Skip to main content
Erschienen in: Journal of Nanoparticle Research 3/2017

01.03.2017 | Technology and Applications

Experimental investigation on the morphology of soot aggregates from the burning of typical solid and liquid fuels

verfasst von: Dongmei Huang, Chenning Guo, Long Shi

Erschienen in: Journal of Nanoparticle Research | Ausgabe 3/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Soot particles from the burning of typical fuels are one of the critical sources causing environmental problems and human disease. To understand the soot formation of these typical fuels, the size and morphology of soot aggregates produced from the burning of typical solid and liquid fuels, including diesel, kerosene, natural rubber (NR) latex foam, and wood crib, were studied by both extractive sampling and subsequent image analysis. The 2D and 3D fractal dimensions together with the diameter distribution of agglomerate and primary particles were analyzed for these four typical fuels. The average diameters of the primary particles were within 45–85 nm when sampling from different heights above the fire sources. Irregular sheet structures and flake-like masses were observed from the burning of NR latex foam and wood cribs. Superaggregates with a mean maximum length scale of over 100 μm were also found from the burning of all these four tested fuels. The fractal dimension of a single aggregate was 3 for all the tested fuels.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Beyler CL, Hirschler MM (2002) Thermal decomposition of polymers. SFPE handbook of fire protection engineering, 3rd Edition: 1.110–1.131 Beyler CL, Hirschler MM (2002) Thermal decomposition of polymers. SFPE handbook of fire protection engineering, 3rd Edition: 1.110–1.131
Zurück zum Zitat Chakrabarty RK, Moosmüller H, Garro MA et al (2006) Emissions from the laboratory combustion of wildland fuels: particle morphology and size. J Geophys Res 111(D7):1–16CrossRef Chakrabarty RK, Moosmüller H, Garro MA et al (2006) Emissions from the laboratory combustion of wildland fuels: particle morphology and size. J Geophys Res 111(D7):1–16CrossRef
Zurück zum Zitat Chakrabarty RK, Garro MA, Garro BA et al (2011) Simulation of aggregates with point-contacting monomers in the cluster–dilute regime. Part 1: determining the most reliable technique for obtaining three-dimensional fractal dimension from two-dimensional images. Aerosol Sci Technol 45(1):75–80CrossRef Chakrabarty RK, Garro MA, Garro BA et al (2011) Simulation of aggregates with point-contacting monomers in the cluster–dilute regime. Part 1: determining the most reliable technique for obtaining three-dimensional fractal dimension from two-dimensional images. Aerosol Sci Technol 45(1):75–80CrossRef
Zurück zum Zitat Chakrabarty RK, Moosmüller H, Garro MA et al (2012) Observation of superaggregates from a reversed gravity low-sooting flame. Aerosol Sci Technol 46(1):i–iiiCrossRef Chakrabarty RK, Moosmüller H, Garro MA et al (2012) Observation of superaggregates from a reversed gravity low-sooting flame. Aerosol Sci Technol 46(1):i–iiiCrossRef
Zurück zum Zitat Chakrabarty RK, Beres ND, Moosmüller H et al (2014) Soot superaggregates from flaming wildfires and their direct radiative forcing. Sci Rep 4:1–8CrossRef Chakrabarty RK, Beres ND, Moosmüller H et al (2014) Soot superaggregates from flaming wildfires and their direct radiative forcing. Sci Rep 4:1–8CrossRef
Zurück zum Zitat Dhaubhadel R, Pierce F, Chakrabarti A et al (2006) Hybrid superaggregate morphology as a result of aggregation in a cluster-dense aerosol. Phys Rev E 73(1):011404CrossRef Dhaubhadel R, Pierce F, Chakrabarti A et al (2006) Hybrid superaggregate morphology as a result of aggregation in a cluster-dense aerosol. Phys Rev E 73(1):011404CrossRef
Zurück zum Zitat Dong JL, Li HX, Yang CM et al (2014) Determination on combustion energies of four oxygenated chemicals. Laboratory Sci 17(6):4–6 Dong JL, Li HX, Yang CM et al (2014) Determination on combustion energies of four oxygenated chemicals. Laboratory Sci 17(6):4–6
Zurück zum Zitat Fang J, Shu XM, Yuan HY et al (2004) Self-preserving size distribution of fire soot fractal coagulation in flaming combustion. J Fire Sci 22(1):53–68CrossRef Fang J, Shu XM, Yuan HY et al (2004) Self-preserving size distribution of fire soot fractal coagulation in flaming combustion. J Fire Sci 22(1):53–68CrossRef
Zurück zum Zitat Fitzpatrick EM, Jones JM, Pourkashanian M et al (2008) Mechanistic aspects of soot formation from the combustion of pine wood. Energ Fuel 22(6):3771–3778CrossRef Fitzpatrick EM, Jones JM, Pourkashanian M et al (2008) Mechanistic aspects of soot formation from the combustion of pine wood. Energ Fuel 22(6):3771–3778CrossRef
Zurück zum Zitat Frenklach M (2002) Reaction mechanism of soot formation in flames. Phys Chem Chem Phys 4(11):2028–2037CrossRef Frenklach M (2002) Reaction mechanism of soot formation in flames. Phys Chem Chem Phys 4(11):2028–2037CrossRef
Zurück zum Zitat Frenklach M, Gardiner WC, Stein SE et al (1986) Mechanism of soot formation in acetylene-oxygen mixtures. Combust Sci Technol 50(1–3):79–115CrossRef Frenklach M, Gardiner WC, Stein SE et al (1986) Mechanism of soot formation in acetylene-oxygen mixtures. Combust Sci Technol 50(1–3):79–115CrossRef
Zurück zum Zitat Frenklach M, Clary DW, Gardiner WC et al. (1988a) Effect of fuel structure on pathways to soot. Paper presented at the Symposium (International) on Combustion Frenklach M, Clary DW, Gardiner WC et al. (1988a) Effect of fuel structure on pathways to soot. Paper presented at the Symposium (International) on Combustion
Zurück zum Zitat Frenklach M, Yuan T, Ramachandra MK (1988b) Soot formation in binary hydrocarbon mixtures. Energ Fuel 2(4):462–480CrossRef Frenklach M, Yuan T, Ramachandra MK (1988b) Soot formation in binary hydrocarbon mixtures. Energ Fuel 2(4):462–480CrossRef
Zurück zum Zitat Fry D, Chakrabarti A, Kim W et al (2004) Structural crossover in dense irreversibly aggregating particulate systems. Phys Rev E 69(6):061401CrossRef Fry D, Chakrabarti A, Kim W et al (2004) Structural crossover in dense irreversibly aggregating particulate systems. Phys Rev E 69(6):061401CrossRef
Zurück zum Zitat Goo J (2012) Development of the size distribution of smoke particles in a compartment fire. Fire Safety J 47:46–53CrossRef Goo J (2012) Development of the size distribution of smoke particles in a compartment fire. Fire Safety J 47:46–53CrossRef
Zurück zum Zitat Gwaze P, Schmid O, Annegarn HJ et al (2006) Comparison of three methods of fractal analysis applied to soot aggregates from wood combustion. J Aerosol Sci 37(7):820–838CrossRef Gwaze P, Schmid O, Annegarn HJ et al (2006) Comparison of three methods of fractal analysis applied to soot aggregates from wood combustion. J Aerosol Sci 37(7):820–838CrossRef
Zurück zum Zitat Hirschler MM (1985a) Soot from fires: I. Properties and methods of investigation. J Fire Sci 3(5):343–374CrossRef Hirschler MM (1985a) Soot from fires: I. Properties and methods of investigation. J Fire Sci 3(5):343–374CrossRef
Zurück zum Zitat Hirschler MM (1985b) Soot from fires: II. Mechanisms of soot formation. J Fire Sci 3(6):380–414CrossRef Hirschler MM (1985b) Soot from fires: II. Mechanisms of soot formation. J Fire Sci 3(6):380–414CrossRef
Zurück zum Zitat Kamens RM, Perry JM, Saucy DA et al (1985) Factors which influence polycyclic aromatic hydrocarbon decomposition on wood smoke particles. Environ Int 11(2):131–136CrossRef Kamens RM, Perry JM, Saucy DA et al (1985) Factors which influence polycyclic aromatic hydrocarbon decomposition on wood smoke particles. Environ Int 11(2):131–136CrossRef
