Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 6/2019

17.09.2018 | Original Paper

PdNPs@thermo-responsive block copolymers composed of PNIPAM and poly(ionic liquid) via RAFT polymerization

verfasst von: Soheila Ghasemi, Zahra Amini Harandi

Erschienen in: Polymer Bulletin | Ausgabe 6/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Preparation and identification of block copolymers comprised of PNIPAM and poly(ionic liquid) of pyridinium sulfonate by two different approaches through changing the order of monomer addition has been reported. Controlled synthesis is performed via reversible addition–fragmentation chain transfer polymerization. Pd nanoparticles (PdNPs) are immobilized onto these block copolymers to utilize them as thermo-responsive catalysts. The block copolymers and their corresponding catalysts were characterized by varied techniques, i.e., FTIR, NMR and UV–Vis spectroscopy, ICP, TGA, DLS and X-ray diffraction. SEM and EDAX were applied to analyze the surface of the sample and its composition. Furthermore, TEM was used to obtain the size of PdNPs and their distribution in the polymer matrix. The catalytic efficiency of the catalysts was examined in the Heck coupling reaction for the production of butyl cinnamate.
Vorheriger Artikel Multi-walled carbon nanotubes buckypaper/epoxy composites: effect of loading and pressure on tensile and electrical properties
Nächster Artikel Effect of incompletely condensed tri-silanol-phenyl-POSS on the thermal stability of silicone rubber

