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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 10/2019

01.10.2019 | ORIGINAL PAPER

Poly(arylene ether ketone) containing amino and fluorenyl groups for highly selective of gas separation

verfasst von: Lei Hou, Zhe Wang, Jingmei Xu, Zhaoyu Chen

Erschienen in: Journal of Polymer Research | Ausgabe 10/2019

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Abstract

In this study, a series of poly(arylene ether ketone) containing amino and fluorenyl groups (Am-PAFEK-X) were successfully prepared by the polycondensation, which was confirmed by analizing its chemical structure with the Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance. It was found that Am-PAFEK-X exhibited high thermal stability (Td5 > 172 °C) and glass transition temperature (Tg > 191 °C) as well as good mechanical properties, and its highest Young’s modulus and tensile strength are respectively 2299 MPa and 59 MPa. In addition, the O2, N2, CO2 and CH4 were applied to study the gas transmission properties of Am-PAFEK-X membranes to different gases, in which the Am-PAFEK-60% had the highest selectivity to CO2/N2 and CO2/CH4, respectively 31.13 and 33.36. As shown in the results, the selectivity of the membrane to CO2 increased with the increase of the large rigid fluorenyl groups, which indicated that the gas permeation results were closely related to the intermolecular interaction and the structure of the polymer chain.
Vorheriger Artikel Structure effect on mechanical and thermal properties in aromatic copolyamides with phenyl substituents
Nächster Artikel Polypyrrole doped graphene oxide reinforced epoxy nanocomposite with advanced properties for coatings of mild steel

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Metadaten
Titel
Poly(arylene ether ketone) containing amino and fluorenyl groups for highly selective of gas separation
verfasst von
Lei Hou
Zhe Wang
Jingmei Xu
Zhaoyu Chen
Publikationsdatum
01.10.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 10/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1906-2

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