Zurück zum Zitat Kearney SP, Pierce F (2012) Evidence of soot superaggregates in a turbulent pool fire. Combust Flame 159(10):3191–3198CrossRef Kearney SP, Pierce F (2012) Evidence of soot superaggregates in a turbulent pool fire. Combust Flame 159(10):3191–3198CrossRef
Zurück zum Zitat Kholghy MR. (2012) The evolution of soot morphology in laminar co-flow diffusion flames of the surrogates for jet A-1 and a synthetic kerosene. University of Toronto Kholghy MR. (2012) The evolution of soot morphology in laminar co-flow diffusion flames of the surrogates for jet A-1 and a synthetic kerosene. University of Toronto
Zurück zum Zitat Kholghy MR, Weingarten J, Sediako AD et al.(2017) Structural effects of biodiesel on soot formation in a laminar coflow diffusion flame. P Combust Inst 36(1): 1321-1328 Kholghy MR, Weingarten J, Sediako AD et al.(2017) Structural effects of biodiesel on soot formation in a laminar coflow diffusion flame. P Combust Inst 36(1): 1321-1328
Zurück zum Zitat Kim W, Sorensen CM, Fry D et al. (2003) Observation of soot superaggregates in laminar acetylene/air diffusion flames with a fractal dimension of 2.6^ 1. Paper presented at the APS Meeting Abstracts Kim W, Sorensen CM, Fry D et al. (2003) Observation of soot superaggregates in laminar acetylene/air diffusion flames with a fractal dimension of 2.6^ 1. Paper presented at the APS Meeting Abstracts
Zurück zum Zitat Kim W, Sorensen CM, Chakrabarti A (2004) Universal occurrence of soot superaggregates with a fractal dimension of 2.6 in heavily sooting laminar diffusion flames. Langmuir 20(10):3969–3973CrossRef Kim W, Sorensen CM, Chakrabarti A (2004) Universal occurrence of soot superaggregates with a fractal dimension of 2.6 in heavily sooting laminar diffusion flames. Langmuir 20(10):3969–3973CrossRef
Zurück zum Zitat Kim W, Sorensen CM, Fry D et al (2006) Soot aggregates, superaggregates and gel-like networks in laminar diffusion flames. J Aerosol Sci 37(3):386–401CrossRef Kim W, Sorensen CM, Fry D et al (2006) Soot aggregates, superaggregates and gel-like networks in laminar diffusion flames. J Aerosol Sci 37(3):386–401CrossRef
Zurück zum Zitat Lamberg H, Nuutinen K, Tissari J et al (2011) Physicochemical characterization of fine particles from small-scale wood combustion. Atmos Environ 45(40):7635–7643CrossRef Lamberg H, Nuutinen K, Tissari J et al (2011) Physicochemical characterization of fine particles from small-scale wood combustion. Atmos Environ 45(40):7635–7643CrossRef
Zurück zum Zitat Lea-Langton AR, Baeza-Romero MT, Boman GV et al (2015) A study of smoke formation from wood combustion. Fuel Processing Technol 137:327–332CrossRef Lea-Langton AR, Baeza-Romero MT, Boman GV et al (2015) A study of smoke formation from wood combustion. Fuel Processing Technol 137:327–332CrossRef
Zurück zum Zitat Lee EJ, Oh KC, Shin HD (2005) Soot formation in inverse diffusion flames of diluted ethene. Fuel 84(5):543–550CrossRef Lee EJ, Oh KC, Shin HD (2005) Soot formation in inverse diffusion flames of diluted ethene. Fuel 84(5):543–550CrossRef
Zurück zum Zitat Li Z, Song CJ, Song J et al (2011) Evolution of the nanostructure, fractal dimension and size of in-cylinder soot during diesel combustion process. Combust Flame 158(8):1624–1630CrossRef Li Z, Song CJ, Song J et al (2011) Evolution of the nanostructure, fractal dimension and size of in-cylinder soot during diesel combustion process. Combust Flame 158(8):1624–1630CrossRef
Zurück zum Zitat Luo H, Lee WMG, Lai YC et al (2005) Measuring the fractal dimension of diesel soot agglomerates by fractional Brownian motion processor. Atmos Environ 39(19):3565–3572CrossRef Luo H, Lee WMG, Lai YC et al (2005) Measuring the fractal dimension of diesel soot agglomerates by fractional Brownian motion processor. Atmos Environ 39(19):3565–3572CrossRef
Zurück zum Zitat Merchan-Merchan W, Sanmiguel SG, McCollam S (2012) Analysis of soot particles derived from biodiesels and diesel fuel air-flames. Fuel 102:525–535CrossRef Merchan-Merchan W, Sanmiguel SG, McCollam S (2012) Analysis of soot particles derived from biodiesels and diesel fuel air-flames. Fuel 102:525–535CrossRef
Zurück zum Zitat Oh KC, Shin HD (2006) The effect of oxygen and carbon dioxide concentration on soot formation in non-premixed flames. Fuel 85(5):615–624CrossRef Oh KC, Shin HD (2006) The effect of oxygen and carbon dioxide concentration on soot formation in non-premixed flames. Fuel 85(5):615–624CrossRef
Zurück zum Zitat Oh C, Sorensen CM (1997) The effect of overlap between monomers on the determination of fractal cluster morphology. J Colloid Interf Sci 193(1):17–25CrossRef Oh C, Sorensen CM (1997) The effect of overlap between monomers on the determination of fractal cluster morphology. J Colloid Interf Sci 193(1):17–25CrossRef
Zurück zum Zitat Onischuk AA, Di Stasio S, Karasev VV et al (2003) Evolution of structure and charge of soot aggregates during and after formation in a propane/air diffusion flame. J Aerosol Sci 34(4):383–403CrossRef Onischuk AA, Di Stasio S, Karasev VV et al (2003) Evolution of structure and charge of soot aggregates during and after formation in a propane/air diffusion flame. J Aerosol Sci 34(4):383–403CrossRef
Zurück zum Zitat Ouf FX, Vendel J, Coppalle A et al (2008) Characterization of soot particles in the plumes of over-ventilated diffusion flames. Combust Sci Technol 180(4):674–698CrossRef Ouf FX, Vendel J, Coppalle A et al (2008) Characterization of soot particles in the plumes of over-ventilated diffusion flames. Combust Sci Technol 180(4):674–698CrossRef
Zurück zum Zitat Ouf FX, Yon J, Ausset P et al (2010) Influence of sampling and storage protocol on fractal morphology of soot studied by transmission electron microscopy. Aerosol Sci Technol 44(11):1005–1017CrossRef Ouf FX, Yon J, Ausset P et al (2010) Influence of sampling and storage protocol on fractal morphology of soot studied by transmission electron microscopy. Aerosol Sci Technol 44(11):1005–1017CrossRef
Zurück zum Zitat Par K, Kittelson DB, McMurry PH (2004) Structural properties of diesel exhaust particles measured by transmission electron microscopy (TEM): relationships to particle mass and mobility. Aerosol Sci Technol 38(9):881–889CrossRef Par K, Kittelson DB, McMurry PH (2004) Structural properties of diesel exhaust particles measured by transmission electron microscopy (TEM): relationships to particle mass and mobility. Aerosol Sci Technol 38(9):881–889CrossRef
Zurück zum Zitat Pickett LM, Siebers DL (2002) An investigation of diesel soot formation processes using micro-orifices. P Combust Inst 29(1):655–662CrossRef Pickett LM, Siebers DL (2002) An investigation of diesel soot formation processes using micro-orifices. P Combust Inst 29(1):655–662CrossRef
Zurück zum Zitat Pitkänen A, Lehtonen H, Huttunen P (1999) Comparison of sedimentary microscopic charcoal particle records in a small lake with dendrochronological data: evidence for the local origin of microscopic charcoal produced by forest fires of low intensity in eastern Finland. The Holocene 9(5):559–567CrossRef Pitkänen A, Lehtonen H, Huttunen P (1999) Comparison of sedimentary microscopic charcoal particle records in a small lake with dendrochronological data: evidence for the local origin of microscopic charcoal produced by forest fires of low intensity in eastern Finland. The Holocene 9(5):559–567CrossRef
Zurück zum Zitat Reid JS, Hobbs PV (1998) Physical and optical properties of young smoke from individual biomass fires in Brazil. J Geophys Res 32:13–32,30 Reid JS, Hobbs PV (1998) Physical and optical properties of young smoke from individual biomass fires in Brazil. J Geophys Res 32:13–32,30
Zurück zum Zitat Robert E, Olofsson NE, Bladh H et al (2014) Soot formation in unstrained diffusion flames. Combust Sci Technol 187(4):577–593CrossRef Robert E, Olofsson NE, Bladh H et al (2014) Soot formation in unstrained diffusion flames. Combust Sci Technol 187(4):577–593CrossRef
Zurück zum Zitat Rockne KJ, Taghon GL, Kosson DS (2000) Pore structure of soot deposits from several combustion sources. Chemosphere 41(8):1125–1135CrossRef Rockne KJ, Taghon GL, Kosson DS (2000) Pore structure of soot deposits from several combustion sources. Chemosphere 41(8):1125–1135CrossRef
Zurück zum Zitat Roh JS, Yang SS, Ryou HS (2007) Tunnel fires: experiments on critical velocity and burning rate in pool fire during longitudinal ventilation. J Fire Sci 25(2):161–176CrossRef Roh JS, Yang SS, Ryou HS (2007) Tunnel fires: experiments on critical velocity and burning rate in pool fire during longitudinal ventilation. J Fire Sci 25(2):161–176CrossRef
Zurück zum Zitat Roslim R, Amir Hashim MY, Augurio PT (2012) Natural latex foam. J Engin Sci 8:15–27 Roslim R, Amir Hashim MY, Augurio PT (2012) Natural latex foam. J Engin Sci 8:15–27
Zurück zum Zitat Saffaripour M, Veshkini A, Kholghy M et al (2014) Experimental investigation and detailed modeling of soot aggregate formation and size distribution in laminar coflow diffusion flames of Jet A-1, a synthetic kerosene, and n-decane. Combust Flame 161(3):848–863CrossRef Saffaripour M, Veshkini A, Kholghy M et al (2014) Experimental investigation and detailed modeling of soot aggregate formation and size distribution in laminar coflow diffusion flames of Jet A-1, a synthetic kerosene, and n-decane. Combust Flame 161(3):848–863CrossRef
Zurück zum Zitat Sorensen CM, Kim W, Fry D et al (2003) Observation of soot superaggregates with a fractal dimension of 2.6 in laminar acetylene/air diffusion flames. Langmuir 19(18):7560–7563CrossRef Sorensen CM, Kim W, Fry D et al (2003) Observation of soot superaggregates with a fractal dimension of 2.6 in laminar acetylene/air diffusion flames. Langmuir 19(18):7560–7563CrossRef
Zurück zum Zitat Tissari J, Lyyränen J, Hytönen K et al (2008) Fine particle and gaseous emissions from normal and smouldering wood combustion in a conventional masonry heater. Atmos Environ 42(34):7862–7873CrossRef Tissari J, Lyyränen J, Hytönen K et al (2008) Fine particle and gaseous emissions from normal and smouldering wood combustion in a conventional masonry heater. Atmos Environ 42(34):7862–7873CrossRef
Zurück zum Zitat Van GC, Marijnissen JCM, Makkee M et al (2004) Measuring diesel soot with a scanning mobility particle sizer and an electrical low-pressure impactor: performance assessment with a model for fractal-like agglomerates. J Aerosol Sci 35(5):633–655CrossRef Van GC, Marijnissen JCM, Makkee M et al (2004) Measuring diesel soot with a scanning mobility particle sizer and an electrical low-pressure impactor: performance assessment with a model for fractal-like agglomerates. J Aerosol Sci 35(5):633–655CrossRef
Zurück zum Zitat Walters RN, Hackett SM, Lyon RE (2000) Heats of combustion of high temperature polymers. Fire Mater 24(5):245–252CrossRef Walters RN, Hackett SM, Lyon RE (2000) Heats of combustion of high temperature polymers. Fire Mater 24(5):245–252CrossRef
Zurück zum Zitat Wen Z, Yun S, Thomson MJ et al (2003) Modeling soot formation in turbulent kerosene/air jet diffusion flames. Combust Flame 135(3):323–340CrossRef Wen Z, Yun S, Thomson MJ et al (2003) Modeling soot formation in turbulent kerosene/air jet diffusion flames. Combust Flame 135(3):323–340CrossRef
Metadaten
Titel
Experimental investigation on the morphology of soot aggregates from the burning of typical solid and liquid fuels
verfasst von
Dongmei Huang
Chenning Guo
Long Shi
Publikationsdatum
01.03.2017
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 3/2017
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-017-3786-x

Weitere Artikel der Ausgabe 3/2017

Journal of Nanoparticle Research 3/2017 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.