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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 14/2019

11.06.2019

Branched dibenzofulvene-based organic dyes for dye-sensitized solar cells under one sun and dim light

verfasst von: Yung-Chung Chen, Guan-Wei Huang, Yuan-Jay Chang, Jun-Jie Wen

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 14/2019

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Abstract

Series of metal-free dyes (OMS4-7) featuring a dibenzofulvene connected with thienyl or furanyl as conjugation bridge, T-shaped diarylamines (diphenylamine or phenyl-1-naphthylamine) as donors and different numbers of cyanoacrylic acid as anchors have been synthesized and applied into dye-sensitized solar cells (DSSCs). The efects of different donors, conjuation segments and number of anchors on optical and photovoltaic properties were investigated through photophysics, electrochemical and photovoltaic measurements. Of the DSSCs, the structure contains mono anchor with thienyl dibenzofulvene linked to diphenylamine, i.e. OMS4-based device exhibited the highest power conversion efficiency (PCE) of 2.42%, a value of Jsc of 6.01 mA cm−2, a Voc of 0.63 V, and a fill factor of 0.63 under 10 mM CDA co-adsorbent and AM 1.5 irradiation. The corresponding device was also conducted with respect to different light intensity such as D65, CWF and TL84. As a result, the cell performance based on TL84 with 2500 lx exhibited the best PCE of 8.78%.
Vorheriger Artikel Reduced graphene oxide modified titania photoanodes for fabrication of the efficient dye-sensitized solar cell
Nächster Artikel Investigation of superconducting and elastic parameters of YBCO/LSMO thick films

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Metadaten
Titel
Branched dibenzofulvene-based organic dyes for dye-sensitized solar cells under one sun and dim light
verfasst von
Yung-Chung Chen
Guan-Wei Huang
Yuan-Jay Chang
Jun-Jie Wen
Publikationsdatum
11.06.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 14/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01660-y

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