nach oben

Adsorption

09.05.2024

Polyaniline/reduced graphene oxide doping induced abundant active sites in enset fiber as an efficient adsorbent material for wastewater treatment

verfasst von: Israel Leka Lera, Genne Hayre, Ayansa Fekadu

Erschienen in: Adsorption

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Analysis of physicochemical properties and water treatment is vital for the environment and societal living standards. In this study, polyaniline (PANI)/enset fiber (EF), reduced graphene oxide/EF, and PANI/rGO/EF composites as adsorbent materials were prepared via facile in-situ chemical oxidative polymerization techniques. The as-synthesized materials were characterized using XRD, FTIR, UV-VIS, TGA, and SEM spectroscopy. Physical characterization revealed the deposition of PANI and rGO on the surface of EF, confirmed by the cloudy and wrinkled fibrous morphology observed in the SEM images. After physical characterization, the adsorption performance of the proposed materials was tested using the batch method. The results showed a maximum adsorption capacity (q_max) of Cu²⁺ and Pb²⁺ ions by PANI/rGO-coated EF was 10.11 mg/g and 13.4 mg/g, respectively, which is higher than that of pristine EF, PANI/EF, and rGO/EF. When all parameters were optimized, the adsorptive removal efficiency of PANI/rGO/EF composite material towards Pb²⁺ and Cu²⁺ ions was 99% and 97.77%, respectively. The Freundlich isotherm data for Cu²⁺ and Pb²⁺ showed a good fit with the experimental data (R² = 0.99 and 0.98), and Langmuir isotherm data for Cu²⁺ and Pb²⁺ (RL = 0.18 and 0.19), respectively. The pseudo-second-order kinetic isotherm was a better fit for physisorption, with R² = 0.99 for Cu2 + and R² = 1 for Pb²⁺. Therefore, the synthesized novel material PANI/rGO/EF shows remarkable adsorption performance compared to EF, PANI/EF, and rGO/EF, due to the doping-induced abundant active sites of the composite material, making it a promising candidate for wastewater treatment techniques.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Kılıç, Z.: The importance of water and conscious use of water. Int. J. Hydrol. 4, 239–241 (2020). https://doi.org/10.15406/ijh.2020.04.00250CrossRef

Younas, F., Younas, S., Bibi, I., Farooqi, Z.U.R., Hameed, M.A., Mohy-Ud-Din, W., Shehzad, M.T., Hussain, M.M., Shakil, Q., Shahid, M., Niazi, N.K.: A critical review on the separation of heavy metal(loid)s from the contaminated water using various agricultural wastes. Int. J. Phytorem. 26, 349–368 (2024). https://doi.org/10.1080/15226514.2023.2242973CrossRef

Nasir, O., Ashraf, S., Rizwan, M.A., Javed, A., Amjad, K., Bibi, R., Nazeer, M.N.: Conventional and Advanced Wastewater Treatment Techniques; Development of sustainable environment and production of Biofertilizers. Int. J. Res. Publ Rev. 5, 5491–5499 (2024). https://doi.org/10.55248/gengpi.5.0124.0364CrossRef

Mojiri, A.: Treatment of Water and Wastewater: Challenges and solutions. Separations. 10, 4–7 (2023). https://doi.org/10.3390/separations10070385CrossRef

Jianle, L.: Yongde Liu a, Jiaxu Wang a, Yongzhi Liu a b, Minghu Zhang a, Luo Zhao a, Si Gu a, Ruohan Lin a, L.C.: Research progress on the application of natural adsorbents in the treatment of livestock wastewater. Desalin. Water Treat. 317, 100015–100018 (2024). https://doi.org/10.1016/j.dwt.2024.100018CrossRef

Nasrollahzadeha, M., Sajjadia, M., Iravanib, S., Varmac, D.: Carbon-based sustainable nanomaterials for water treatment: State-of-art and future perspectives. Chemospher. 263, 128005 (2019). https://doi.org/10.1016/j.chemosphere.2020.128005

Agbozu, I.E., Emoruwa, F.O.: Batch adsorption of heavy metals (Cu, Pb, Fe, Cr and Cd) from aqueous solutions using coconut husk. 8, 239–246 (2014). https://doi.org/10.5897/AJEST2013.1577

Sathasivam, K., Haris, M.R.H.M.: Banana trunk fibers as an efficient biosorbent for the removal of cd(II), Cu(II), Fe(II) and zn(II) from aqueous solutions. J. Chil. Chem. Soc. 55, 278–282 (2010). https://doi.org/10.4067/S0717-97072010000200030CrossRef

Vieira, A.M.S., Vieira, M.F., Silva, G.F., Araújo, Á.A., Fagundes-Klen, M.R., Veit, M.T., Bergamasco, R.: Use of Moringa oleifera seed as a natural adsorbent for wastewater treatment. Water Air Soil. Pollut. 206, 273–281 (2010). https://doi.org/10.1007/s11270-009-0104-yCrossRef

10.

