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Colloid and Polymer Science

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24.01.2019 | Original Contribution

Moisture-activated dynamics on crystallite surfaces in cellulose

verfasst von: Christopher J. Garvey, George P. Simon, Andrew K. Whittaker, Ian H. Parker

Erschienen in: Colloid and Polymer Science | Ausgabe 4/2019

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Abstract

The structural basis of the interdependence between moisture content and activation of cooperative dynamics in natural cellulose is explored using a solid state NMR experiment which is able to localize these motions to cellulose chains on the surface of the unitary crystallite. Making assumptions based on current knowledge of biosynthesis of cellulose and the dipolar line widths of ¹H spectra in solids, it is shown that the sorption of moisture causes the activation of cooperative motion of cellulose chains on the surface of the cellulose crystallite in a manner which is related to the moisture content. An important implication for these results is that densification of cellulose and associated changes in the water sorption isotherm, is possible by structural relaxation on the nano, or unitary crystallite scale. The result is also discussed in term of the evolving and modern picture of cellulose.

Vorheriger Artikel On the features of cooperative mobility in the amorphous phase of ferroelectric polymers

Nächster Artikel A re-formulation of the Mori–Tanaka method for predicting material properties of fiber-reinforced polymers/composites

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Titel: Moisture-activated dynamics on crystallite surfaces in cellulose
verfasst von: Christopher J. Garvey
George P. Simon
Andrew K. Whittaker
Ian H. Parker
Publikationsdatum: 24.01.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 4/2019
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-018-04464-4

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