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2013 | OriginalPaper | Buchkapitel

8. Lithium Ion Batteries, Electrochemical Reactions in

verfasst von : Paul J. Sideris, Steve G. Greenbaum

Erschienen in: Batteries for Sustainability

Verlag: Springer New York

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Abstract

Despite their spectacular success in portable electronics applications, continued technical advances of lithium-ion batteries are crucial to establishing large-scale storage applications such as electric vehicles and enabling development of renewable intermittent energy sources, i.e., wind and solar. Paramount considerations in realizing scaled-up battery systems are safety, cost, energy density, and service lifetime. Some of these applications also require rapid charge and discharge capability. To move beyond the current generation of lithium-ion batteries, it is necessary to understand some of the outstanding materials issues of the individual components (i.e., electrodes and electrolytes) as well as the battery system as a whole where the components interact under conditions of elevated temperature and electric current flow.

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Vorheriges Kapitel Lithium Battery Electrolyte Stability and Performance from Molecular Modeling and Simulations

Nächstes Kapitel Lithium-Ion Batteries, Safety

Goodenough J, Kim Y (2010) Challenges for rechargeable Li batteries. Chem Mater 22:587–603CrossRef

Whittingham MS (1976) Electrical energy storage and intercalation chemistry. Science 192(4244):1126–1127CrossRef

Dahn JR, von Sacken U, Juzkow MW, Al-Janaby H (1991) Rechargeable LiNiO₂/carbon cells. J Electrochem Soc 138:2207–2211CrossRef

Delmas C, Peres J, Rougier A, Demourgues A, Weill F, Chadwick A, Broussely M, Perton F, Biensan P, Willmann P (1997) On the behavior of the Li_xNiO₂ system: an electrochemical and structural overview. J Power Sources 68(1):120–125CrossRef

Saadoune I, Delmas C (1996) LiNi_1–yCo_yO₂ positive electrode materials: relationships between the structure, physical properties and electrochemical behaviour. J Mater Chem 6(2):193–199CrossRef

Capitaine F, Gravereau P, Delmas C (1996) A new variety of LiMnO₂ with a layered structure. Solid State Ion 89(3–4):197–202CrossRef

Rossen E, Jones C, Dahn J (1992) Structure and electrochemistry of Li_xMn_yNi_1–yO₂. Solid State Ion 57(3–4):311–318CrossRef

Liu Z, Yu A, Lee J (1999) Synthesis and characterization of LiNi_1–x–yCo_xMn_yO₂ as the cathode materials of secondary lithium batteries. J Power Sources 82:416–419CrossRef

Yoshio M, Noguchi H, Itoh J, Okada M, Mouri T (2000) Preparation and properties of LiCo_yMn_xNi_1–x–yO₂ as a cathode for lithium ion batteries. J Power Sources 90(2):176–181CrossRef

10.

Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon JM (2000) Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries. Nature 407(6803):496–499CrossRef

11.

Li H, Richter G, Maier J (2003) Reversible formation and decomposition of LiF clusters using transition metal fluorides as precursors and their application in rechargeable Li batteries. Adv Mater 15(9):736–739 (Weinheim, Germany)CrossRef

12.

Li H, Balaya P, Maier J (2004) Li-storage via heterogeneous reaction in selected binary metal fluorides and oxides. J Electrochem Soc 151(11):A1878–A1885CrossRef

13.

Badway F, Cosandey F, Pereira N, Amatucci G (2003) Carbon metal fluoride nanocomposites – high-capacity reversible metal fluoride conversion materials as rechargeable positive electrodes for Li batteries. J Electrochem Soc 150(10):A1318–A1327CrossRef

14.

Badway F, Pereira N, Cosandey F, Amatucci G (2003) Carbon-metal fluoride nanocomposites – structure and electrochemistry of FeF₃: C. J Electrochem Soc 150(9):A1209–A1218CrossRef

15.

Badway F, Mansour A, Pereira N, Al-Sharab J, Cosandey F, Plitz I, Amatucci G (2007) Structure and electrochemistry of copper fluoride nanocomposites utilizing mixed conducting matrices. Chem Mater 19(17):4129–4141CrossRef

16.

Armand M (1994) The history of polymer electrolytes. Solid State Ion 69:309–319CrossRef

17.

Armand M (1986) Polymer electrolytes. Annu Rev Mater Sci 16:245–261CrossRef

18.

Fenton DE, Parker JM, Wright PV (1973) Complexes of alkali-metal ions with poly(ethylene oxide). Polymer 14(11):589CrossRef

19.

Tarascon J-M, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414:359–367CrossRef

20.

Myung ST, Komaba S, Hirosaki N, Yashiro H, Kumagai N (2004) Emulsion drying synthesis of olivine LiFePO₄/C composite and its electrochemical properties as lithium intercalation material. Electrochim Acta 49(24):4213–4222CrossRef

21.

Rietveld HM (1969) A profile refinement method for nuclear and magnetic structures. J Appl Crystallogr 2:65–71CrossRef

22.

Proffen T, Billinge SJL (1999) PDFFIT, a program for full profile structural refinement of the atomic pair distribution function. J Appl Crystallogr 32:572–575CrossRef

23.

McGreevy RL, Pusztai L (1988) Reverse monte carlo simulation: a new technique for the determination of disordered structures. Mol Simul 1:359–367CrossRef

24.

Dedryvere R, Laruelle S, Grugeon S, Poizot P, Gonbeau D, Tarascon JM (2004) Contribution of X-ray photoelectron spectroscopy to the study of the electrochemical reactivity of CoO toward lithium. Chem Mater 16(6):1056–1061CrossRef

25.

Alamgir FM, Petersburg CF, Daniel RC, Jaye C, Fischer DA (2009) Soft X-ray characterization technique for Li batteries under operating conditions. J Synchrotron Radiat 16:610–615CrossRef

26.

Stern EA (1974) Theory of extended X-Ray-absorption fine-structure. Phys Rev B 10(8):3027–3037CrossRef

27.

Sayers DE, Stern EA, Lytle FW (1971) New technique for investigating noncrystalline structures – Fourier analysis of extended X-ray – absorption fine structure. Phys Rev Lett 27(18):1204–1207CrossRef

28.

Tsai YW, Hwang BJ, Ceder G, Sheu HS, Liu DG, Lee JF (2005) In-situ X-ray absorption spectroscopic study on variation of electronic transitions and local structure of LiNi_1/3Co_1/3Mn_1/3O₂ cathode material during electrochemical cycling. Chem Mater 17(12):3191–3199CrossRef

29.

Yoon W, Kim N, Yang X, McBreen J, Grey C (2003) Li-6 MAS NMR and in situ X-ray studies of lithium nickel manganese oxides. J Power Sources 119:649–653CrossRef

30.

Grey CP, Lee YJ (2003) Lithium MAS NMR studies of cathode materials for lithium-ion batteries. Solid State Sci 5(6):883–894CrossRef

31.

Carlier D, Menetrier M, Grey C, Delmas C, Ceder G (2003) Understanding the NMR shifts in paramagnetic transition metal oxides using density functional theory calculations. Phys Rev B 67 174103:1–14

32.

Letellier M, Chevallier F, Beguin F, Frackowiak E, Rouzaud J (2004) The first in situ Li-7 NMR study of the reversible lithium insertion mechanism in disorganised carbons. J Phys Chem Solids 65(2–3):245–251CrossRef

33.

Levitt MH (2001) Spin dynamics: basics of nuclear magnetic resonance. Wiley, New York

34.

Slichter CP (1990) Principles of nuclear magnetic resonance. Springer, Berlin

35.

Stejskal E, Tanner J (1965) Spin diffusion measurements: spin echoes in the presence of a time-dependent field gradient. J Chem Phys 42:288–292CrossRef

36.

Kimmich R, Unrath W, Schnur G, Rommel E (1991) NMR measurement of small self-diffusion coefficients in the fringe-field of superconducting magnets. J Magn Reson 91(1):136–140

37.

Demco D, Johansson A, Tegenfeldt J (1994) Constant-relaxation methods for diffusion measurements in the fringe-field of superconducting magnets. J Magn Reson Ser A 110(2):183–193CrossRef

38.

Gorecki W, Jeannin M, Belorizky E, Roux C, Armand M (1995) Physical properties of solid polymer electrolyte PEO(LiTFSI) complexes. J Phys Cond Matter 7(34):6823–6832CrossRef

39.

Johansson A, Gogoll A, Tegenfeldt J (1996) Diffusion and ionic conductivity in Li(CF₃SO₃)PEG(10) and LiN(CF₃SO₂)(2)PEG(10). Polymer 37(8):1387–1393CrossRef

40.

Hayamizu K, Aihara Y, Price W (2000) Correlating the NMR self-diffusion and relaxation measurements with ionic conductivity in polymer electrolytes composed of cross-linked poly(ethylene oxide-propylene oxide) doped with LiN(SO₂CF₃)(2). J Chem Phys 113(11):4785–4793CrossRef

41.

Hayamizu K, Aihara Y, Price W (2001) NMR and ion conductivity studies on cross-linked poly(ethyleneoxide-propyleneoxide) and branched polyether doped with LiN(SO₂CF₃)(2). Electrochim Acta 46(10–11):1475–1485CrossRef

42.

Adebahr J, Forsyth M, Gavelin P, Jacobsson P, Oradd G (2002) Ion and solvent dynamics in gel electrolytes based on ethylene oxide grafted acrylate polymers. J Phys Chem B 106(47):12119–12123CrossRef

43.

Gorecki W, Roux C, Clemancey M, Armand M, Belorizky E (2002) NMR and conductivity study of polymer electrolytes in the imide family: P(EO)/Li[N(SO₂CnF2n + 1)(SO₂CmF2m + 1)]. Chemphyschem 3(7):620–625CrossRef

44.

Croce F, Appetecchi G, Persi L, Scrosati B (1998) Nanocomposite polymer electrolytes for lithium batteries. Nature 394:456–458CrossRef

45.

Zhou F, MacFarlane D, Forsyth M (2003) Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes. Electrochim Acta 48(12):1749–1758CrossRef

46.

Kalita M, Bukat M, Ciosek M, Siekierski M, Chung S, Rodriguez T, Greenbaum S, Kovarsky R, Golodnitsky D, Peled E, Zane D, Scrosati B, Wieczorek W (2005) Effect of calixpyrrole in PEO-LiBF₄ polymer electrolytes. Electrochimia Acta 50(19):3942–3948CrossRef

47.

Koudriachova MV, Harrison NM, de Leeuw SW (2002) Density-functional simulations of lithium intercalation in rutile. Phys Rev B 65 235423:1–12

48.

Kang K, Ceder G (2006) Factors that affect Li mobility in layered lithium transition metal oxides. Phys Rev B 74 094105:1–7

49.

Tibbetts K, Miranda CR, Meng YS, Ceder G (2007) An ab initio study of lithium diffusion in titanium disulfide nanotubes. Chem Mater 19(22):5302–5308CrossRef

50.

Aydinol MK, Kohan AF, Ceder G, Cho K, Joannopoulos J (1997) Ab initio study of lithium intercalation in metal oxides and metal dichalcogenides. Phys Rev B 56(3):1354–1365CrossRef

51.

Courtney IA, Tse JS, Mao O, Hafner J, Dahn JR (1998) Ab initio calculation of the lithium-tin voltage profile. Phys Rev B 58(23):15583–15588CrossRef

52.

Meng YS, Wu YW, Hwang BJ, Li Y, Ceder G (2004) Combining ab initio computation with experiments for designing new electrode materials for advanced lithium batteries: LiNi_1/3Fe_1/6Co_1/6Mn_1/3O₂. J Electrochem Soc 151(8):A1134–A1140CrossRef

53.

Arroyo-DeDompablo ME, Van der Ven A, Ceder G (2002) First-principles calculations of lithium ordering and phase stability on Li_xNiO₂. Phys Rev B 66 064112:1–9

54.

Wolverton C, Zunger A (1998) Prediction of Li intercalation and battery voltages in layered versus cubic Li_xCoO₂. J Electrochem Soc 145(7):2424–2431CrossRef

55.

Hwang B, Tsai Y, Carlier D, Ceder G (2003) A combined computational/experimental study on LiNi_1/3Co_1/3Mn_1/3O₂. Chem Mater 15(19):3676–3682CrossRef

56.

Kganyago KR, Ngoepe PE, Catlow CRA (2003) Ab initio calculation of the voltage profile for LiC₆. Solid State Ion 159(1–2):21–23CrossRef

57.

Launay M, Boucher F, Gressier P, Ouvrard G (2003) A DFT study of lithium battery materials: application to the β-VOXO4 systems (X = P, As, S). J Solid State Chem 176(2):556–566CrossRef

58.

Zhou F, Cococcioni M, Marianetti CA, Morgan D, Ceder G (2004) First-principles prediction of redox potentials in transition-metal compounds with LDA + U. Phys Rev B 70 235121:1–8

59.

Reed J, Ceder G (2002) Charge, potential, and phase stability of layered Li(Ni0.5Mn0.5)O-2. Electrochem State Lett 5(7):A145–A148CrossRef

60.

Arroyo-DeDompablo ME, Ceder G (2003) First-principles calculations on Li_xNiO₂: phase stability and monoclinic distortion. J Power Sources 119121:654–657CrossRef

61.

Carlier D, Van der Ven A, Delmas C, Ceder G (2003) First-principles investigation of phase stability in the O-2-LiCoO₂ system. Chem Mater 15(13):2651–2660CrossRef

62.

Perdew JP, Burke K, Ernzerhof M (1996) Generalized gradient approximation made simple. Phys Rev Lett 77(18):3865–3868CrossRef

63.

Blochl PE (1994) Projector augmented-wave method. Phys Rev B 50(24):17953–17979CrossRef

64.

Kresse G, Joubert J (1999) From ultrasoft pseudopotentials to the projector augmented-wave method. Phys Rev B 59(3):1758–1775CrossRef

65.

Kresse G, Furthmuller J (1996) Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys Rev B 54(16):11169–11186CrossRef

66.

Bar-Tow D, Peled E, Burstein L (1999) A study of highly oriented pyrolytic graphite as a model for the graphite anode in Li-ion batteries. J Electrochem Soc 146(3):824–832CrossRef

67.

Peled E, Tow DB, Merson A, Gladkich A, Burstein L, Golodnitsky D (2001) Composition, depth profiles and lateral distribution of materials in the SEI built on HOPG-TOF SIMS and XPS studies. J Power Sources 97–98:52–57CrossRef

68.

Lu M, Cheng H, Yang Y (2008) A comparison of solid electrolyte interphase (SEI) on the artificial graphite anode of the aged and cycled commercial lithium ion cells. Electrochim Acta 53(9):3539–3546CrossRef

69.

Peled E, Golodnitsky D, Ulus A, Yufit V (2004) Effect of carbon substrate on SEI composition and morphology. Electrochim Acta 50(2–3):391–395CrossRef

70.

Ota H, Kominato A, Chun WJ, Yasukawa E, Kasuya S (2003) Effect of cyclic phosphate additive in non-flammable electrolyte. J Power Sources 119:393–398CrossRef

71.

Andersson AM, Edstrom K (2001) Chemical composition and morphology of the elevated temperature SEI on graphite. J Electrochem Soc 148(10):A1100–A1109CrossRef

72.

Andersson AM, Edstrom K, Rao N, Wendsjo A (1999) Temperature dependence of the passivation layer on graphite. J Power Sources 82:286–290CrossRef

73.

Meyer BM, Leifer N, Sakamoto S, Greenbaum SG, Grey CP (2005) High field multinuclear NMR investigation of the SEI layer in lithium rechargeable batteries. Electrochem Solid State Lett 8(3):A145–A148CrossRef

74.

Dupre N, Martin JF, Degryse J, Fernandez V, Soudan P, Guyomard D (2010) Aging of the LiFePO₄ positive electrode interface in electrolyte. J Power Sources 195(21):7415–7425CrossRef

75.

Dupre N, Martin J, Oliveri J, Soudan P, Guyomard D, Yamada A, Kanno R (2009) Aging of the LiNi_1/2Mn_1/2O₂ positive electrode interface in electrolyte. J Electrochem Soc 156(5):C180–C185CrossRef

76.

Dupre N, Martin JF, Guyomard D, Yamada A, Kanno R (2008) Detection of surface layers using Li-7 MAS NMR. J Mater Chem 18(36):4266–4273CrossRef

77.

Leifer N, Smart MC, Prakash GKS, Gonzalez L, Sanchez L, Smith KA, Bhalla P, Grey CP, Greenbaum SG (2011) 13C solid state NMR suggests unusual breakdown products in SEI formation on lithium ion electrodes. J Electrochem Soc 158(5):A471–A480CrossRef

78.

Fernicola A, Weise F, Greenbaum S, Kagimoto J, Scrosati B, Soleto A (2009) Lithium-ion-conducting electrolytes: from an ionic liquid to the polymer membrane. J Electrochem Soc 156(7):A514–A520CrossRef

79.

Scrosati B (1995) Battery technology – challenge of portable power. Nature 373:557–558CrossRef

80.

Gray FM (1991) Solid polymer electrolytes: fundamentals and electrochemical applications. VCH, New York

81.

Kalita M, Bukat M, Ciosek M, Siekierski M, Chung SH, Rodriguez T, Greenbaum SG, Kovarsky R, Golodnitsky D, Peled E, Zane D, Scrosati B, Wieczorek W (2005) Effect of calixpyrrole in PEO-LiBF₄ polymer electrolytes. Electrochim Acta 50(19):3942–3948CrossRef

82.

Periasamy P, Tatsumi K, Shikano M, Fujieda T, Saito Y, Sakai T, Mizuhata M, Kajinami A, Deki S (2000) Studies on PVdF-based gel polymer electrolytes. J Power Sources 88(2):269–273CrossRef

83.

Pawlowska A, Zukowska G, Kalita M, Solgala A, Parzuchowski P, Siekierski M (2007) The effect of receptor-polymer matrix compatibility on properties of PEO-based polymer electrolytes containing a supramolecular additive. Part 1. Studies on phenomenon of compatibility. J Power Sources 173(2):755–764CrossRef

84.

Bloise A, Donoso J, Magon C, Rosario A, Pereira E (2003) NMR and conductivity study of PEO-based composite polymer electrolytes. Electrochim Acta 48(14–16):2239–2246CrossRef

85.

Masuda Y, Seki M, Nakayama M, Wakihara M, Mita H (2006) Study on ionic conductivity of polymer electrolyte plasticized with PEG-aluminate ester for rechargeable lithium ion battery. Solid State Ion 117(9–10):843–846CrossRef

86.

Dai Y, Wang Y, Greenbaum S, Bajue S, Golodnitsky D, Ardel G, Strauss E, Peled E (1998) Electrical, thermal and NMR investigation of composite solid electrolytes based on PEO, LiI and high surface area inorganic oxides. Electrochim Acta 43(10–11):1557–1561CrossRef

87.

Best A, Adebahr J, Jacobsson P, MacFarlane D, Forsyth M (2001) Microscopic interactions in nanocomposite electrolytes. Macromolecules 34(13):4549–4555CrossRef

88.

Adebahr J, Best A, Byrne N, Jacobsson P, MacFarlane D, Forsyth M (2003) Ion transport in polymer electrolytes containing nanoparticulate TiO₂: The influence of polymer morphology. Phys Chem Chem Phys 5:720–725CrossRef

89.

Berthier C, Gorecki W, Minier M, Armand M, Chabagno J, Rigaud P (1983) Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts. Solid State Ion 11(1):91–95CrossRef

90.

Chung S, Jeffrey K, Stevens J (1991) A Li-7 nuclear magnetic resonance study of LiCF₃SO₃ complexed in poly(propylene-glycol). J Chem Phys 94(3):1803–1811CrossRef

91.

Donoso J, Bonagamba T, Panepucci H, Oliveira L, Gorecki W, Berthier C, Armand M (1993) Nuclear magnetic relaxation study of poly(ethylene oxide)-lithium salt based electrolytes. J Chem Phys 98(12):10026–10036CrossRef

92.

Johansson A, Tegenfeldt J (1996) Segmental mobility in complexes of Pb(CF₃SO₃)(2) and poly(ethylene oxide) studied by NMR spectroscopy. J Chem Phys 104(13):5317–5325CrossRef

93.

Chung S, Wang Y, Greenbaum S, Golodnitsky D, Peled E (1999) Uniaxial stress effects in poly(ethylene oxide)-LiI polymer electrolyte film – a Li-7 nuclear magnetic resonance study. Electrochem Solid State Lett 2(11):553–555CrossRef

94.

Golodnitsky D, Livshits E, Kovarsky R, Peled E, Chung S, Suarez S, Greenbaum S (2004) New generation of ordered polymer electrolytes for lithium batteries. Electrochem Solid State Lett 7(11):A412–A415CrossRef

95.

Golodnitsky D, Livshits E, Ulus A, Barkay Z, Lapides I, Peled E, Chung S, Greenbaum S (2001) Fast ion transport phenomena in oriented semicrystalline LiI-P(EO)n-based polymer electrolytes. J Phys Chem A 105(44):10098–10106CrossRef

96.

Armand MB, Chabagno JM, Duclot MJ (1979) Fast ion transport in solids. Elsevier, New York

97.

Gadjourova Z, Andreev Y, Tunstall D, Bruce P (2001) Ionic conductivity in crystalline polymer electrolytes. Nature 412:520–523CrossRef

98.

Padhi A, Nanjundaswamy K, Goodenough J (1997) Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc 144(4):1188–1194CrossRef

99.

Morgan D, Van der Ven A, Ceder G (2004) Li conductivity in Li_xMPO₄ (M=Mn, Fe, Co, Ni) olivine materials. Electrochem Solid State Lett 7(2):A30–A32CrossRef

100.

Yamada A, Chung S, Hinokuma K (2001) Optimized LiFePO₄ for lithium battery cathodes. J Electrochem Soc 148(3):A224–A229CrossRef

101.

Padhi A, Nanjundaswamy K, Masquelier C, Okada S, Goodenough J (1997) Effect of structure on the Fe³⁺/Fe²⁺ redox couple in iron phosphates. J Electrochem Soc 144(5):1609–1613CrossRef

102.

Tucker M, Doeff M, Richardson T, Finones R, Cairns E, Reimer J (2002) Hyperfine fields at the Li site in LiFePO4-type olivine materials for lithium rechargeable batteries: a Li-7 MAS NMR and SQUID study. J Am Chem Soc 124(15):3832–3833CrossRef

103.

Gee B, Horne CR, Cairns EJ, Reimer JA (1998) Supertransferred hyperfine fields at Li-7: Variable temperature Li-7 NMR studies of LiMn₂O₄-based spinels. J Phys Chem B 102(50):10142–10149CrossRef

104.

Wilcke SL, Lee YJ, Cairns EJ, Reimer JA (2007) Covalency measurements via NMR in lithium metal phosphates. Appl Magn Reson 32(4):547–563CrossRef

105.

Leifer N, Colon A, Martocci K, Greenbaum S, Alamgir F, Reddy T, Gleason N, Leising R, Takeuchi E (2007) Nuclear magnetic resonance and X-ray absorption spectroscopic studies of lithium insertion in silver vanadium oxide cathodes. J Electrochem Soc 154(6):A500–A506CrossRef

106.

Crespi A, Skarstad P, Zandbergen H (1995) Characterization of silver vanadium oxide cathode material by high-resolution electron microscopy. J Power Sources 54(1):68–71CrossRef

107.

Takeuchi K, Marschilok A, Davis S, Leising R, Takeuchi E (2001) Silver vanadium oxides and related battery applications. Coord Chem Rev 219–221:283–310CrossRef

108.

Ramasamy R, Feger C, Strange T, Popov B (2006) Discharge characteristics of silver vanadium oxide cathodes. J Appl Electrochem 36(4):487–497CrossRef

109.

Vijayakumar M, Selvasekarapandian S, Nakamura K, Kanashiro T, Kesavamoorthy R (2004) Li-7 MAS-NMR and vibrational spectroscopic investigations of Li_xV₂O₅ (x = 10, 12 and 14). Solid State Ion 167(1–2):41–47CrossRef

110.

Holland G, Buttry D, Yarger J (2002) Li-7 NMR studies of electrochemically lithiated V₂O₅ xerogels. Chem Mater 14(9):3875–3881CrossRef

111.

Holland G, Yarger J, Buttry D, Huguenin F, Torresi R (2003) Solid-state NMR study of ion-exchange processes in V₂O₅ xerogel, polyaniline/V₂O₅, and sulfonated polyaniline/V₂O₅ nanocomposites. J Electrochem Soc 150(12):A1718–A1722CrossRef

112.

Nakamura K, Nishioka D, Michihiro Y, Vijayakumar M, Selvasekarapandian S, Kanashiro T (2006) Li-7 and V-51 NMR study on Li+ ionic diffusion in lithium intercalated Li_xV₂O₅. Solid State Ion 177(1–2):129–135CrossRef

113.

West K, Crespi A (1995) Lithium insertion into silver vanadium-oxide, Ag₂V₄O₁₁. J Power Sources 54(2):334–337CrossRef

114.

Rozier P, Galy J (1997) Ag_1.2V₃O₈ crystal structure: Relationship with Ag₂V₄O_11–y interpretation of physical properties. J Solid State Chem 134(2):294–301CrossRef

115.

Rozier P, Savariault J, Galy J, Marichal C, Hirschinger J, Granger P (1996) Epsilon-Li_xV₂O₅ bronzes (0.33 ≤ × ≤ 0.64) a joint study by X-ray powder diffraction and 6Li, 7Li MAS NMR. Eur J Solid State Inorg Chem 33(1):1–13

116.

Kuwabara K, Itoh M, Sugiyama K (1986) Ionic-electronic mixed conduction in Li_xV₂O₅. Solid State Ion 20(2):135–139CrossRef

117.

Garcia-Alvarado F, Tarascon J (1994) Lithium intercalation in Ag₂V₄O₁₁. Solid State Ion 73(3–4):247–254CrossRef

118.

Stallworth P, Kostov S, denBoer M, Greenbaum S, Lampe-Onnerud C (1998) X-ray absorption and magnetic resonance spectroscopic studies of Li_xV₆O₁₃. J Appl Phys 83(3):1247–1255CrossRef

119.

Yamakawa N, Jiang M, Grey CP (2009) Investigation of the conversion reaction mechanisms for binary copper(II) compounds by solid-state NMR spectroscopy and X-ray diffraction. Chem Mater 21(14):3162–3176CrossRef

120.

Yamakawa N, Jiang M, Key B, Grey CP (2009) Identifying the local structures formed during lithiation of the conversion material, iron fluoride, in a Li ion battery: a solid-state NMR, X-ray diffraction, and pair distribution function analysis study. J Am Chem Soc 131(30):10525–10536CrossRef

121.

Chung JS, Sohn HJ (2002) Electrochemical behaviors of CuS as a cathode material for lithium secondary batteries. J Power Sources 108(1–2):226–231CrossRef

122.

Debart A, Dupont L, Patrice R, Tarascon JM (2006) Reactivity of transition metal (Co, Ni, Cu) sulphides versus lithium: the intriguing case of the copper sulphide. Solid State Sci 8(6):640–651CrossRef

123.

Ikeda H, Narukawa S (1983) Behavior of various cathode materials for non-aqueous lithium cells. J Power Sources 9(3–4):329–334CrossRef

124.

Grugeon S, Laruelle S, Herrera-Urbina R, Dupont L, Poizot P, Tarascon J (2001) Particle size effects on the electrochemical performance of copper oxides toward lithium. J Electrochem Soc 148(4):A285–A292CrossRef

125.

Arai H, Okada S, Sakurai Y, Yamaki J (1997) Cathode performance and voltage estimation of metal trihalides. J Power Sources 68(2):716–719CrossRef

126.

Cosandey F, Al-Sharab J, Badway F, Amatucci G, Stadelmann P (2007) EELS spectroscopy of iron fluorides and FeFx/C nanocomposite electrodes used in Li-ion batteries. Microsc Microanal 13(2):87–95CrossRef

127.

Doe R, Persson K, Meng Y, Ceder G (2008) First-principles investigation of the Li-Fe-F phase diagram and equilibrium and nonequilibrium conversion reactions of iron fluorides with lithium. Chem Mater 20(16):5274–5283CrossRef

128.

Nielsen U, Paik Y, Julmis K, Schoonen M, Reeder R, Grey C (2005) Investigating sorption on iron-oxyhydroxide soil minerals by solid-state NMR spectroscopy: A Li-6 MAS NMR study of adsorption and absorption on goethite. J Phys Chem B 109(39):18310–18315CrossRef

129.

Kim J, Nielsen U, Grey C (2008) Local environments and lithium adsorption on the iron oxyhydroxides lepidocrocite (gamma-FeOOH) and goethite (alpha-FeOOH): A H-2 and Li-7 solid-state MAS NMR study. J Am Chem Soc 130(4):1285–1295CrossRef

130.

Liao P, MacDonald B, Dunlap R, Dahn J (2008) Combinatorially prepared [LiF](1-x)Fe-x nanocomposites for positive electrode materials in Li-ion batteries. Chem Mater 20(2):454–461CrossRef

131.

Breger J, Dupre N, Chupas P, Lee P, Proffen T, Parise J, Grey C (2005) Short- and long-range order in the positive electrode material, Li(NiMn)(0.5)O-2: a joint X-ray and neutron diffraction, pair distribution function analysis and NMR study. J Am Chem Soc 127(20):7529–7537CrossRef

132.

Yoon W, Paik Y, Yang X, Balasubramanian M, McBreen J, Grey C (2002) Investigation of the local structure of the LiNi_0.5Mn_0.5O₂ cathode material during electrochemical cycling by X-ray absorption and NMR spectroscopy. Electrochem Solid State Lett 5(11):A263–A266CrossRef

133.

Yoon W, Iannopollo S, Grey C, Carlier D, Gorman J, Reed J, Ceder G (2004) Local structure and cation ordering in O₃ lithium nickel manganese oxides with stoichiometry Li[Ni_xMn_(2–x)/3Li_(1–2x)/3]O₋₂ – NMR studies and first principles calculations. Electrochem Solid State Lett 7(7):A167–A171CrossRef

134.

Van der Ven A, Ceder G (2004) Ordering in Li_−x(Ni_0.5Mn_0.5)O_–2 and its relation to charge capacity and electrochemical behavior in rechargeable lithium batteries. Electrochem Commun 6(10):1045–1050CrossRef

135.

Meng YS, Ceder G, Grey CP, Yoon W-S, Shao-Horn Y (2004) Understanding the crystal structure of layered LiNi_0.5Mn_0.5O₂ by electron diffraction and powder diffraction simulation. Electrochem Solid State Lett 7(6):A155–A158CrossRef

136.

Cahill LS, Chapman RP, Britten JF, Goward GR (2006) Li-7 NMR and two-dimensional exchange study of lithium dynamics in monoclinic Li₃V₂(PO₄)(3). J Phys Chem B 110(14):7171–7177CrossRef

137.

Matsumura Y, Wang S, Mondori J (1995) Interactions between disordered carbon and lithium in lithium ion rechargeable batteries. Carbon 33(10):1457–1462CrossRef

138.

Wang S, Kakumoto T, Matsui H, Matsumura Y (1999) Mechanism of lithium insertion into disordered carbon. Synth Met 103(1–3):2523–2524CrossRef

139.

Nakagawa Y, Wang S, Matsumura Y, Yamaguchi C (1997) Li-7-NMR study of lithium charged in carbon electrode. Synth Met 85(1–3):1363–1364CrossRef

140.

Conard J, Estrade H (1977) Résonance magnétique nucléaire du lithium interstitiel dans le graphite. Mater Sci Eng 31:173–176CrossRef

141.

Peled E, Menachem C, BarTow D, Melman A (1996) Improved graphite anode for lithium-ion batteries – chemically bonded solid electrolyte interface and nanochannel formation. J Electrochem Soc 143(1):L4–L7CrossRef

142.

Menachem C, Wang Y, Flowers J, Peled E, Greenbaum S (1998) Characterization of lithiated natural graphite before and after mild oxidation. J Power Sources 76(2):180–185CrossRef

143.

Wang Y, Yufit V, Guo X, Peled E, Greenbaum S (2001) Li-7 nuclear magnetic resonance study of lithium insertion in pristine and partially oxidized graphite. J Power Sources 94(2):230–237CrossRef

144.

Gotoh K, Maeda M, Nagai A, Goto A, Tansho M, Hashi K, Shimizu T, Ishida H (2006) Properties of a novel hard-carbon optimized to large size Li ion secondary battery studied by Li-7 NMR. J Power Sources 162(2):1322–1328CrossRef

145.

Persson K, Sethuraman VA, Hardwick LJ, Hinuma Y, Meng YS, van der Ven A, Srinivasan V, Kostecki R, Ceder G (2010) Lithium diffusion in graphitic carbon. J Phys Chem Lett 1(8):1176–1180CrossRef

146.

Gerald RE, Klingler RJ, Sandi G, Johnson CS, Scanlon LG, Rathke JW (2000) Li-7 NMR study of intercalated lithium in curved carbon lattices. J Power Sources 89(2):237–243CrossRef

147.

Chevallier F, Letellier M, Morcrette M, Tarascon JM, Frackowiak E, Rouzaud JN, Beguin F (2003) In situ Li-7-nuclear magnetic resonance observation of reversible lithium insertion into disordered carbons. Electrochem Solid State Lett 6(11):A225–A228CrossRef

148.

Letellier M, Chevallier F, Clinard C, Frackowiak E, Rouzaud JN, Beguin F, Morcrette M, Tarascon JM (2003) The first in situ Li-7 nuclear magnetic resonance study of lithium insertion in hard-carbon anode materials for Li-ion batteries. J Chem Phys 118(13):6038–6045CrossRef

149.

Key B, Bhattacharyya R, Morcrette M, Seznec V, Tarascon JM, Grey CP (2009) Real-time NMR investigations of structural changes in silicon electrodes for lithium-ion batteries. J Am Chem Soc 131(26):9239–9249CrossRef

150.

Nesper R (1990) Structure and chemical bonding in zintl-phases containing Lithium. Prog Solid State Chem 20(1):1–45CrossRef

Balbuena PB, Wang Y (2004) Lithium-ion batteries: solid electrolyte interphase. Imperial College Press, LondonCrossRef

Linden D, Reddy TB (2002) Handbook of batteries, 3rd edn. McGraw-Hill, New York

Titel: Lithium Ion Batteries, Electrochemical Reactions in
verfasst von: Paul J. Sideris
Steve G. Greenbaum
Verlag: Springer New York
Buch: Batteries for Sustainability
Print ISBN: 978-1-4614-5790-9

Electronic ISBN: 978-1-4614-5791-6

Copyright-Jahr: 2013
DOI: https://doi.org/10.1007/978-1-4614-5791-6_8