nach oben

Arabian Journal for Science and Engineering

Erschienen in:

02.01.2023 | Research Article-chemical Engineering

Novel Fe⁰ Embedded Alginate Beads and Coated with CuO-Fe₃O₄ as a Sustainable Catalyst for Photo-Fenton Degradation of Oxytetracycline in Wastewater

verfasst von: Muna Awadh Alrebaki, Muneer M. Ba-Abbad, Ahmad Zuhairi Abdullah

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 7/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A novel catalyst made of zero-valent iron (Fe⁰) well dispersed and immobilized on alginate beads and coated using CuO-Fe₃O₄ (CuO-Fe₃O₄-Fe⁰/Abs) was designed and fabricated as a sustainable catalyst to degrade oxytetracycline using a heterogeneous photo-Fenton process. The CuO-Fe₃O₄ component was incorporated as a thin layer to cover the beads during the cross-linking reaction to allow immobilization of Fe⁰ inside the bead structure. Characterization analyses such as Fourier transform infrared spectroscopy, scanning electron microscopy with energy-dispersive spectroscopy and X-ray photoelectron spectroscopy confirmed the successful immobilization of Fe⁰ on the thin layer of CuO-Fe₃O₄ on the beads. The performance test of the catalysts showed that they effectively removed OTC from water through the Fenton and photo-Fenton process at a wide range of pH values (pH 3–8) under visible irradiation. The optimum conditions to completely degrade 20 mg/L antibiotics were achieved at pH 3.0 in the presence of 200 mg/L (CuO-Fe₃O₄-Fe⁰/Abs) catalyst within 60 min of reaction time because of the synergic effect associated with Fe⁰ Fenton reaction in the presence of CuO-Fe₃O₄. These results proved the high performance of the catalyst for the OTC degradation in wastewater satisfactorily fits the pseudo-first-order kinetic model. The k value increases from 0.0476 for Cycle 1 to 0.0831 min⁻¹ for Cycle 4 to indicate that chemical reaction indeed played the predominant role in the OTC degradation. It also had high stability with the controlled release of Fe⁰ into the solution to enhance its catalytic activity.

Vorheriger Artikel Synthesis and Characterization of Nylon 6,6-Polyvinyl Alcohol-Based Polyelectrolytic Membrane

Nächster Artikel Techno-Economic, Energy, Exergy, and Environmental Comparison of Hydrogen Production from Natural gas, Biogas, and their Combination as Feedstock

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Fouad, K.; Bassyouni, M.; Alalm, M.G.; Saleh, M.Y.: Recent developments in recalcitrant organic pollutants degradation using immobilized photocatalysts. Appl. Phys. A 127(8), 1–28 (2021). https://doi.org/10.1007/s00339-021-04724-1CrossRef

King, S.T.; Sylvander, M.; Kheperu, M.; Racz, L.; Harper, W.F., Jr.: Detecting recalcitrant organic chemicals in water with microbial fuel cells and artificial neural networks. Sci. Total Environ. 497, 527–533 (2014). https://doi.org/10.1016/j.scitotenv.2014.07.108CrossRef

O’Connor, D.; Hou, D.; Ok, Y.S.; Song, Y.; Sarmah, A.K.; Li, X.; Tack, F.M.: Sustainable in situ remediation of recalcitrant organic pollutants in groundwater with controlled release materials: a review. J. Control. Release 283, 200–213 (2018). https://doi.org/10.1016/j.jconrel.2018.06.007CrossRef

Klein, E.Y.; van Boeckel, T.P.; Martinez, E.M.; Pant, S.; Gandra, S.; Levin, S.A.; Goossens, H.; Laxminarayan, R.: Global increase and geographic convergence in antibiotic consumption between 2000 and 2015. Proc. Nat. Acad. Sci. 115(15), E3463–E3470 (2018). https://doi.org/10.1073/pnas.171729511CrossRef

Hassouna, M.; Amin, R.R.; Ahmed-Anwar, A.A.; Mahmoud, R.K.: Efficient removal of oxytetracycline and some heavy metals from aqueous solutions by Mg-Al layered double hydroxide nanomaterial. Egypt. J. Chem. 62, 177–195 (2019). https://doi.org/10.21608/EJCHEM.2019.6102.1510CrossRef

Leal, J.; Esteves, V.; Santos, E.: Use of sunlight to degrade oxytetracycline in marine aquaculture’s waters. Environ. Pollut. 213, 932–939 (2016). https://doi.org/10.1016/j.envpol.2016.03.040CrossRef

Ferreira, L.; Salmerón, I.; Peres, J.; Tavares, P.; Lucas, M.; Malato, S.: Advanced oxidation processes as sustainable technologies for the reduction of elderberry agro-industrial water impact. Water Resour. Ind. 24, 100137 (2020). https://doi.org/10.1016/j.wri.2020.100137CrossRef

Hitam, C.; Jalil, A.: A review on exploration of Fe₂O₃ photocatalyst towards degradation of dyes and organic contaminants. J. Environ. Manage 258, 110050 (2020). https://doi.org/10.1016/j.jenvman.2019.110050CrossRef

Le, T.T.; Murugesan, K.; Lee, C.-S.; Vu, C.H.; Chang, Y.-S.; Jeon, J.-R.: Degradation of synthetic pollutants in real wastewater using laccase encapsulated in core–shell magnetic copper alginate beads. Bioresour. Technol. 216, 203–210 (2016). https://doi.org/10.1016/j.biortech.2016.05.077CrossRef

10.

Hassandoost, R.; Pouran, S.R.; Khataee, A.; Orooji, Y.; Joo, S.W.: Hierarchically structured ternary heterojunctions based on Ce³⁺/Ce⁴⁺ modified Fe₃O₄ nanoparticles anchored onto graphene oxide sheets as magnetic visible-light-active photocatalysts for decontamination of oxytetracycline. J. Hazard. Mater. 376, 200–211 (2019). https://doi.org/10.1016/j.jhazmat.2019.05.035CrossRef

11.

Liu, M.; Yu, S.; Hou, L.-A.; Hu, X.: Removal of oxytetracycline by Fe₂O₃–TiO₂/modified zeolite composites under visible light irradiation. J. Mater. Sci. Mater. Electron. 30(10), 9087–9096 (2019). https://doi.org/10.1007/s10854-019-01052-2CrossRef

12.

Lei, Y.; Chen, C.-S.; Tu, Y.-J.; Huang, Y.-H.; Zhang, H.: Heterogeneous degradation of organic pollutants by persulfate activated by CuO-Fe₃O₄: mechanism, stability, and effects of pH and bicarbonate ions. Environ. Sci. Technol. 49(11), 6838–6845 (2015). https://doi.org/10.1021/acs.est.5b00623CrossRef

13.

Dong, Y.; Dong, W.; Cao, Y.; Han, Z.; Ding, Z.: Preparation and catalytic activity of Fe alginate gel beads for oxidative degradation of azo dyes under visible light irradiation. Catal. Today 175(1), 346–355 (2011). https://doi.org/10.1016/j.cattod.2011.03.035CrossRef

14.

Kim, H.; Hong, H.-J.; Jung, J.; Kim, S.-H.; Yang, J.-W.: Degradation of trichloroethylene (TCE) by nanoscale zero-valent iron (nZVI) immobilized in alginate bead. J. Hazard. Mater. 176(1–3), 1038–1043 (2010). https://doi.org/10.1016/j.jhazmat.2009.11.145CrossRef

15.

Kang, Y.-G.; Vu, H.C.; Le, T.T.; Chang, Y.-S.: Activation of persulfate by a novel Fe (II)-immobilized chitosan/alginate composite for bisphenol a degradation. Chem. Eng. J. 353, 736–745 (2018). https://doi.org/10.1016/j.cej.2018.07.175CrossRef

16.

Bilal, M.; Iqbal, H.M.: Lignin peroxidase immobilization on Ca-alginate beads and its dye degradation performance in a packed bed reactor system. Biocatal. Agric. Biotechnol. 20, 101205 (2019). https://doi.org/10.1016/j.bcab.2019.101205CrossRef

17.

Lee, C.-S.; Gong, J.; Huong, C.V.; Oh, D.-S.; Chang, Y.-S.: Macroporous alginate substrate-bound growth of Fe⁰ nanoparticles with high redox activities for nitrate removal from aqueous solutions. Chem. Eng. J. 298, 206–213 (2016). https://doi.org/10.1016/j.cej.2016.03.113CrossRef

18.