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Vekariya RL (2017) A review of ionic liquids: applications towards catalytic organic transformations. J Mol Liq 227:44–60CrossRef
2.
Walden P (1914) Chem Zentralbl 85:1800–1801
3.
Morton MD, Hamer CK (2018) Ionic liquids—the beginning of the end or the end of the beginning?—a look at the life of ionic liquids through patent claims. Sep Purif Technol 196:3–9CrossRef
4.
Angell CA, Ansari Y, Zhao Z (2012) Ionic liquids: past, present and future. Faraday Discuss 154:9–27CrossRefPubMed
5.
Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry. Chem Soc Rev 37:123–150CrossRef
6.
Yuan J, Mecerreyes D, Antonietti M (2013) Poly(ionic liquid)s: an update. Prog Polym Sci 38:1009–1036CrossRef
7.
Salamone JC, Israel SC, Taylor P, Snider B (1973) Synthesis and homopolymerization of vinylimidazolium salts. Polymer 14:639–644CrossRef
8.
Ohno H, Ito K (1998) Room-temperature molten salt polymers as a matrix for fast ion conduction. Chem Lett 27:751–752CrossRef
9.
Yuan J, Antonietti M (2011) Poly(ionic liquid)s: polymers expanding classical property profiles. Polymer 52:1469–1482CrossRef
10.
Men Y, Kuzmicz D, Yuan J (2014) Poly(ionic liquid) colloidal particles. Curr Opin Colloid Interface 19:76–83CrossRef
11.
Eftekhari A, Saitoc T (2017) Synthesis and properties of polymerized ionic liquids. Eur Polym J 90:245–272CrossRef
12.
Qian W, Texter J, Yan F (2017) Frontiers in poly(ionic liquid)s: syntheses and applications. Chem Soc Rev 46:1124–1159CrossRefPubMed
13.
Nasiri M, Bertrand A, Reineke TM, Hillmyer MA (2014) Polymeric nanocylinders by combining block copolymer self-assembly and nanoskiving. ACS Appl Mater Interfaces 6:16283–16288CrossRefPubMedPubMedCentral
14.
Agustina S, Tokuda M, Minami H, Boyer C, Zetterlund PB (2017) Synthesis of polymeric nano-objects of various morphologies based on block copolymer self-assembly using microporous membranes. React Chem Eng 2:451–457CrossRef
15.
Stefik M, Guldin S, Vignolini S, Wiesner U, Steiner U (2015) Block copolymer self-assembly for nanophotonics. Chem Soc Rev 44:5076–5091CrossRefPubMed
16.
Dai Y, Li Y, Wang S (2015) ABC triblock copolymer-stabilized gold nanoparticles for catalytic reduction of 4-nitrophenol. J Catal 329:425–430CrossRef
17.
Gallagher JJ, Hillmyer MA, Reineke TM (2016) Acrylic triblock copolymers incorporating isosorbide for pressure sensitive adhesives. ACS Sustain Chem Eng 4:3379–3387CrossRef
18.
Nasiri M, Saxon DJ, Reineke TM (2018) Enhanced mechanical and adhesion properties in sustainable triblock copolymers via non-covalent interactions. Macromolecules 51:2456–2465CrossRef
19.
20.
Feng H, Lu X, Wang W, Kang NG, Mays JW (2017) Block copolymers: synthesis, self-assembly, and applications. Polymers 9:494–525CrossRefPubMedCentral
21.
Wu WC, Chen CY, Lee WY, Chen WC (2015) Stimuli-responsive conjugated rod-coil block copolymers: synthesis, morphology and applications. Polymer 65:1–16CrossRef
22.
Vijayakrishna K, Jewrajka SK, Ruiz A, Marcilla R, Pomposo JA, Mecerreyes D, Taton D, Gnanou Y (2008) Synthesis by RAFT and ionic responsiveness of double hydrophilic block copolymers based on ionic liquid monomer units. Macromolecules 41:6299–6308CrossRef
23.
Yuan J, Schlaad H, Giordano C, Antonietti M (2011) Double hydrophilic diblock copolymers containing a poly(ionic liquid) segment: controlled synthesis, solution property, and application as carbon precursor. Eur Polym J 47:772–781CrossRef
24.
Mori H, Ebina Y, Kambara R, Nakabayashi K (2012) Temperature-responsive self-assembly of star block copolymers with poly(ionic liquid) segments. Polym J 44:550–560CrossRef
25.
Mori H, Yahagi M, Endo T (2009) RAFT polymerization of N-vinylimidazolium salts and synthesis of thermos responsive ionic liquid block copolymers. Macromolecules 42:8082–8092CrossRef
26.
Kamiya J, Raman V, Masaki W, Mamoru I, Noriyoshi M (2015) Tunable LCST behavior of poly(N-isopropylacrylamide/ionic liquid) copolymers. Polym Chem 6:6819–6825CrossRef
27.
Karjalainen E, Chenna N, Laurinmaki P, Butcher SJ, Tenhu H (2013) Diblock copolymers consisting of a polymerized ionic liquid and poly(N-isopropylacrylamide). Effects of PNIPAM block length and counter ion on self-assembling and thermal properties. Polym Chem 4:1014–1024CrossRef
28.
Wang Z, Lai H, Wu P (2012) Influence of PIL segment on solution properties of poly(N-isopropylacrylamide)-b-poly(ionic liquid) copolymer: micelles, thermal phase behavior and microdynamics. Soft Matter 8:11644–11653CrossRef
29.
Weber N, Texter J, Tauer K (2011) The synthesis of special block copolymers using a reaction calorimeter. Macromol Symp 302:224–234CrossRef
30.
Yua R, Tauer K (2014) From particles to stabilizing blocks—polymerized ionic liquids in aqueous heterophase polymerization. Polym Chem 5:5644–5655CrossRef
31.
Men Y, Drechsler M, Yuan J (2013) Double-stimuli-responsive spherical polymer brushes with a poly(ionic liquid) core and a thermos responsive shell. Macromol Rapid Commun 34:1721–1727CrossRefPubMed
32.
Karjalainen E, Khlebnikov V, Korpi A, Hirvonen SP, Hietala S, Aseyev V, Tenhu H (2015) Complex interactions in aqueous PIL-PNIPAm-PIL triblock copolymer solutions. Polymer 58:180–188CrossRef
33.
Ghasemi S, Amini Harandi Z (2018) Thermo-responsive poly(N-isopropylacrylamide)-block-poly(ionic liquid) of pyridinium sulfonate immobilized Pd nanoparticles in C–C coupling reactions. RSC Adv 8:14570–14578CrossRef
34.
Keddie DJ (2014) A guide to the synthesis of block copolymers using reversible-addition fragmentation chain transfer (RAFT) polymerization. Chem Soc Rev 43:496–505CrossRefPubMed
Metadaten
Titel
PdNPs@thermo-responsive block copolymers composed of PNIPAM and poly(ionic liquid) via RAFT polymerization
verfasst von
Soheila Ghasemi
Zahra Amini Harandi
Publikationsdatum
17.09.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 6/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2532-6

Weitere Artikel der Ausgabe 6/2019

Polymer Bulletin 6/2019 Zur Ausgabe

Original Paper

Conducting hydrogel based on chitosan, polypyrrole and magnetite nanoparticles: a broadband dielectric spectroscopy study

Original Paper

Electropolymerization of styrene in alcoholic solution and preparation of its bilayer with polyacrylamide

Original Paper

High-performance poly(vinyl alcohol)–chitosan sponge modified with graphene oxide

Original Paper

Building an electron push–pull system of linear conjugated polymers for improving photocatalytic hydrogen evolution efficiency

Review

Advances in the synthesis of non-isocyanate polyurethanes

Original Paper

Effect of incompletely condensed tri-silanol-phenyl-POSS on the thermal stability of silicone rubber

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise