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Journal of Materials Science: Materials in Electronics

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01.04.2024

Luminescence characterization of rare earth (RE = Tb, Dy, Eu) ions activated Ca₈NaGd(PO₄)₆F₂ halophosphor synthesis by modified Pechini method

verfasst von: Bharti Bawanthade, Ashok Mistry, Vidya Bawanthade, Ashish Mathur, Sanjay J. Dhoble

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 11/2024

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Abstract

Fluorapatite composites Ca₈NaGd(PO₄)₆F₂:Dy³⁺, Tb³⁺, and Eu³⁺ were successfully synthesised for the first time by the modified Pechini method for different concentrations of Dy, Tb, and Eu. As synthesised, Ca₈NaGd(PO₄)₆F₂:x% Dy, Tb, and Eu show intense emission in the blue, green, and red regions, respectively. In Ca₈NaGd(PO₄)₆F₂:x%Tb³⁺, Dy³⁺ shows intense green and blue emission at λ_ex = 274 nm, which confirms energy transfer from Gd³⁺ to Tb³⁺ and Gd³⁺ to Dy³⁺. Under λ_ex = 274 nm Ca₈NaGd(PO₄)₆F₂:x%Eu³⁺, yellow emission is more intense, while at λ_ex = 392 nm red emission is more dominant. Ca₈NaGd(PO₄)₆F₂ with 1% Tb³⁺ has a longer decay time of 3.25 ms as compared with that of 1% Dy³⁺ and 10% Eu³⁺, which have 1.73 ms and 2.27 ms, respectively. Ca₈NaGd(PO₄)₆F₂ doped with 5% Eu³⁺ has a comparatively higher band gap (3.919 eV) than 1% Dy³⁺ (3.918 eV) and Tb³⁺ (3.914 eV) obtained from the Tauc plot. Ca₈NaGd(PO₄)₆F₂ without an activator shows self-emission at 316 nm under λ_ex = 274 nm in the NBUVB region. On analysing the optical properties of the as-prepared Ca₈NaGd(PO₄)₆F_2, authors suggest that an undoped matrix can be used for phototherapy and that a matrix doped with Eu³⁺, Tb³⁺, and Dy³⁺ activator ions becomes a useful candidate for the generation of white LEDs due to emission in the red, green, and blue regions, respectively, with good optical qualities.

Vorheriger Artikel Correction: Effect of Ni dopant on the capacitive behavior of CuS for supercapacitor application

Nächster Artikel CuBi2O4/Bi2MoO6 heterojunction photocatalyst for degradation of tetracycline and rhodamine B: preparation, characterization, and mechanism study

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Titel: Luminescence characterization of rare earth (RE = Tb, Dy, Eu) ions activated Ca8NaGd(PO4)6F2 halophosphor synthesis by modified Pechini method
verfasst von: Bharti Bawanthade
Ashok Mistry
Vidya Bawanthade
Ashish Mathur
Sanjay J. Dhoble
Publikationsdatum: 01.04.2024
Verlag: Springer US
Erschienen in: Journal of Materials Science: Materials in Electronics / Ausgabe 11/2024
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-024-12525-4

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