Structural Relaxation, Glass Transition, Viscous Formability, and Crystallization of Zr-Cu–Based Bulk Metallic Glasses on Heating

In this article, we summarize our recent findings on relaxation, glass transition, viscous flow, and crystallization of Zr-Cu–based metallic glasses on heating. At least two processes related to the diffusivities of different alloying elements take place in the glass-transition region of a Zr-Cu-Al-Ni glassy alloy. Also, we report an unusual solidification behavior of the bulk glassy alloy produced using low-purity Zr in which both primary and eutectic-type structural constituents were formed simultaneously during solidification of the melt. In addition, viscous flow and structure changes in the Zr-Cu-Al-Ag glassy alloy are examined in both the glass-transition and supercooled liquid regions. This alloy is found to exhibit localized phase separation leading to nanocrystallization before massive crystallization of the entire sample.