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Erschienen in: Journal of Materials Science 5/2020

27.09.2019 | Metals & corrosion

Flexible and thermally stable superhydrophobic surface with excellent anti-corrosion behavior

verfasst von: Huibin Zhu, Weihong Hu, Sipei Zhao, Xin Zhang, Li Pei, Guizhe Zhao, Zhi Wang

Erschienen in: Journal of Materials Science | Ausgabe 5/2020

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Abstract

Superhydrophobic films with excellent flexibility, mechanical robust and thermally stable properties have been fabricated through a facile one-step spray-coating process based on bisphenol A based benzoxazine (BA-a), polyurethane (PU) prepolymer, and mesoporous SiO2 (SBA-15). The curing mechanism between BA-a and PU prepolymer morphologies, water contact angles and thermal stability of coatings were characterized and discussed. In addition, the corrosion behavior of the superhydrophobic coatings on the tin plate was characterized by the polarization curve and electrochemical impedance spectroscopy. The coatings made by different weight ratios of BA-a to PU can maintain a contact angle higher than 150°; meanwhile, the coatings had a micro-nano structure with a Tg more than 221 °C. The coatings can be bent by the finger which illustrates their excellent flexible properties. Furthermore, friction coefficient of coatings can reach 1.70. The electrochemical corrosion test results indicated that the superhydrophobic coatings possessed excellent corrosion resistance (Icorr can reach 8.90 × 10−5 A cm−2 with certain ratio), which could have a potential at harsh environment.

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Metadaten
Titel
Flexible and thermally stable superhydrophobic surface with excellent anti-corrosion behavior
verfasst von
Huibin Zhu
Weihong Hu
Sipei Zhao
Xin Zhang
Li Pei
Guizhe Zhao
Zhi Wang
Publikationsdatum
27.09.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 5/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-04050-1

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