Rahman, M.W., Nipa, S.T., Rima, S.Z., Hasan, M.M., Saha, R., Halim, M.A., Ali, Y., Deb, A.: Pseudo-stem banana fiber as a potential low-cost adsorbent to remove methylene blue from synthetic wastewater. Appl. Water Sci. 12, 1–16 (2022). https://doi.org/10.1007/s13201-022-01769-2CrossRef

11.

Chandala Jatkar a b, Amruta Koli b, Akshata Pattanshetti b, Rohant Dhabbe b, Rahul Dhale c, Rajendra Kumbhar b, Jaykumar Patil a, S.S.: Pre and post-adsorption properties of modified banana fibre as sustainable bio-material for environmental and futuristic industrial applications. Ind. Crops Prod. 209, 118000–118003: (2024)

12.

Jadoun, S.P.F.U.Y.: A review on adsorption of heavy metals from wastewater using conducting polymer-based materials. J. Environ. Chem. Eng. 11, 109215–109226 (2023). https://doi.org/10.1016/j.jece.2022.109226CrossRef

13.

Diro, S.T., Bahru, T.B., Lera, I.L.: Polyaniline doping induced abundant active sites in orange peel as an efficient adsorbent material for water treatment. Adsorption. (2024). https://doi.org/10.1007/s10450-024-00466-7CrossRef

14.

Kour, G.A.R.K.: Conducting polymer based nanoadsorbents for removal of heavy metal Ions/Dyes from Wastewater. Adv. Hybrid. Conduct Polym. Technol. 3, 135–157 (2021). https://doi.org/10.1007/978-3-030-62090-5_7CrossRef

15.

Mahmud, H.N.M.E., Huq, A.K.O., Yahya, R.: Polymer-based adsorbent for heavy metals removal from aqueous solution. IOP Conf. Ser. Mater. Sci. Eng. 206 (2017). https://doi.org/10.1088/1757-899X/206/1/012100

16.

Kanwal, F., Rehman, R., Mahmud, T., Anwar, J., Ilyas, R., ISO-thermal and thermodynamical modeling of chromium (iii) adsorption by composites of polyaniline with rice husk and saw dust: J. Chil. Chem. Soc. 1, 1058–1063 (2012)CrossRef

17.

Reza, M.S., Afroze, S., Kuterbekov, K., Kabyshev, A., Zh. Bekmyrza, K., Haque, M.N., Islam, S.N., Hossain, M.A., Hassan, M., Roy, H., Islam, M.S., Pervez, M.N., Azad, A.K.: Advanced Applications of Carbonaceous Materials in Sustainable Water Treatment, Energy Storage, and CO2 Capture: A Comprehensive Review. Sustain. 15, (2023). https://doi.org/10.3390/su15118815

18.

Liu, Y.: Application of graphene oxide in water treatment. IOP Conf. Ser. Earth Environ. Sci. 94 (2017). https://doi.org/10.1088/1755-1315/94/1/012060

19.

Jiříčková, A., Jankovský, O., Sofer, Z., Sedmidubský, D.: Synthesis and applications of Graphene Oxide. Mater. (Basel). 15 (2022). https://doi.org/10.3390/ma15030920

20.

Teklu, T., Wangatia, L.M., Alemayehu, E.: Sisal fibers coated with conducting polyaniline: Property and structural studies. Polym. Sci. - Ser. B. 59, 624–629 (2017). https://doi.org/10.1134/S1560090417050153CrossRef

21.

Jiang, L., Cui, Z.: One-step synthesis of oriented polyaniline nanorods through electrochemical deposition. Polym. Bull. 56, 529–537 (2006). https://doi.org/10.1007/s00289-005-0494-yCrossRef

22.

Shao, W., Jamal, R., Xu, F., Ubul, A., Abdiryim, T.: The effect of a small amount of water on the structure and electrochemical properties of solid-state synthesized polyaniline. Mater. (Basel). 5, 1811–1825 (2012). https://doi.org/10.3390/ma5101811CrossRef

23.

Zhu, H., Peng, S., Jiang, W.: Electrochemical properties of PANI as single electrode of electrochemical capacitors in acid electrolytes. Sci. World J. 2013 (2013). https://doi.org/10.1155/2013/940153

24.

Sydulu Singu, B., Srinivasan, P., Pabba, S.: Benzoyl Peroxide Oxidation Route to Nano Form Polyaniline Salt containing dual dopants for Pseudocapacitor. J. Electrochem. Soc. 159, A6–A13 (2011). https://doi.org/10.1149/2.036201jesCrossRef

25.

Temesgen, A.G., Sahu, O.: Process ability enhancement of false Banana Fibre process ability enhancement of false Banana Fibre for Rural Development. J. Agric. Econ. Ext. Rural Dev. 1, 64–073 (2014). https://doi.org/10.13140/RG.2.2.36612.01926CrossRef

26.

Tibolla, H., Pelissari, F.M., Menegalli, F.C.: Cellulose nanofibers produced from banana peel by chemical and enzymatic treatment. Lwt. 59, 1311–1318 (2014). https://doi.org/10.1016/j.lwt.2014.04.011CrossRef

27.

Cherian, B.M., Pothan, L.A., Nguyen-Chung, T., Mennig, G., Kottaisamy, M., Thomas, S.: A novel method for the synthesis of cellulose nanofibril whiskers from banana fibers and characterization. J. Agric. Food Chem. 56, 5617–5627 (2008). https://doi.org/10.1021/jf8003674CrossRefPubMed

28.

Sanches, E.A., Soares, J.C., Iost, R.M., Marangoni, V.S., Trovati, G., Batista, T., Mafud, A.C., Zucolotto, V., Mascarenhas, Y.P.: Structural characterization of emeraldine-salt polyaniline/gold nanoparticles complexes. J. Nanomater. 2011, 1–8 (2011). https://doi.org/10.1155/2011/697071CrossRef

29.

Krishnamoorthy, K., Veerapandian, M., Yun, K., Kim, S.J.: The chemical and structural analysis of graphene oxide with different degrees of oxidation. Carbon N Y. 53, 38–49 (2013). https://doi.org/10.1016/j.carbon.2012.10.013CrossRef

30.

Blanton, T.N., Majumdar, D.: Characterization of X-ray irradiated graphene oxide coatings using X-ray diffraction, X-ray photoelectron spectroscopy, and atomic force microscopy. Powder Diffr. 28, 68–71 (2013). https://doi.org/10.1017/S0885715613000109CrossRef

31.

Mitra, M., Kulsi, C., Chatterjee, K., Kargupta, K.: Reduced graphene oxide-polyaniline composites—synthesis, characterization and optimization for thermoelectric applications. RSC Adv. 5, 31039–31048 (2015). https://doi.org/10.1039/c5ra01794gCrossRef

32.

Pereira, P.H.F., Benini, C., Watashi, K.C.C., Voorwald, C.Y., Cioffi, H.J.C.: Characterization of high density polyethylene (HDPE) reinforced with banana peel fibers. BioResources. 8, 2351–2365 (2013). https://doi.org/10.15376/biores.8.2.2351-2365CrossRef

33.

Joshi, P.V., Mandot, A.A., Patel, B.H.: Enzymatic extraction of Nano Cellulose from Banana Stem: Morphological, structural and thermal characterization. J. Nat. Prod. Plant. Resour. 8, 1–11 (2018)

34.

Israel, L.L., et al.: Insights into the Electrochemical behavior and kinetics of NiP@PANI/ rGO as a high–performance electrode for Alkaline Urea Oxidation. Electrocatalysis. 13, 1–16 (2022). https://doi.org/10.1007/s12678-022-00718-6CrossRef

35.

Ahmed, N., sabah, Hsu, C.Y., Mahmoud, Z.H., Sayadi, H., Kianfar, E.: A graphene oxide/polyaniline nanocomposite biosensor: Synthesis, characterization, and electrochemical detection of bilirubin. RSC Adv. 13, 36280–36292 (2023). https://doi.org/10.1039/d3ra06815cCrossRefPubMedPubMedCentral

36.

Shaban, M., Abukhadra, M.R., Rabia, M., Elkader, Y.A., Abd El-Halim, M.R.: Investigation the adsorption properties of graphene oxide and polyaniline nano/micro structures for efficient removal of toxic cr(VI) contaminants from aqueous solutions; kinetic and equilibrium studies. Rend. Lincei. 29, 141–154 (2018). https://doi.org/10.1007/s12210-018-0673-zCrossRef

37.

Repon, M.R., Islam, M.T., Mamun, M.A., Al: Ecological risk assessment and health safety speculation during color fastness properties enhancement of natural dyed cotton through metallic mordants. Fash Text. 4 (2017). https://doi.org/10.1186/s40691-017-0109-x

38.

Lera, I.L., Khasnabis, S., Wangatia, L.M., Femi, O.E.: Polypyrrole @ polyaniline-reduced graphene oxide nanocomposite support material and cobalt for the enhanced electrocatalytic activity of nickel phosphide microsphere towards alkaline urea oxidation polypyrrole @ polyaniline-reduced graphene oxide nanocomp. (2021)

39.

Arsalan, M., Siddique, I., Awais, A., Baoji, M., Khan, I.: Highly Ef fi cient PANI-WH Novel Composite for Remediation of Ni (II), Pb (II), and Cu (II) From Wastewater. 10, 1–12 (2022). https://doi.org/10.3389/fenvs.2022.895463

40.

Alawa, B., Srivastava, A., Srivastava, J.K., Palsaniya, J.: Adsorption of heavy metals from industrial downstream using polypyrrole as a polycomposite material. Nov Int. J. Eng. Technol. 3, 35–46 (2014). https://doi.org/https://d1wqtxts1xzle7.cloudfront.net/

41.

Ugwu, E.I., Tursunov, O., Kodirov, D., Shaker, L.M., Al-Amiery, A.A., Yangibaeva, I., Shavkarov, F.: Adsorption mechanisms for heavy metal removal using low cost adsorbents: A review. IOP Conf. Ser. Earth Environ. Sci. 614, 0–12 (2020). https://doi.org/10.1088/1755-1315/614/1/012166CrossRef

42.

Ajenifuja, E., Ajao, J.A., Ajayi, E.O.B.: Adsorption isotherm studies of Cu (II) and Co (II) in high concentration aqueous solutions on photocatalytically modified diatomaceous ceramic adsorbents. Appl. Water Sci. 7, 3793–3801 (2017). https://doi.org/10.1007/s13201-017-0527-3CrossRef

43.

Wang, X., Guo, Y., Yang, L., Han, M., Zhao, J., Cheng, X.: Journal of Environmental & Nanomaterials as Sorbents to Remove Heavy Metal Ions in Wastewater Treatment. 2, (2012). https://doi.org/10.4172/2161-0525.1000154

44.

Ajenifuja, E., Ajao, J.A., Ajayi, E.O.B.: Equilibrium adsorption isotherm studies of Cu (II) and Co (II) in high concentration aqueous solutions on Ag-TiO2-modified kaolinite ceramic adsorbents. Appl. Water Sci. 7, 2279–2286 (2017). https://doi.org/10.1007/s13201-016-0403-6CrossRef

45.

Kasirajan, R., Bekele, A., Girma, E.: Adsorption of lead (Pb-II) using CaO-NPs synthesized by solgel process from hen eggshell: Response surface methodology for modeling, optimization and kinetic studies. South. Afr. J. Chem. Eng. 40, 209–229 (2022). https://doi.org/10.1016/j.sajce.2022.03.008CrossRef

46.

Tola, A.T., Geleta, G.S.: Assessment of essential and potentially toxic metals in raw cow milk from Mukaturi town, Oromia Regional State. Ethiopia Sci. Total Environ. 926, 171983–171987 (2024). https://doi.org/10.1016/j.scitotenv.2024.171987CrossRef

Titel: Polyaniline/reduced graphene oxide doping induced abundant active sites in enset fiber as an efficient adsorbent material for wastewater treatment
verfasst von: Israel Leka Lera
Genne Hayre
Ayansa Fekadu
Publikationsdatum: 09.05.2024
Verlag: Springer US
Erschienen in: Adsorption
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-024-00482-7

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht