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Rare Metals
Erschienen in: Rare Metals 2/2021

08.08.2020 | Original Article

Self-assembly synthesis of SnNb2O6/amino-functionalized graphene nanocomposite as high-rate anode materials for sodium-ion batteries

verfasst von: Min Huang, Ji-Xin Liu, Peng Huang, Hai Hu, Chao Lai

Erschienen in: Rare Metals | Ausgabe 2/2021

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Abstract

A two-dimensional (2D) SnNb2O6/amino-functionalized graphene (En-RGO) nanocomposite with a representative 2D–2D architecture has been constructed by an easy self-assembly approach and firstly investigated as anode materials for secondary sodium-ion batteries. The SnNb2O6 nanosheets are evenly anchored with the amino-functionalized graphene through electrostatic attractive interplay between the negatively charged SnNb2O6 and positively charged En-RGO after modification. As a result, a remarkable reversible capacity of 300 mAh·g−1 was obtained at 50 mA·g−1, and significantly, the En-RGO electrode could also deliver ultra-long calendar life up to 1900 cycles with a high reversible capacity of 200 mAh·g−1 at current of 500 mA·g−1. Such excellent electrochemical characteristics can be mainly ascribed to its fast pseudo-capacitive energy storage mechanism, and the capacitive contribution can even reach up to 90% at 1.2 mV·s−1.

Graphic abstract

Vorheriger Artikel Promoting performance of lithium–sulfur battery via in situ sulfur reduced graphite oxide coating
Nächster Artikel Stable sodium metal anode enhanced by advanced electrolytes with SbF3 additive

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Metadaten
Titel
Self-assembly synthesis of SnNb2O6/amino-functionalized graphene nanocomposite as high-rate anode materials for sodium-ion batteries
verfasst von
Min Huang
Ji-Xin Liu
Peng Huang
Hai Hu
Chao Lai
Publikationsdatum
08.08.2020
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 2/2021
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01527-w

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