Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 12/2017

08.11.2017

Fabrication of Superhydrophobic Calcium Phosphate Coating on Mg-Zn-Ca alloy and Its Corrosion Resistance

verfasst von: Lashuang Zhang, Yue Jiang, Wei Zai, Guangyu Li, Shaocheng Liu, Jianshe Lian, Zhonghao Jiang

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 12/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A novel superhydrophobic calcium phosphate coating was prepared on a magnesium alloy substrate by a highly effective chemical conversion process and subsequent chemical modification. Different methods were employed to characterize the surface morphology and chemical composition as well as measure the wettability of the coating. It was demonstrated that the as-prepared superhydrophobic calcium phosphate coating has a typical three-level hierarchical structure consisted of micro-protrusions, submicro-lumps and nano-grains, conferring excellent superhydrophobicity with a water contact angle of 159°. The electrochemical measurements and appropriate equivalent circuit revealed that the corrosion-resistant performance of the superhydrophobic calcium phosphate coating was significantly improved as compared with that of the substrate, the corrosion potential of the superhydrophobic coating increases from −1.56 to −1.36 V, and its corrosion current density decreases from 1.29 × 10−4 to 1.3 × 10−6 A/cm2. The anti-corrosion mechanism of the superhydrophobic coating was also discussed. It can be indicated that the corrosion inhibitive properties of the coating are in accordance with its hydrophobicity, which is owing to the presence of a protective layer of air trapped in the grooves of the coating surface to isolate the underlying materials from the external environment.
Vorheriger Artikel Effect of Oxide Additives on Phase Evolution and Tribological Behavior of Zirconia-Toughened Alumina Composite
Nächster Artikel Precipitation Kinetics of M23C6 Carbides in the Super304H Austenitic Heat-Resistant Steel

