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Technical Physics

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01.09.2019 | PHYSICS OF NANOSTRUCTURES

Melting Behaviour of Fractal-Shaped Nanoparticles (the Example of Si–Ge System)

verfasst von: A. V. Shishulin, V. B. Fedoseev, A. V. Shishulina

Erschienen in: Technical Physics | Ausgabe 9/2019

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Abstract

The influence of shape on phase equilibria in a two-phase region between liquidus and solidus temperatures has been simulated using Si–Ge nanoparticles as an example. The shape and volume of a particle have been set by its effective radius and fractal dimension. The temperature dependence of the fractal dimension of the phases has been taken into consideration in terms of a simple geometrical model. It has been shown that decreasing the volume of a nanoparticle and its fractal dimension (which corresponds to nanoparticles of a more complicated shape) leads to narrowing down the temperature range of the heterogeneous region, changes in phase transition temperatures and equilibrium compositions of co-existing phases. It has been found that at different temperatures the dependences of the composition of the liquid phase on a particle’s morphology differ which is explained by implementing different mechanisms of reducing the surface energy.

Vorheriger Artikel Investigation of a Contamination Film Formed by the Electron Beam Irradiation

Nächster Artikel Role of the Solid–Aqueous Medium Interface in Transferring Light-Induced Excitation of Silicon

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Titel: Melting Behaviour of Fractal-Shaped Nanoparticles (the Example of Si–Ge System)
verfasst von: A. V. Shishulin
V. B. Fedoseev
A. V. Shishulina
Publikationsdatum: 01.09.2019
Verlag: Pleiades Publishing
Erschienen in: Technical Physics / Ausgabe 9/2019
Print ISSN: 1063-7842
Elektronische ISSN: 1090-6525
DOI: https://doi.org/10.1134/S1063784219090172

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