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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 12/2018

24.10.2018 | Original Contribution

Polaron localization in polyaniline through methylene blue dye interaction for tuned charge transport and optical properties

verfasst von: Kamanashis Sarkar, Krishna Deb, Ajit Debnath, Arun Bera, Animesh Debnath, Biswajit Saha

Erschienen in: Colloid and Polymer Science | Ausgabe 12/2018

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Abstract

An excellent control over the charged transport process and optical properties in polyaniline has been attained through successful localization of polarons formed in the polyaniline chain. The localization of polaron in polyaniline has been achieved through its interaction with methylene blue (MB) dye. Polyaniline has been synthesized on paper substrate from aniline using FeCl3 as polymerizing agent. On optical measurement of prepared sample, a remarkable red shift in the optical band gap has been observed varying from 2.63 to 2.47 eV. The charge transport behavior as reflected from its I-V measurement shows a nice tuning in the logarithmic scale. The chemical interaction between the MB dye and the polaronic charged defect states brings this brilliant tuning in the optical and electrical properties of polyaniline. Predominantly, the intra-chain charge transport of the polyaniline backbone is affected by the MB dye interaction.
Nächster Artikel Dynamic moduli of flocculated kaolinite sediments: effect of salinity, flocculant dose, and settling time

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Metadaten
Titel
Polaron localization in polyaniline through methylene blue dye interaction for tuned charge transport and optical properties
verfasst von
Kamanashis Sarkar
Krishna Deb
Ajit Debnath
Arun Bera
Animesh Debnath
Biswajit Saha
Publikationsdatum
24.10.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 12/2018
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-018-4419-3

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