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
L. Zhao, Q. Liu, R. Gao, J. Wang, W. Yang, and L. Liu, One-Step Method for the Fabrication of Superhydrophobic Surface on Magnesium Alloy and Its Corrosion Protection, Antifouling Performance, Corros. Sci., 2014, 80, p 177-183CrossRef
2.
Y. Liu, X. Yin, J. Zhang, Y. Wang, Z. Han, and L. Ren, Biomimetic Hydrophobic Surface Fabricated by Chemical Etching Method from Hierarchically Structured Magnesium Alloy Substrate, Appl. Surf. Sci., 2013, 280, p 845-849CrossRef
3.
R. Gao, Q. Liu, J. Wang, X. Zhang, W. Yang, J. Liu, and L. Liu, Fabrication of Fibrous Szaibelyite with Hierarchical Structure Superhydrophobic Coating on AZ31 Magnesium Alloy for Corrosion Protection, Chem. Eng. J., 2014, 241, p 352-359CrossRef
4.
J.L. Zhang, C.D. Gu, and J.P. Tu, Robust Slippery Coating with Superior Corrosion Resistance and Anti-Icing Performance for AZ31B Mg Alloy Protection, ACS Appl. Mater. Interfaces, 2017, 9, p 11247-11257CrossRef
5.
Y. Liu, S. Li, J. Zhang, Y. Wang, Z. Han, and L. Ren, Fabrication of Biomimetic Superhydrophobic Surface with Controlled Adhesion by Electrodeposition, Chem. Eng. J., 2014, 248, p 440-447CrossRef
6.
K.A. Khalil, E.S. Sherif, and A.A. Almajid, Corrosion Passivation in Simulated Body Fluid of Magnesium/Hydroxyapatite Nanocomposites Sintered by High Frequency Induction Heating, Int. J. Electrochem. Sci., 2011, 6, p 6184-6199
7.
J. Liao, M. Hotta, and Y. Mori, Improved Corrosion Resistance of a High-Strength Mg-Al-Mn-Ca Magnesium Alloy Made by Rapid Solidification Powder Metallurgy, Mater. Sci. Eng. A, 2012, 544, p 10-20CrossRef
8.
H. Ardelean, I. Frateur, and P. Marcus, Corrosion Protection of Magnesium Alloys by Cerium, Zirconium and Niobium-Based Conversion Coatings, Corros. Sci., 2008, 50, p 1907-1918CrossRef
9.
E. Celia, T. Darmanin, E. Taffin de Givenchy, S. Amigoni, and F. Guittard, Recent Advances in Designing Superhydrophobic Surfaces, J. Colloid Interface Sci., 2013, 402, p 1-18CrossRef
10.
H. Wang, R. Akid, and M. Gobara, Scratch-Resistant Anticorrosion sol–gel Coating for the Protection of AZ31 Magnesium Alloy via a Low Temperature sol–gel Route, Corros. Sci., 2010, 52, p 2565-2570CrossRef
11.
J.L. Zhang, C.D. Gu, Y.Y. Tong, W. Yan, and J.P. Tu, A Smart Superhydrophobic Coating on AZ31B Magnesium Alloy with Self-Healing Effect. Adv. Mater. Interfaces, 2016, 3, p 1500694CrossRef
12.
D. Zang, R. Zhu, W. Zhang, X. Yu, L. Lin, X. Guo, M. Liu, and L. Jiang, Corrosion-Resistant Superhydrophobic Coatings on Mg Alloy Surfaces Inspired by Lotus Seedpod, Adv. Func. Mater., 2017, 27, p 1605446CrossRef
13.
Z. Guo, W. Liu, and B.L. Su, Superhydrophobic Surfaces: From Natural to Biomimetic to Functional, J. Colloid Interface Sci., 2011, 353, p 335-355CrossRef
14.
J. Song, Y. Lu, S. Huang, X. Liu, L. Wu, and W. Xu, A Simple Immersion Approach for Fabricating Superhydrophobic Mg Alloy Surfaces, Appl. Surf. Sci., 2013, 266, p 445-450CrossRef
15.
B. Bhushan and Y.C. Jung, Natural and Biomimetic Artificial Surfaces for Superhydrophobicity, Self-Cleaning, Low Adhesion, and Drag Reduction, Prog. Mater Sci., 2011, 56, p 1-108CrossRef
16.
X. Liu, Z. Jiang, Y. Guo, Z. Zhang, and L. Ren, Fabrication of Super-Hydrophobic Nano-Sized Copper Films by Electroless Plating, Thin Solid Films, 2010, 518, p 3731-3734CrossRef
17.
M.-H. Han, S.-C. Go, and Y.-H. Ahn, Fabrication of Superhydrophobic Surface on Magnesium Substrate by Chemical Etching, Bull. Korean Chem. Soc., 2012, 33, p 1363-1366CrossRef
18.
Y. Liu, X. Yin, J. Zhang, S. Yu, Z. Han, and L. Ren, A electro-Deposition Process for Fabrication Of Biomimetic Super-Hydrophobic Surface and Its Corrosion Resistance on Magnesium Alloy, Electrochim. Acta, 2014, 125, p 395-403CrossRef
19.
C.D. Gu, X.J. Xu, and J.P. Tu, Fabrication and Wettability of Nanoporous Silver Film on Copper from Choline Chloride-Based Deep Eutectic Solvents, J. Phys. Chem. C, 2010, 114, p 13614-13619CrossRef
