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Erschienen in: Arabian Journal for Science and Engineering 7/2019

02.05.2019 | Research Article - Physics

Mechanism of FCC structure formation in NiCoFeCuMn equiatomic high-entropy alloys

verfasst von: Chenghuang Tang, Haimei Ye, Yongzhong Zhan

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 7/2019

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Abstract

Microstructural formation mechanism of NiCoFeCuMn equiatomic high-entropy alloys has been discussed from a viewpoint of interaction energy. It is indicated that when the interaction energy (Iij) is higher than a threshold value (It), spinodal decomposition may occur, leading to segregation of similar atoms and formation of a phase independently. Segregation of similar atoms is prone to appear in the alloys containing Fe–Cu or Cu–Cr components. However, when it is Iij < It, heterogeneous atoms segregation may appear. Components like Mn–Ni, Mn–Cu and Mn–Co et al. in the NiCoFeCuMn alloy prone to segregate. For the equiatomic HEAs, interaction energy Iij can effectively reflect the formation mechanism of single-FCC crystal structure and is a principle criterion for material design.

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Metadaten
Titel
Mechanism of FCC structure formation in NiCoFeCuMn equiatomic high-entropy alloys
verfasst von
Chenghuang Tang
Haimei Ye
Yongzhong Zhan
Publikationsdatum
02.05.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Arabian Journal for Science and Engineering / Ausgabe 7/2019
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI
https://doi.org/10.1007/s13369-019-03875-x

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