nach oben

Rare Metals

Erschienen in:

17.03.2023 | Letter

Microstructure and stability of SrCe_0.9Yb_0.1O_3−α ceramics in H₂/H₂O/CO₂ supercritical environment

verfasst von: Jia-Chen Wang, Wei-Jing Wang, Yu-Mei Ren, Qing-He Yu

Erschienen in: Rare Metals | Ausgabe 5/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

SrCe_0.9Yb_0.1O_3−α ceramic samples were obtained by dry pressing and sintering of powders prepared by solid reaction method. X-ray diffraction (XRD) and the field-emission scanning microscope (SEM) were used for phase and microstructure analysis of samples. XRD results showed that the ceramics sintered in the air were pure perovskite structures. SEM results revealed that the average grain size of ceramics increased from 2 to 10 μm when the sintering temperature increased from 1400 to 1500 °C. The supercritical environmental exposure tests for the sintered ceramics at different temperatures were carried out in the reaction kettle with temperature of 650 °C and pressure of 25 MPa. The SrCe_0.9Yb_0.1O_3−α ceramics could not exist stably in a supercritical environment with a volume ratio of 52:14:34 of H₂O:CO₂:H₂.

Graphical abstract

Vorheriger Artikel Anchoring Fe(OH)3 nanoparticles on Ni-MOF nanosheets for efficient electrocatalytic oxygen evolution

Nächster Artikel Annealing atmosphere-dependent capacitive energy storage

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

[1]

Zajc W, Rusinek D, Zheng K, Molenda J. Applicability of Gd-doped BaZrO₃, SrZrO₃, BaCeO₃ and SrCeO₃ proton conducting perovskites as electrolytes for solid oxide fuel cells. Open Chem. 2013;11(4):471. https://doi.org/10.2478/s11532-012-0144-9.CrossRef

[2]

Knight KS, Marshall WG, Bonanos N, Francis DJ. Pressure dependence of the crystal structure of SrCeO₃ perovskite. J Alloy Compd. 2005;394(1):131. https://doi.org/10.1016/j.jallcom.2004.11.020.CrossRef

[3]

Uchida H, Yoshikawa H, Iwahara H. Dissolution of water vapor (or hydrogen) and proton conduction in SrCeO₃-based oxides at high temperature. Solid State Ionics. 1989;35(3–4):229. https://doi.org/10.1016/0167-2738(89)90301-9.CrossRef

[4]

Zhao JB, Wu LL. Yb³⁺- and Er³⁺-doped Y₂O₃ microcrystals for upconversion photoluminescence and energy transfer with enhancements of near-ultraviolet emission. Rare Met. 2021;40(1):123. https://doi.org/10.1007/s12598-019-01269-4.CrossRef

[5]

Tolchard J, Grande T. Physicochemical compatibility of SrCeO₃ with potential SOFC cathodes. J Solid State Chem. 2007;180(10):2808. https://doi.org/10.1016/j.jssc.2007.08.004.CrossRef

[6]

Choi JW. Efficient and robust ceramic interconnects based on a mixed-cation perovskite for solid oxide fuel cells. Ceram Int. 2019;45(4):4902. https://doi.org/10.1016/j.ceramint.2018.11.189.CrossRef

[7]

Li XB, Huang WT, Zhang RR, Guo Y, Yang HJ, He XY, Yu MX, Wang LX, Zhang QT. Synthesis and luminescence of ultrasmall CsPbBr₃ nanocrystals and CsPbBr₃/Cs₄PbBr₆ composites by one-pot method. Rare Met. 2022;41(4):1230. https://doi.org/10.1007/s12598-021-01856-4.CrossRef

[8]

Kumar AS, Balaji R, Jayakumar S. Thermal, structural and electrical properties of samarium doped barium cerate electrolyte for sofcs. Mater Chem Phys. 2017;202:82. https://doi.org/10.1016/j.matchemphys.2017.09.008.CrossRef

[9]

Dubal SU, Jamale AP, Jadhav ST, Patil SP, Bhosale CH, Jadhav LD. Yttrium doped BaCeO₃ thin films by spray pyrolysis technique for application in solid oxide fuel cell. J Alloy Compd. 2014;587:664. https://doi.org/10.1016/j.jallcom.2013.10.093.CrossRef

[10]

Tanaka M, Katahira K, Asakura Y, Ohshima T. Hydrogen pump using a high-temperature proton conductor for nuclear fusion engineering applications. Solid State Ionics. 2010;181(3–4):215. https://doi.org/10.1016/j.ssi.2009.01.020.CrossRef

[11]

Kochetova N, Animitsa I, Medvedev D, Demin A, Tsiakaras P. Recent activity in the development of proton-conducting oxides for high-temperature applications. RSC Adv. 2016;6(77):73222. https://doi.org/10.1039/C6RA13347A.CrossRef

[12]

Wang L, Ding MH, Lin XL. Preparation, microstructure and performance evaluation of HfO_xN₁₋_x coating. Chin J Rare Met. 2022;46(10):1287. https://doi.org/10.13373/j.cnki.cjrm.XY20050007.CrossRef

[13]

Kumar AS, Balaji R, Jayakumar S, Pradeep C. Microwave assisted sintering of gadolinium doped barium cerate electrolyte for intermediate temperature solid oxide fuel cells. Mater Chem Phys. 2016;182:520. https://doi.org/10.1016/j.matchemphys.2016.07.066.CrossRef

[14]

Matsumoto H, Sakai T, Okuyama Y. Proton-conducting oxide and applications to hydrogen energy devices. Pure Appl Chem. 2012;85(2):427. https://doi.org/10.1351/PAC-CON-12-07-11.CrossRef

[15]

Shin Y, Park W, Chang J, Park J. Evaluation of the high temperature electrolysis of steam to produce hydrogen. Int J Hydrog Energy. 2007;32(10):1486. https://doi.org/10.1016/j.ijhydene.2006.10.028.CrossRef

[16]

Yu B, Zhang WQ, Xu JM, Chen J. Status and research of highly efficient hydrogen production through high temperature steam electrolysis at INET. Int J Hydrog Energy. 2010;35(7):2829. https://doi.org/10.1016/j.ijhydene.2009.05.037.CrossRef

[17]

Uchida H, Kimura H, Iwahara H. Limiting current in a high-temperature hydrogen pump with a SrCeO₃-based proton conductor. J Appl Electrochem. 1990;20(3):390. https://doi.org/10.1007/BF01076046.CrossRef

[18]

Kawamura Y, Arita T, Isobe K, Shu W, Yamanishi T. Enhancement of pumping performance of electrochemical hydrogen pump by modified electrode. Fusion Eng Des. 2008;83(4):625. https://doi.org/10.1016/j.fusengdes.2008.01.009.CrossRef

[19]

Yajima T, Iwahara H, Uchida H. Protonic and oxide ionic conduction in BaCeO₃-based ceramics—effect of partial substitution for Ba in BaCe_0.9O_3−α with Ca. Solid State Ionics. 1991;47(1):117. https://doi.org/10.1016/0167-2738(91)90189-I.CrossRef

[20]

Yajima T, Iwahara H. Studies on behavior and mobility of protons in doped perovskite-type oxides: (I) in situ measurement of hydrogen concentration in SrCe_0.95Yb_0.05O_3−α at high temperature. Solid State Ionics. 1992;50(3):281. https://doi.org/10.1016/0167-2738(92)90230-M.CrossRef

[21]

Okuyama Y, Isa K, Lee Y, Sakai T, Matsumoto H. Incorporation and conduction of proton in SrCe_0.9−xZr_xY_0.1O_3−δ. Solid State Ionics. 2015;275:35. https://doi.org/10.1016/j.ssi.2015.01.010.CrossRef

[22]

Phair JW, Badwal SPS. Materials for separation membranes in hydrogen and oxygen production and future power generation. Sci Technol Adv Mater. 2006;7(8):792. https://doi.org/10.1016/j.stam.2006.11.005.CrossRef

[23]

Yuan J, Sun J, Wang J, Zhang H, Dong S, Jiang J, Deng L, Zhou X, Cao X. SrCeO₃ as a novel thermal barrier coating candidate for high–temperature applications. J Alloy Compd. 2018;740:519. https://doi.org/10.1016/j.jallcom.2018.01.021.CrossRef

[24]

Hung IM, Chiang YJ, Jang JSC, Lin JC, Lee SW, Chang JK, His CS. The proton conduction and hydrogen permeation characteristic of Sr(Ce_0.6Zr_0.4)_0.85Y_0.15O₃₋_δ ceramic separation membrane. J Eur Ceram Soc. 2015;35(1):163. https://doi.org/10.1016/j.jeurceramsoc.2014.08.019.CrossRef

[25]

Mineshige A, Okada S, Sakai K, Kobune M, Fujii S, Matsumoto H, Shimura T, Iwahara H, Ogumi Z. Oxygen nonstoichiometry in SrCeO₃-based high-temperature protonic conductors evaluated by Raman spectroscopy. Solid State Ionics. 2003;162–163:41. https://doi.org/10.1016/S0167-2738(03)00232-7.CrossRef

[26]

Mather GC, Figueiredo FM, Romero de Paz J, García-Martín S. Strontium superstoichiometry and defect structure of SrCeO₃ perovskite. Inorg Chem. 2008;47(3):921. https://doi.org/10.1021/ic701703c.CrossRef

[27]

Mather GC, Poulidi D, Thursfield A, Pascual MJ, Jurado JR, Metcalfe IS. Hydrogen-permeation characteristics of a SrCeO₃-based ceramic separation membrane: thermal, ageing and surface-modification effects. Solid State Ionics. 2010;181(3):230. https://doi.org/10.1016/j.ssi.2009.03.014.CrossRef

[28]

Offer GJ. PEM fuel cell electrocatalysts and catalyst layers: fundamentals and applications. Pem Fuel Cell Electrocatalysts Catal Layers. 2008;53(4):655. https://doi.org/10.1007/978-1-84800-936-3_8.CrossRef

[29]

Stolten D, Samsun RC, Garland N. Fuel Cells: Data, Facts, and Figures. Germany: John Wiley & Sons; 2016. 58.CrossRef

[30]

Jin H, Xu B, Li H, Ku X, Fan J. Numerical investigation of coal gasification in supercritical water with the ReaxFF molecular dynamics method. Int J Hydrog Energy. 2018;43(45):20513. https://doi.org/10.1016/j.ijhydene.2018.09.163.CrossRef

Titel: Microstructure and stability of SrCe0.9Yb0.1O3−α ceramics in H2/H2O/CO2 supercritical environment
verfasst von: Jia-Chen Wang
Wei-Jing Wang
Yu-Mei Ren
Qing-He Yu
Publikationsdatum: 17.03.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 5/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02296-y

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 5/2023

Improved energy storage performance of bismuth sodium titanate-based lead-free relaxor ferroelectric ceramics via Bi-containing complex ions doping

FeCo-N encapsuled in nitrogen-doped carbon nanotubes as bifunctional electrocatalysts with a high stability for zinc air batteries

Monoclinic β-AgVO3 coupled with CdS formed a 1D/1D p–n heterojunction for efficient photocatalytic hydrogen evolution

Spatially strain-induced and selective preparation of MoxN (x = 1, 2) as a highly effective nanoarchitectonic catalyst for hydrogen evolution reaction in a wide pH range

Anchoring Fe(OH)3 nanoparticles on Ni-MOF nanosheets for efficient electrocatalytic oxygen evolution

Local chemical ordering coordinated thermal stability of nanograined high-entropy alloys

Premium Partner

Marktübersichten