Ref Data 31:387–535CrossRef
32.
Zurück zum Zitat Rayer AV, Sumon KZ, Henni A, Tontiwachwuthikul P (2011) Physicochemical properties of 1-methyl piperazine (1) + water (2) system at T = (298.15–343.15) K and atmospheric pressure. J Chem Thermodyn 43:1897–1905CrossRef Rayer AV, Sumon KZ, Henni A, Tontiwachwuthikul P (2011) Physicochemical properties of 1-methyl piperazine (1) + water (2) system at T = (298.15–343.15) K and atmospheric pressure. J Chem Thermodyn 43:1897–1905CrossRef
33.
Zurück zum Zitat Shinde BR, Jadhav SS, Shinde SU, Shengule DR, Jadhav KM (2011) Ion–solvent interactions studies in aqueous manganous chloride solution by ultrasonic velocity measurement at different temperatures. Arch Phy Res 2:107–113 Shinde BR, Jadhav SS, Shinde SU, Shengule DR, Jadhav KM (2011) Ion–solvent interactions studies in aqueous manganous chloride solution by ultrasonic velocity measurement at different temperatures. Arch Phy Res 2:107–113
34.
Zurück zum Zitat Spieweck F, Bettin H (1992) Solid and liquid density determination. Tech Mess 59:285–292CrossRef Spieweck F, Bettin H (1992) Solid and liquid density determination. Tech Mess 59:285–292CrossRef
35.
Zurück zum Zitat Palaiologou MM, Arianas GK, Tsierkezos NG (2006) Thermodynamic investigation of dimethyl sulfoxide binary mixtures at 293.15 and 313.15 K. J Solution Chem 35:1551–1565CrossRef Palaiologou MM, Arianas GK, Tsierkezos NG (2006) Thermodynamic investigation of dimethyl sulfoxide binary mixtures at 293.15 and 313.15 K. J Solution Chem 35:1551–1565CrossRef
36.
Zurück zum Zitat Landolt-Börnstein (1990) Numerical data and functional relationships in science and technology new series, Band V, ed. Springer, Berlin Landolt-Börnstein (1990) Numerical data and functional relationships in science and technology new series, Band V, ed. Springer, Berlin
37.
Zurück zum Zitat Harvey AH, Gallagher JS, Sengers JMHL (1990) Revised formulation for refractive index of water and steam as a function of wavelenght, temperature and density. J Phys Chem Res 27:761–774 Harvey AH, Gallagher JS, Sengers JMHL (1990) Revised formulation for refractive index of water and steam as a function of wavelenght, temperature and density. J Phys Chem Res 27:761–774
38.
Zurück zum Zitat Evaluation of measurement data-guide to the expression of uncertainty in measurement. Report of Working Group 1 of the Joint Committee for Guides in Metrology, 2008 Evaluation of measurement data-guide to the expression of uncertainty in measurement. Report of Working Group 1 of the Joint Committee for Guides in Metrology, 2008
39.
Zurück zum Zitat Gonzalez C, Resa JM, Lanz J, Iglesias M (2006) Intermolecular interactions in soybean oil + different organic solvents by ultrasonic velocity measurements. J Food Eng 77:152–161CrossRef Gonzalez C, Resa JM, Lanz J, Iglesias M (2006) Intermolecular interactions in soybean oil + different organic solvents by ultrasonic velocity measurements. J Food Eng 77:152–161CrossRef
40.
Zurück zum Zitat Rowlinson JS, Swinton FL (1982) Liquid and liquid mixtures, 3rd edn. Butterworths, London Rowlinson JS, Swinton FL (1982) Liquid and liquid mixtures, 3rd edn. Butterworths, London
41.
Zurück zum Zitat Gerecze NG (1977) Ultrasonic studies in solution of poly(ethylene glycol). Acoustica 38:51–57 Gerecze NG (1977) Ultrasonic studies in solution of poly(ethylene glycol). Acoustica 38:51–57
43.
Zurück zum Zitat Naidu SV, John K, Brahmam PV, Challa PK (2004) Ultrasonic studies of poly(vinyl acetate) solution in dimethylformamide. Int J Polym Anal Char 9:351–359CrossRef Naidu SV, John K, Brahmam PV, Challa PK (2004) Ultrasonic studies of poly(vinyl acetate) solution in dimethylformamide. Int J Polym Anal Char 9:351–359CrossRef
44.
Zurück zum Zitat Reddy VN, Rao KSWK, Subha MCS, Rao KC (2010) Miscibility behaviour of dextrin/PVA blends in water at 35°C, International Conference on Advances in Polymer Technology, India, Feb. 26–27:356–368 Reddy VN, Rao KSWK, Subha MCS, Rao KC (2010) Miscibility behaviour of dextrin/PVA blends in water at 35°C, International Conference on Advances in Polymer Technology, India, Feb. 26–27:356–368
45.
Zurück zum Zitat Larsen ES, Berman H (1934) The microscopic determination of the nonopaque minerals. US Geol Surv Bull 848:30–32 Larsen ES, Berman H (1934) The microscopic determination of the nonopaque minerals. US Geol Surv Bull 848:30–32
46.
Zurück zum Zitat Allen RD (1956) A new equation relating index of refraction and specific gravity. Am Mineralogist 41:245–257 Allen RD (1956) A new equation relating index of refraction and specific gravity. Am Mineralogist 41:245–257
47.
Zurück zum Zitat Venkateswara RA, Raman GK, Varada RA (1993) Acoustical parameters of polystyrene in binary mixture. Asian J Chem 5:582–592 Venkateswara RA, Raman GK, Varada RA (1993) Acoustical parameters of polystyrene in binary mixture. Asian J Chem 5:582–592
48.
Zurück zum Zitat Fahimi A, Jurewicz I, Smith RJ, Sharrock CS, Bradley DA, Henley SJ, Coleman JN, Dalton AB (2013) Density controlled conductivity of pristine graphene films. Carbon 64:435–443CrossRef Fahimi A, Jurewicz I, Smith RJ, Sharrock CS, Bradley DA, Henley SJ, Coleman JN, Dalton AB (2013) Density controlled conductivity of pristine graphene films. Carbon 64:435–443CrossRef
49.
Zurück zum Zitat Cicero G, Grossman JC, Schwegler E, Gygi F, Galli G (2008) Water confined in nanotubes and between graphene sheets: a first principle study. J Am Chem Soc 130:1871–1878CrossRef Cicero G, Grossman JC, Schwegler E, Gygi F, Galli G (2008) Water confined in nanotubes and between graphene sheets: a first principle study. J Am Chem Soc 130:1871–1878CrossRef
50.
Zurück zum Zitat Rafiee J, Rafiee MA, Yu Z-Z, Koratkar N (2010) Superhydrophobic to superhydrophilic wetting control in graphene films. Adv Mater 22:2151–2154CrossRef Rafiee J, Rafiee MA, Yu Z-Z, Koratkar N (2010) Superhydrophobic to superhydrophilic wetting control in graphene films. Adv Mater 22:2151–2154CrossRef
51.
Zurück zum Zitat Jeong WJ, Ha MY, Yoon HS, Ambrosia M (2012) Dynamic behavior of water droplets on solid surfaces with pillar-type nanostructures. Langmuir 28:5360–5371CrossRef Jeong WJ, Ha MY, Yoon HS, Ambrosia M (2012) Dynamic behavior of water droplets on solid surfaces with pillar-type nanostructures. Langmuir 28:5360–5371CrossRef
52.
Zurück zum Zitat Ma J, Alfe D, Michaelides A, Wang E (2009) Stone-wales defects in graphene and other planar sp2-bonded materials. Phys Rev B 80:033407–033411CrossRef Ma J, Alfe D, Michaelides A, Wang E (2009) Stone-wales defects in graphene and other planar sp2-bonded materials. Phys Rev B 80:033407–033411CrossRef
53.
Zurück zum Zitat Meyer JC, Kisielowski C, Erni R, Rosell MD, Crommie MF, Zettl A (2008) Direct imaging of lattice atoms and topological defects in graphene membranes. Nano Lett 8:3582–3586CrossRef Meyer JC, Kisielowski C, Erni R, Rosell MD, Crommie MF, Zettl A (2008) Direct imaging of lattice atoms and topological defects in graphene membranes. Nano Lett 8:3582–3586CrossRef
54.
Zurück zum Zitat Banhart F, Kotakoski J, Krasheninnikov AV (2011) Structural defects in graphene. ACS Nano 5:26–41CrossRef Banhart F, Kotakoski J, Krasheninnikov AV (2011) Structural defects in graphene. ACS Nano 5:26–41CrossRef
55.
Zurück zum Zitat Banhart F (2009) Interactions between metals and carbon nanotubes: at the interface between old and new materials. Nanoscale 1:201–213CrossRef Banhart F (2009) Interactions between metals and carbon nanotubes: at the interface between old and new materials. Nanoscale 1:201–213CrossRef
Metadaten
Titel
Thermophysical investigations of exfoliated graphite nanoplatelets and active carbon in binary aqueous environments at different temperatures
verfasst von
Ion Ion
Florinela Sirbu
Alina Catrinel Ion
Publikationsdatum
01.01.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 2/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8616-2

Weitere Artikel der Ausgabe 2/2015

Journal of Materials Science 2/2015 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.