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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2019

31.03.2019 | Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Sol-gel-assisted preparation of SiO2@Co3O4 heterostructure from laboratory glass waste as a potential anode for lithium-ion battery

verfasst von: Arul Prasath, Arumugam Selva Sharma, Perumal Elumalai

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2019

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Abstract

In this work, a simple sol–gel method was developed to incorporate Co3O4 into glass waste-derived SiO2 to generate a heterostructured SiO2@Co3O4 nanocomposite. Morphological analysis revealed the presence of tiny Co3O4 grains embedded on to the surface of the spherically shaped SiO2 particles. The SiO2@Co3O4 hetrostructure anode exhibited a reversible capacity as high as 684 mA h g−1 at 0.5 C. Even after 50 cycles, the anode material showed a remarkable Coulombic efficiency of 99% with capacity retention as high as 75% (507 mA h g−1). The synergistic contribution resulting from the alloying/conversion mechanisms associated with the SiO2@Co3O4 resulted in enhanced electrochemical performance.
Vorheriger Artikel In situ sol–gel preparation of ZrO2 in nano-composite polymer electrolyte of PVDF-HFP/MG49 for lithium-ion polymer battery

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Metadaten
Titel
Sol-gel-assisted preparation of SiO2@Co3O4 heterostructure from laboratory glass waste as a potential anode for lithium-ion battery
verfasst von
Arul Prasath
Arumugam Selva Sharma
Perumal Elumalai
Publikationsdatum
31.03.2019
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2019
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-019-04980-x

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