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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 12/2015

01.12.2015 | Original Paper

New superabsorbent hydrogels synthesized by copolymerization of acrylamide and N-2-hydroxyethyl acrylamide with itaconic acid or itaconates containing ethylene oxide units in the side chain

verfasst von: Amal El Halah, Jesús Contreras, Luis Rojas-Rojas, Mariel Rivas, Milagros Romero, Francisco López-Carrasquero

Erschienen in: Journal of Polymer Research | Ausgabe 12/2015

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Abstract

A series of acrylamide/itaconic acid (AAm/IA), acrylamide/monomethoxyethyl itaconate (AAm/MEI), and acrylamide/dimethoxyethyl itaconate (AAm/DEI) hydrogels were synthesized in AAm/comonomer molar ratios of 100/0, 90/10, 80/20, and 70/30. In all cases, almost quantitative yields were obtained, and the swelling ability increased when comonomer proportion increased. AAm/MEI and AAm/IA reach swelling values more than 40,000, and both systems swelled more than AAm/DEI. This fact pointed out that the carboxylic acid groups present in IA and MEI are mainly responsible for the swelling. All of these hydrogels are stable up to 150 °C as indicated by the TGA measurements. For comparison, the synthesis of a series of N-2-hydroxyethyl acrylamide/itaconic acid (HEAAm/IA), N-2-hydroxyethyl acrylamide /monomethoxyethyl itaconate (HEAAm/MEI), and N-2-hydroxyethyl acrylamide /dimethoxyethyl itaconate (HEAAm/DEI) hydrogels were also carried out. The swelling behavior of HEAAm/IA and HEAAm/MEI was opposite to the former; in these cases the presence of the itaconate comonomer diminish the swelling ability. A diffusion mechanism study was carried out for all the series.
Vorheriger Artikel Investigation of proton conductivity of PVDF based anhydrous proton exchange membranes (PEMs) obtained via a facile “Grafting Through” strategy
Nächster Artikel A comparative study on thermodynamic phase behavior analysis of cellulose acetate, cellulose acetate propionate and cellulose acetate butyrate-DMF-water ternary systems

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Metadaten
Titel
New superabsorbent hydrogels synthesized by copolymerization of acrylamide and N-2-hydroxyethyl acrylamide with itaconic acid or itaconates containing ethylene oxide units in the side chain
verfasst von
Amal El Halah
Jesús Contreras
Luis Rojas-Rojas
Mariel Rivas
Milagros Romero
Francisco López-Carrasquero
Publikationsdatum
01.12.2015
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 12/2015
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-015-0876-2

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