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28.08.2018 | Composites

Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties

verfasst von: Shimei Guo, Lichun Ma, Guojun Song, Xiaoru Li, Peiyao Li, Mingye Wang, Longlong Shi, Zheng Gu, Yudong Huang

Erschienen in: Journal of Materials Science | Ausgabe 24/2018

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Abstract

Interface interactions are the important problems in improving the mechanical properties of graphene and polymer composites. In this work, a simple method is proposed to prepare epoxy composites with admirable properties through constructing dendrimers with cyanuric chloride (TCT) and diethylenetriamine (DETA) onto graphene oxide (GO) surface. The FTIR, XRD, XPS, Raman spectroscopy, SEM and TEM were used to confirm the successful grafting of TCT and DETA molecules onto the surface of GO. The interfacial adhesion between GO–TCT–DETA and epoxy resin is enhanced due to the formation of a strong chemical bond between the amino group on the GO surface and the epoxy resins. The tensile and flexural strength of GO–TCT–DETA/epoxy composites have considerable improvement (40.79 and 48.56%) compared with that of epoxy resin due to stronger interfacial interaction. In addition, the strengthening mechanism and dispersion of GO–TCT–DETA in epoxy matrix were also demonstrated.

Vorheriger Artikel One-pot strategy for covalent construction of POSS-modified silane layer on carbon fiber to enhance interfacial properties and anti-hydrothermal aging behaviors of PPBES composites

Nächster Artikel Ultra-sensitive room-temperature H2S sensor using Ag–In2O3 nanorod composites

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Titel: Covalent grafting of triazine derivatives onto graphene oxide for preparation of epoxy composites with improved interfacial and mechanical properties
verfasst von: Shimei Guo
Lichun Ma
Guojun Song
Xiaoru Li
Peiyao Li
Mingye Wang
Longlong Shi
Zheng Gu
Yudong Huang
Publikationsdatum: 28.08.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 24/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2788-0

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