20.
S. Yuan, S.O. Pehkonen, B. Liang, Y.P. Ting, K.G. Neoh, and E.T. Kang, Superhydrophobic Fluoropolymer-Modified Copper Surface via Surface Graft Polymerisation for Corrosion Protection, Corros. Sci., 2011, 53, p 2738-2747CrossRef
21.
L.B. Boinovich, A.M. Emelyanenko, A.D. Modestov, A.G. Domantovsky, and K.A. Emelyanenko, Synergistic Effect of Superhydrophobicity and Oxidized Layers on Corrosion Resistance of Aluminum Alloy Surface Textured by Nanosecond Laser Treatment, ACS Appl. Mater. Interfaces, 2015, 7, p 19500-19508CrossRef
22.
R. Qiu, D. Zhang, and P. Wang, Superhydrophobic-Carbon Fibre Growth on a Zinc Surface for Corrosion Inhibition, Corros. Sci., 2013, 66, p 350-359CrossRef
23.
J. Ou, M. Liu, W. Li, F. Wang, M. Xue, and C. Li, Corrosion Behavior of Superhydrophobic Surfaces of Ti Alloys in NaCl Solutions, Appl. Surf. Sci., 2012, 258, p 4724-4728CrossRef
24.
Z. She, Q. Li, Z. Wang, C. Tan, J. Zhou, and L. Li, Highly Anticorrosion, Self-Cleaning Superhydrophobic Ni-Co Surface Fabricated on AZ91D Magnesium Alloy, Surf. Coat. Technol., 2014, 251, p 7-14CrossRef
25.
T. Ishizaki, J. Hieda, N. Saito, N. Saito, and O. Takai, Corrosion Resistance and Chemical Stability of Super-Hydrophobic Film Deposited on Magnesium Alloy AZ31 by Microwave Plasma-Enhanced Chemical Vapor Deposition, Electrochim. Acta, 2010, 55, p 7094-7101CrossRef
26.
W. Xu, J. Song, J. Sun, Y. Lu, and Z. Yu, Rapid Fabrication of Large-Area, Corrosion-Resistant Superhydrophobic Mg Alloy Surfaces, ACS Appl. Mater. Interfaces, 2011, 3, p 4404-4414CrossRef
27.
Y. Wang, W. Wang, L. Zhong, J. Wang, Q. Jiang, and X. Guo, Super-Hydrophobic Surface on Pure Magnesium Substrate by Wet Chemical Method, Appl. Surf. Sci., 2010, 256, p 3837-3840CrossRef
28.
Z. She, Q. Li, Z. Wang, L. Li, F. Chen, and J. Zhou, Novel Method for Controllable Fabrication of a Superhydrophobic CuO Surface on AZ91D Magnesium Alloy, ACS Appl. Mater. Interfaces, 2012, 4, p 4348-4356CrossRef
29.
K. Liu, M. Zhang, J. Zhai, J. Wang, and L. Jiang, Bioinspired Construction of Mg-Li Alloys Surfaces with Stable Superhydrophobicity and Improved Corrosion Resistance, Appl. Phys. Lett., 2008, 92, p 183103CrossRef
30.
T. Ishizaki and M. Sakamoto, Facile Formation of Biomimetic Color-Tuned Superhydrophobic Magnesium Alloy with Corrosion Resistance, Langmuir ACS J. Surf. Colloids, 2011, 27, p 2375-2381CrossRef
31.
X.B. Chen, N. Birbilis, and T.B. Abbott, Effect of [Ca2+] and [PO4 3−] Levels on the Formation of Calcium Phosphate Conversion Coatings on Die-Cast Magnesium Alloy AZ91D, Corros. Sci., 2012, 55, p 226-232CrossRef
32.
H. Huo, Y. Li, and F. Wang, Corrosion of AZ91D Magnesium Alloy with a Chemical Conversion Coating and Electroless Nickel Layer, Corros. Sci., 2004, 46, p 1467-1477CrossRef
33.
Z. She, Q. Li, Z. Wang, L. Li, F. Chen, and J. Zhou, Researching the Fabrication of Anticorrosion Superhydrophobic Surface on Magnesium Alloy and Its Mechanical Stability and Durability, Chem. Eng. J., 2013, 228, p 415-424CrossRef
34.
C. Gu, J. Lian, G. Li, L. Niu, and Z. Jiang, Electroless Ni-P Plating on AZ91D Magnesium Alloy from a Sulfate Solution, J. Alloy. Compd., 2005, 391, p 104-109CrossRef
35.
Y. Zhu, G. Wu, Y.-H. Zhang, and Q. Zhao, Growth and Characterization of Mg(OH)2 Film on Magnesium Alloy AZ31, Appl. Surf. Sci., 2011, 257, p 6129-6137CrossRef
36.
L.Y. Niu, Z.H. Jiang, G.Y. Li, C.D. Gu, and J.S. Lian, A Study and Application of Zinc Phosphate Coating on AZ91D Magnesium Alloy, Surf. Coat. Technol., 2006, 200, p 3021-3026CrossRef
37.
G.Y. Li, J.S. Lian, L.Y. Niu, Z.H. Jiang, and Q. Jiang, Growth of Zinc Phosphate Coatings on AZ91D Magnesium Alloy, Surf. Coat. Technol., 2006, 201, p 1814-1820CrossRef
38.
Y. Song, D. Shan, R. Chen, F. Zhang, and E.-H. Han, Formation Mechanism of Phosphate Conversion Film on Mg-8.8Li Alloy, Corros. Sci., 2009, 51, p 62-69CrossRef
39.
A.A.G. Song, D. St John, X. Wu, and J. Nairn, The Anodic Dissolution of Magnesium in Chloride and Sulphate Solutions, Corros. Sci., 1997, 39, p 1981-2004CrossRef
40.
K.C. Emregül and A.A. Aksüt, The Effect of Sodium Molybdate on the Pitting Corrosion of Aluminum, Corros. Sci., 2003, 45, p 2415-2433CrossRef
41.
J.E. Gray-Munro and M. Strong, The Mechanism of Deposition of Calcium Phosphate Coatings from Solution onto Magnesium Alloy AZ31, J. Biomed. Mater. Res. Part A, 2009, 90, p 339-350CrossRef
42.
W. Li and Z. Kang, Fabrication of Corrosion Resistant Superhydrophobic Surface with Self-Cleaning Property on Magnesium Alloy and Its Mechanical Stability, Surf. Coat. Technol., 2014, 253, p 205-213CrossRef
43.
Z. Wang, Q. Li, Z. She, F. Chen, L. Li, X. Zhang, and P. Zhang, Facile and Fast Fabrication of Superhydrophobic Surface on Magnesium Alloy, Appl. Surf. Sci., 2013, 271, p 182-192CrossRef
44.
Y. Liu, Z. Yu, S. Zhou, and L. Wu, Self-Assembled Monolayers on Magnesium Alloy Surfaces from Carboxylate Ions, Appl. Surf. Sci., 2006, 252, p 3818-3827CrossRef
45.
Q. Liu, D. Chen, and Z. Kang, One-Step Electrodeposition Process to Fabricate Corrosion-Resistant Superhydrophobic Surface on Magnesium Alloy, ACS Appl. Mater. Interfaces, 2015, 7, p 1859-1867CrossRef
46.
A.L.G.M. Stern, A Theoretical Analysis of the Shape of Polarization Curves, J. Electrochem. Soc., 1957, 104, p 56-63CrossRef
47.
H. Duan, K. Du, C. Yan, and F. Wang, Electrochemical Corrosion Behavior of Composite Coatings of Sealed MAO Film on Magnesium Alloy AZ91D, Electrochim. Acta, 2006, 51, p 2898-2908CrossRef
48.
L. Lei, J. Shi, X. Wang, D. Liu, and H. Xu, Microstructure and Electrochemical Behavior of Cerium Conversion Coating Modified with Silane Agent on Magnesium Substrates, Appl. Surf. Sci., 2016, 376, p 161-171CrossRef
49.
T. Ishizaki, N. Kamiyama, K. Watanabe, and A. Serizawa, Corrosion Resistance of Mg(OH)2/Mg-Al Layered Double Hydroxide Composite Film Formed Directly on Combustion-Resistant Magnesium Alloy AMCa602 by Steam Coating, Corros. Sci., 2015, 92, p 76-84CrossRef
50.
P. Wang, D. Zhang, R. Qiu, and B. Hou, Super-Hydrophobic Film Prepared on Zinc as Corrosion Barrier, Corros. Sci., 2011, 53, p 2080-2086CrossRef
51.
Y. Liu, J. Xue, D. Luo, H. Wang, X. Gong, Z. Han, and L. Ren, One-Step Fabrication of Biomimetic Superhydrophobic Surface by Electrodeposition on Magnesium Alloy and Its Corrosion Inhibition, J. Colloid Interface Sci., 2017, 491, p 313-320CrossRef
52.
F. Su and K. Yao, Facile Fabrication of Superhydrophobic Surface with Excellent Mechanical Abrasion and Corrosion Resistance on Copper Substrate by a Novel Method, ACS Appl. Mater. Interfaces, 2014, 6, p 8762-8770CrossRef
Metadaten
Titel
Fabrication of Superhydrophobic Calcium Phosphate Coating on Mg-Zn-Ca alloy and Its Corrosion Resistance
verfasst von
Lashuang Zhang
Yue Jiang
Wei Zai
Guangyu Li
Shaocheng Liu
Jianshe Lian
Zhonghao Jiang
Publikationsdatum
08.11.2017
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 12/2017
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-017-2994-y

Weitere Artikel der Ausgabe 12/2017

Journal of Materials Engineering and Performance 12/2017 Zur Ausgabe

OriginalPaper

Investigation of Thermal Conductivities and Expansion Coefficients of (Yb1 − x La x )2AlTaO7 Ceramics

OriginalPaper

Correlation Between Structural Parameters and Mechanical Properties of Al5083 Sheets Processed by ECAR

OriginalPaper

Cyclic Elastoplastic Performance of Aluminum 7075-T6 Under Strain- and Stress-Controlled Loading

OriginalPaper

Synergistic Effects of Temperature, Oxidation and Stress Level on Fatigue Damage Evolution and Lifetime Prediction of Cross-Ply SiC/CAS Ceramic-Matrix Composites Through Hysteresis-Based Parameters

OriginalPaper

Experimental Research on Selective Laser Melting AlSi10Mg Alloys: Process, Densification and Performance

OriginalPaper

Dislocation and Structural Studies at Metal–Metallic Glass Interface at Low Temperature

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise