Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Rare Metals
Erschienen in: Rare Metals 7/2021

20.08.2020 | Original Article

Dual-property blue and red emission carbon dots for Fe(III) ions detection and cellular imaging

verfasst von: Yin-Long Xu, Rui-Xue Mo, Cai-Yu Qi, Zeng Ren, Xiu-Zhi Jia, Zi-Gui Kan, Cao-Long Li, Fei Wang

Erschienen in: Rare Metals | Ausgabe 7/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The excitation wavelength-dependent and -independent emissions are two crucial fluorescent properties of carbon dots (CDs). However, CDs reported till date exhibit only one of these properties, which limits their practical applications. Herein, dual-property carbon dots (DCDs) with both the excitation wavelength-dependent and -independent emissions were synthesized via a facile one-step solvothermal method using 4-(2-pyridylazo)-resorcinol as the carbon precursor. The multi-functional applications of the resulting DCDs were also evaluated. The as-prepared DCDs exhibited not only excellent monodispersity, high photostability, and storage stability, but also low toxicity, good biocompatibility, and cellular bioimaging capability. In addition, the DCDs exhibited excitation-dependent emission photoluminescence under low excitation wavelengths. The DCDs exhibited good Fe3+ detection by quenching the blue emission fluorescence and showed a relatively low Fe3+ detection limit of 0.067 μmol·L−1 based on three times signal-to-noise criteria (R2 = 0.99). Furthermore, the DCDs showed excitation-independent emission at low excitation wavelengths and exhibited red emission at about 598 nm to avoid damage to the body. These results demonstrate the excellent bioimaging properties of the DCDs. Owing to their dual PL properties, the as-prepared DCDs exhibited multi-functional applications: Fe3+ detection and A549 cell bioimaging. These results will be helpful in developing novel CDs for applications in various fields.

Graphic abstract

Vorheriger Artikel Hot pressing sintering process and sintering mechanism of W–La2O3–Y2O3–ZrO2
Nächster Artikel Development of sandwich joining piece to fabricate segmented half-Heusler/skutterudite thermoelectric joints

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
[1]
Xu X, Ray R, Gu Y, Ploehn HJ, Gearheart L, Raker K, Scrivens WA. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments. J Am Chem Soc. 2004;126(40):12736.
[2]
Liu HP, Ye T, Mao CD. Fluorescent carbon nanoparticles derived from candle soot. Angew Chem Int Ed. 2007;46(34):6437.
[3]
Wang YF, Hu AG. Carbon quantum dots: synthesis, properties and applications. J Mater Chem C. 2014;2(34):6921.
[4]
Lim SY, Shen W, Gao ZQ. Carbon quantum dots and their applications. Chem Soc Rev. 2015;44(1):362.
[5]
Sun S, Jiang K, Qian SH, Wang YH, Lin HW. Applying carbon dots-metal ions ensembles as a multichannel fluorescent sensor array: detection and discrimination of phosphate anions. Anal Chem. 2017;89(10):5542.
[6]
Lu S, Sui L, Wu M, Zhu S, Yong X, Yang B. Graphitic nitrogen and high-crystalline triggered strong photoluminescence and room-temperature ferromagnetism in carbonized polymer dots. Adv Sci (Weinh). 2019;6(2):1801192.
[7]
Yang DX, Qu D, Miao X, Jiang WS, An L, Wen YJ, Wu DD, Sun ZC. TiO2 sensitized by red-, green-, blue-emissive carbon dots for enhanced H2 production. Rare Met. 2019;38(5):404.
[8]
Yeh TF, Teng CY, Chen SJ, Teng HS. Nitrogen-doped graphene oxide quantum dots as photocatalysts for overall water-splitting under visible light illumination. Adv Mater. 2014;26(20):3297.
[9]
Ming H, Ma Z, Liu Y, Pan KM, Yu H, Wang F, Kang ZH. Large scale electrochemical synthesis of high quality carbon nanodots and their photocatalytic property. Dalton Trans. 2012;41(31):9526.
[10]
Zhu SJ, Meng QN, Wang L, Zhang JH, Song YB, Jin H, Zhang K, Sun HC, Wang HY, Yang B. Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew Chem Int Ed. 2013;52(14):3953.
[11]
Kong B, Zhu A, Ding C, Zhao X, Li B, Tian Y. Carbon dot-based inorganic-organic nanosystem for two-photon imaging and biosensing of pH variation in living cells and tissues. Adv Mater. 2012;24(43):5844.
[12]
Li Z, Yu HJ, Bian T, Zhao YF, Zhou C, Shang L, Liu YH, Wu LZ, Tung CH, Zhang TR. Highly luminescent nitrogen-doped carbon quantum dots as effective fluorescent probes for mercuric and iodide ions. J Mater Chem C. 2015;3(9):1922.
[13]
Qu SN, Wang XY, Lu QP, Liu XY, Wang LJ. A biocompatible fluorescent ink based on water-soluble luminescent carbon nanodots. Angew Chem Int Ed. 2012;51(49):12215.
[14]
Baker SN, Baker GA. Luminescent carbon nanodots: emergent nanolights. Angew Chem Int Ed. 2010;49(38):6726.
[15]
Gupta A, Chaudhary A, Mehta P, Dwivedi C, Khan S, Verma NC, Nandi CK. Nitrogen-doped, thiol-functionalized carbon dots for ultrasensitive Hg(II) detection. Chem Commun. 2015;51(53):10750.
[16]
Liu CY, Chang KW, Guo WB, Li H, Shen L, Chen WY, Yan DW. Improving charge transport property and energy transfer with carbon quantum dots in inverted polymer solar cells. Appl Phys Lett. 2014;105(7):073306.
[17]
Li Y, Hu Y, Zhao Y, Shi GQ, Deng LE, Hou YB, Qu LT. An electrochemical avenue to green-luminescent graphene quantum dots as potential electron-acceptors for photovoltaics. Adv Mater. 2011;23(6):776.
[18]
Ge JC, Jia QY, Liu WM, Guo L, Liu QY, Lan MH, Zhang HY, Meng XM, Wang PF. Red-emissive carbon dots for fluorescent, photoacoustic, and thermal theranostics in living mice. Adv Mater. 2015;27(28):4169.
[19]
Zheng M, Ruan SB, Liu S, Sun TT, Qu D, Zhao HF, Xie ZG, Gao HL, Jing XB, Sun ZC. Self-targeting fluorescent carbon dots for diagnosis of brain cancer cells. ACS Nano. 2015;9(11):11455.
[20]
Zheng M, Liu S, Li J, Qu D, Zhao HF, Guan XG, Hu XL, Xie ZG, Jing XB, Sun ZC. Integrating oxaliplatin with highly luminescent carbon dots: an unprecedented theranostic agent for personalized medicine. Adv Mater. 2014;26(21):3554.
[21]
Huang XL, Zhang F, Zhu L, Choi KY, Guo N, Guo JX, Tackett K, Anilkumar P, Liu G, Quan QM, Choi HS, Niu G, Sun YP, Lee S, Chen XY. Effect of injection routes on the biodistribution, clearance, and tumor uptake of carbon dots. ACS Nano. 2013;7(7):5684.
