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Journal of Materials Science
Erschienen in: Journal of Materials Science 16/2018

17.05.2018 | Chemical routes to materials

Facile preparation of porous carbon nitride for visible light photocatalytic reduction and oxidation applications

verfasst von: Shipeng Wan, Man Ou, Yongheng Xiong, Qin Zhong, Shule Zhang

Erschienen in: Journal of Materials Science | Ausgabe 16/2018

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Abstract

In this work, we have employed melamine, cyanuric acid and thymine to fabricate triazine-based carbon nitrides (CNs) by supramolecular approach. The resultant CNs possess large specific surface area, hierarchical porous structure, better light absorption capacity and high separation rate of photoinduced carriers. Then, the photocatalytic reduction and oxidation performance has been evaluated. The obtained CNs exhibit enhanced photocatalytic reduction performance on water splitting to H2, the largest hydrogen evolution rate can reach 8466.3 μmol g−1 h−1, which is 81.9 times as high as that of bulk CN. Simultaneously, the porous CNs show excellent photocatalytic reduction ability on the conversion of CO2 to H2, CO and CH4. Of particular interest is that they have high selectivity for CO. It’s worth noting that the porous CNs also possess outstanding photocatalytic oxidation ability on high concentration nitric oxide (NO), and the highest NO conversion rate can reach 79.3% under visible light. The enhanced photocatalytic performance for the multifunctional porous CN can be ascribed to the synergic effect of large specific surface area, strong light absorption capacity and fast separation of photoinduced electron–hole pairs. Finally, the photocatalytic reduction and oxidation mechanism of the porous CN is also proposed and discussed.
Vorheriger Artikel Physicochemical and electrochemical properties of the carbon materials containing nitrogen and cobalt derived from acetonitrile and Co–Al layered double hydroxides
Nächster Artikel Facile fabrication of hierarchical BiVO4/TiO2 heterostructures for enhanced photocatalytic activities under visible-light irradiation

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Metadaten
Titel
Facile preparation of porous carbon nitride for visible light photocatalytic reduction and oxidation applications
verfasst von
Shipeng Wan
Man Ou
Yongheng Xiong
Qin Zhong
Shule Zhang
Publikationsdatum
17.05.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 16/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2441-y

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