Bilal, M.; Rasheed, T.; Iqbal, H.M.; Hu, H.; Wang, W.; Zhang, X.: Novel characteristics of horseradish peroxidase immobilized onto the polyvinyl alcohol-alginate beads and its methyl orange degradation potential. Int. J. Biol. Macromol. 105, 328–335 (2017). https://doi.org/10.1016/j.ijbiomac.2017.07.042CrossRef

19.

Pullin, H.; Springell, R.; Parry, S.; Scott, T.: The effect of aqueous corrosion on the structure and reactivity of zero-valent iron nanoparticles. Chem. Eng. J. 308, 568–577 (2017). https://doi.org/10.1016/j.cej.2016.09.088CrossRef

20.

Hwang, Y.-H.; Kim, D.-G.; Shin, H.-S.: Effects of synthesis conditions on the characteristics and reactivity of nano scale zero valent iron. Appl. Catal. B Environ. 105(1–2), 144–150 (2011). https://doi.org/10.1016/j.apcatb.2011.04.005CrossRef

21.

Ba-Abbad, M.M.; Kadhum, A.A.H.; Mohamad, A.B.; Takriff, M.S.; Sopian, K.: Synthesis and catalytic activity of TiO₂ nanoparticles for photochemical oxidation of concentrated chlorophenols under direct solar radiation. Int. J. Electrochem. Sci 7(6), 4871–4888 (2012)

22.

Jiang, Y.; Ran, J.; Mao, K.; Yang, X.; Zhong, L.; Yang, C.; Feng, X.; Zhang, H.: Recent progress in Fenton/Fenton-like reactions for the removal of antibiotics in aqueous environments. Ecotoxicol. Environ. Saf. 236, 113464 (2022). https://doi.org/10.1016/j.ecoenv.2022.113464CrossRef

23.

Li, Z.; Wang, M.; Jin, C.; Kang, J.; Liu, J.; Yang, H.; Zhang, Y.; Pu, Q.; Zhao, Y.; You, M.; Wu, Z.: Synthesis of novel Co₃O₄ hierarchical porous nanosheets via corn stem and MOF-Co templates for efficient oxytetracycline degradation by peroxymonosulfate activation. Chem. Eng. J. 392, 123789 (2020). https://doi.org/10.1016/j.cej.2019.123789CrossRef

24.

Zhao, N.; Liu, K.; He, C.; Gao, J.; Zhang, W.; Zhao, T.; Tsang, D.C.W.; Qiu, R.: Singlet oxygen mediated the selective removal of oxytetracycline in C/Fe₃C/Fe⁰ system as compared to chloramphenicol. Environ. Int. 143, 105899 (2020). https://doi.org/10.1016/j.envint.2020.105899CrossRef

25.

Wang, Q.; Ma, Y.; Xing, S.: Comparative study of Cu-based bimetallic oxides for Fenton-like degradation of organic pollutants. Chemosphere 203, 450–456 (2018). https://doi.org/10.1016/j.chemosphere.2018.04.013CrossRef

26.

Wu, Z.; Gu, Y.; Xin, S.; Lu, L.; Huang, Z.; Li, M.; Cui, Y.; Fu, R.; Wang, S.: Cu_xNi_yCo-LDH nanosheets on graphene oxide: An efficient and stable Fenton-like catalyst for dual-mechanism degradation of tetracycline. Chem. Eng. J. 434, 134574 (2022). https://doi.org/10.1016/j.cej.2022.134574CrossRef

27.

Pham, V.L.; Kim, D.-G.; Ko, S.-O.: Cu@Fe₃O₄ core-shell nanoparticle-catalyzed oxidative degradation of the antibiotic oxytetracycline in pre-treated landfill leachate. Chemosphere 191, 639–650 (2018). https://doi.org/10.1016/j.chemosphere.2017.10.090CrossRef

28.

Pereira, J.H.; Queirós, D.B.; Reis, A.C.; Nunes, O.C.; Borges, M.T.; Boaventura, R.A.; Vilar, V.J.: Process enhancement at near neutral pH of a homogeneous photo-Fenton reaction using ferricarboxylate complexes: application to oxytetracycline degradation. Chem. Eng. J. 253, 217–228 (2014). https://doi.org/10.1016/j.cej.2014.05.037CrossRef

29.

Masschelein, C.A.; Ryder, D.S.; Simon, J.-P.: Immobilized cell technology in beer production. Crit. Rev. Biotechnol. 14(2), 155–177 (1994). https://doi.org/10.3109/07388559409086966CrossRef

30.

Kessler, A.; Hedberg, J.; Blomberg, E.; Odnevall, I.: Reactive oxygen species formed by metal and metal oxide nanoparticles in physiological media—a review of reactions of importance to nanotoxicity and proposal for categorization. Nanomaterials 12(11), 1922 (2022). https://doi.org/10.3390/nano12111922CrossRef

31.

Hu, X.; Li, C.; Song, J.; Zheng, S.; Sun, Z.: Multidimensional assembly of oxygen vacancy-rich amorphous TiO₂-BiOBr-sepiolite composite for rapid elimination of formaldehyde and oxytetracycline under visible light. J. Colloid Interface Sci. 574, 61–73 (2020). https://doi.org/10.1016/j.jcis.2020.04.035CrossRef

32.

Li, N.; Zhou, L.; Jin, X.; Owens, G.; Chen, Z.: Simultaneous removal of tetracycline and oxytetracycline antibiotics from wastewater using a ZIF-8 metal organic-framework. J. Hazard. Mater. 366, 563–572 (2019). https://doi.org/10.1016/j.jhazmat.2018.12.047CrossRef

33.

Priya, B.; Raizada, P.; Singh, N.; Thakur, P.; Singh, P.: Adsorptional photocatalytic mineralization of oxytetracycline and ampicillin antibiotics using Bi₂O₃/BiOCl supported on graphene sand composite and chitosan. J. Colloid Interface Sci. 479, 271–283 (2016). https://doi.org/10.1016/j.jcis.2016.06.067CrossRef

34.

Raizada, P.; Kumari, J.; Shandilya, P.; Singh, P.: Kinetics of photocatalytic mineralization of oxytetracycline and ampicillin using activated carbon supported ZnO/ZnWO. Desalination 79, 204–213 (2017). https://doi.org/10.5004/dwt.2017.20831CrossRef

35.

Raizada, P.; Kumari, J.; Shandilya, P.; Dhiman, R.; Singh, V.P.; Singh, P.: Magnetically retrievable Bi₂WO₆/Fe₃O₄ immobilized on graphene sand composite for investigation of photocatalytic mineralization of oxytetracycline and ampicillin. Process Saf. Environ. Prot. 106, 104–116 (2017). https://doi.org/10.1016/j.psep.2016.12.012CrossRef

Titel: Novel Fe0 Embedded Alginate Beads and Coated with CuO-Fe3O4 as a Sustainable Catalyst for Photo-Fenton Degradation of Oxytetracycline in Wastewater
verfasst von: Muna Awadh Alrebaki
Muneer M. Ba-Abbad
Ahmad Zuhairi Abdullah
Publikationsdatum: 02.01.2023
Verlag: Springer Berlin Heidelberg
Erschienen in: Arabian Journal for Science and Engineering / Ausgabe 7/2023
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI: https://doi.org/10.1007/s13369-022-07577-9

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 7/2023

Hydrophobic Montmorillonite/PVDF Membrane: Experimental Investigation of Membrane Synthesis toward Wetting Characterization and Performance via DCMD

Friction Coefficients Calculation via Surface Roughness Characterization for Tight Sedimentary Rocks

Performance Assessment of Binary Liquid Fuels DMAZ-TMEDA with Some Nitric Acid-Based Oxidizers

Investigation of the Effects of Silica Nanofluid for Enhanced Oil Recovery Applications: CFD Simulation Study

Constructed Wetlands for Wastewater Treatment in Saudi Arabia: Opportunities and Sustainability

Improved Stabilization of Sulfated Zirconia by Molybdenum: Synergy of Metal Sites and Acid Sites in the n-Hexane Hydro-Isomerization

Premium Partner

Marktübersichten