[22]
Feng T, Ai XZ, An GH, Yang PP, Zhao YL. Charge-convertible carbon dots for imaging-guided drug delivery with enhanced in vivo cancer therapeutic efficiency. ACS Nano. 2016;10(4):4410.
[23]
Choi Y, Kim S, Choi MH, Ryoo SR, Park J, Min DH, Kim BS. Highly biocompatible carbon nanodots for simultaneous bioimaging and targeted photodynamic therapy in vitro and in vivo. Adv Funct Mater. 2014;24(37):5781.
[24]
Luo PJG, Sahu S, Yang ST, Sonkar SK, Wang JP, Wang HF, LeCroy GE, Cao L, Sun YP. Carbon “quantum” dots for optical bioimaging. J Mater Chem B. 2013;1(16):2116.
[25]
Miao P, Han K, Tang YG, Wang BD, Lin T, Cheng WB. Recent advances in carbon nanodots: synthesis, properties and biomedical applications. Nanoscale. 2015;7(5):1586.
[26]
Liu WJ, Li C, Ren YJ, Sun XB, Pan W, Li YH, Wang JP, Wang WJ. Carbon dots: surface engineering and applications. J Mater Chem B. 2016;4(35):5772.
[27]
Lu S, Sui L, Liu J, Zhu S, Chen A, Jin M, Yang B. Near-infrared photoluminescent polymer-carbon nanodots with two-photon fluorescence. Adv Mater. 2017;29(15):1603443.
[28]
Ko HY, Chang YW, Paramasivam G, Jeong MS, Cho SJ, Kim SH. In vivo imaging of tumour bearing near-infrared fluorescence-emitting carbon nanodots derived from tire soot. Chem Commun. 2013;49(87):10290.
[29]
Qu D, Sun ZC, Zheng M, Li J, Zhang YQ, Zhang GQ, Zhao HF, Liu XY, Xie ZG. Three colors emission from S, N co-doped graphene quantum dots for visible light H2 production and bioimaging. Adv Opt Mater. 2015;3(3):360.
[30]
Jiang K, Sun S, Zhang L, Lu Y, Wu AG, Cai CZ, Lin HW. Red, green, and blue luminescence by carbon dots: full-color emission tuning and multicolor cellular imaging. Angew Chem Int Ed. 2015;54(18):5360.
[31]
Sun S, Zhang L, Jiang K, Wu AG, Lin HW. Toward high-efficient red emissive carbon dots: facile preparation, unique properties, and applications as multifunctional theranostic agents. Chem Mater. 2016;28(23):8659.
[32]
Pan LL, Sun S, Zhang AD, Jiang K, Zhang L, Dong CQ, Huang Q, Wu AG, Lin HW. Truly fluorescent excitation-dependent carbon dots and their applications in multicolor cellular imaging and multidimensional sensing. Adv Mater. 2015;27(47):7782.
[33]
Miao XA, Yan XL, Qu D, Li DB, Tao FF, Sun ZC. Red emissive sulfur, nitrogen codoped carbon dots and their application in ion detection and theraonostics. ACS Appl Mater Interfaces. 2017;9(22):18549.
[34]
Yang L, Jiang WH, Qiu LP, Jiang XW, Zuo DY, Wang DK, Yang L. One pot synthesis of highly luminescent polyethylene glycol anchored carbon dots functionalized with a nuclear localization signal peptide for cell nucleus imaging. Nanoscale. 2015;7(14):6104.
[35]
Chen PC, Chen YN, Hsu PC, Shih CC, Chang HT. Photoluminescent organosilane-functionalized carbon dots as temperature probes. Chem Commun. 2013;49(16):1639.
[36]
Xu Q, Kuang TR, Liu Y, Cai LL, Peng XF, Sreeprasad TS, Zhao P, Yu ZQ, Li N. Heteroatom-doped carbon dots: synthesis, characterization, properties, photoluminescence mechanism and biological applications. J Mater Chem B. 2016;4(45):7204.
[37]
Li W, Zhang ZH, Kong BA, Feng SS, Wang JX, Wang LZ, Yang JP, Zhang F, Wu PY, Zhao DY. Simple and green synthesis of nitrogen-doped photoluminescent carbonaceous nanospheres for bioimaging. Angew Chem Int Ed. 2013;52(31):8151.
[38]
Chandra S, Patra P, Pathan SH, Roy S, Mitra S, Layek A, Bhar R, Pramanik P, Goswami A. Luminescent S-doped carbon dots: an emergent architecture for multimodal applications. J Mater Chem B. 2013;1(18):2375.
[39]
Dong YQ, Pang HC, Yang HB, Guo CX, Shao JW, Chi YW, Li CM, Yu T. Carbon-based dots co-doped with nitrogen and sulfur for high quantum yield and excitation-independent emission. Angew Chem Int Ed. 2013;52(30):7800.
[40]
Liu ZX, Chen BB, Liu ML, Zou HY, Huang CZ. Cu(I)-doped carbon quantum dots with zigzag edge structures for highly efficient catalysis of azide-alkyne cycloadditions. Green Chem. 2017;19(6):1479.
[41]
Wang TY, Chen CY, Wang CM, Tan YZ, Liao WS. Multicolor functional carbon dots via one-step refluxing synthesis. ACS Sens. 2017;2(3):354.
[42]
Jiang K, Sun S, Zhang L, Wang YH, Cai CZ, Lin HW. Bright-yellow-emissive N-doped carbon dots: preparation, cellular imaging, and bifunctional sensing. ACS Appl Mater Interfaces. 2015;7(41):23231.
[43]
Li XM, Zhang SL, Kulinich SA, Liu YL, Zeng HB. Engineering surface states of carbon dots to achieve controllable luminescence for solid-luminescent composites and sensitive Be2+ detection. Sci Rep. 2014;4(4):4976.
[44]
Nie H, Li MJ, Li QS, Liang SJ, Tan YY, Sheng L, Shi W, Zhang SXA. Carbon dots with continuously tunable full-color emission and their application in ratiometric pH sensing. Chem Mater. 2014;26(10):3104.
[45]
Chen L, Song LP, Zhang YC, Wang P, Xiao ZD, Guo YG, Cao FF. Nitrogen and sulfur codoped reduced graphene oxide as a general platform for rapid and sensitive fluorescent detection of biological species. ACS Appl Mater Interfaces. 2016;8(18):11255.
[46]
Yang Y, Cui J, Zheng M, Hu C, Tan S, Xiao Y, Yang Q, Liu Y. One-step synthesis of amino-functionalized fluorescent carbon nanoparticles by hydrothermal carbonization of chitosan. Chem Commun (Camb). 2012;48(3):380.
[47]
Qian Z, Ma J, Shan X, Feng H, Shao L, Chen J. Highly luminescent N-doped carbon quantum dots as an effective multifunctional fluorescence sensing platform. Chemistry. 2014;20(8):2254.
[48]
Ding H, Ji Y, Wei JS, Gao QY, Zhou ZY, Xiong HM. Facile synthesis of red-emitting carbon dots from pulp-free lemon juice for bioimaging. J Mater Chem B. 2017;5(26):5272.
[49]
Reckmeier CJ, Wang Y, Zboril R, Rogach AL. Influence of doping and temperature on solvatochromic shifts in optical spectra of carbon dots. J Phys Chem C. 2016;120(19):10591.
[50]
Liu YH, Duan WX, Song W, Liu JJ, Ren CL, Wu J, Liu D, Chen HL. Red emission B, N, S-co-doped carbon dots for colorimetric and fluorescent dual mode detection of Fe3+ ions in complex biological fluids and living cells. ACS Appl Mater Interfaces. 2017;9(14):12663.
[51]
Zhu SJ, Song YB, Zhao XH, Shao JR, Zhang JH, Yang B. The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): current state and future perspective. Nano Res. 2015;8(2):355.
[52]
Baker RD, Greer FR, Nutr C. Clinical report-diagnosis and prevention of iron deficiency and iron-deficiency anemia in infants and young children (0–3 years of age). Pediatrics. 2010;126(5):1040.
[53]
Torti SV, Torti FM. Iron and cancer: more ore to be mined. Nat Rev Cancer. 2013;13(5):342.
Metadaten
Titel
Dual-property blue and red emission carbon dots for Fe(III) ions detection and cellular imaging
verfasst von
Yin-Long Xu
Rui-Xue Mo
Cai-Yu Qi
Zeng Ren
Xiu-Zhi Jia
Zi-Gui Kan
Cao-Long Li
Fei Wang
Publikationsdatum
20.08.2020
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 7/2021
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01506-1

Weitere Artikel der Ausgabe 7/2021

Rare Metals 7/2021 Zur Ausgabe

Original Article

Equilibrium and mechanism studies of gold(I) extraction from alkaline aurocyanide solution by using fluorine-free ionic liquids

OriginalPaper

Synthesis and formation mechanism of nanocrystalline ZrB2–Al2O3 composite powders via an amorphous precursor

OriginalPaper

Microstructure and mechanical properties of TC4 joints brazed with Ti–Zr–Cu–Sn amorphous filler alloy

Original Article

Hot pressing sintering process and sintering mechanism of W–La2O3–Y2O3–ZrO2

Original Article

Using highly concentrated chloride solutions to leach valuable metals from cathode-active materials in spent lithium-ion batteries

OriginalPaper

The tetragonal-like distortion of Fe–Ga alloys interstitial doped with Cu

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise