nach oben

Journal of Polymer Research

Erschienen in:

01.09.2022 | Original Paper

Preparation and characterization of biobased hybrid nanocomposite of Polyvinyl chloride/thermoplastic starch with Mg–Al layered double hydroxide and waste rice husk ash

verfasst von: Nipu Dutta, Pradip Newar, Manaj Narzary, Tarun Kumar Maji

Erschienen in: Journal of Polymer Research | Ausgabe 9/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this study, a bio-based hybrid nanocomposite was prepared with Polyvinyl chloride (PVC) as a synthetic matrix, thermoplastic starch as biometrics, and industrial waste rice husk ash (RHA) as nanofiller in the ratio of 2:1:1. The composites were prepared in a green method of melt mixing in presence of bio-based additives such as epoxidized soybean oil (ESO) performing a dual role as compatibilizer and plasticizer along with tannic acid—calcium oxide (TA-CaO) adduct as a heat stabilizer. Layered double hydroxide (LDH) was prepared from Mg (NO₃)₂·6H₂O and Al (NO₃)₃·9H₂O and further successfully modified with cetyltrimethyl ammonium bromide (CTAB). The addition of organically modified layered double hydroxide (OLDH) as nanomaterial enhanced the composite’s thermal, mechanical and chemical properties along with water vapour and flame resistance properties. A significant improvement of 169% in tensile and 87% in flexural strength was observed for composites having 5 phr OLDH. Homogeneous dispersion of the LDH layers was evident from the TEM micrographs which suggested a better interaction among components. Composite with 5phr reinforced OLDH showed an overall improvement in properties.

Vorheriger Artikel The effect of partial replacement of maleic anhydride by itaconic acid in sebacic acid-based unsaturated polyester on its various properties

Nächster Artikel Synthesis and characterization of low temperature curable phthalonitrile containing propargyl- novolacs through click-chemistry approach

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Rathnam V, Kichu A, Dutta N et al (2020) Influence of organically modified nanoclay and TiO2 nanopowder on the properties of Azadirachta indica wood flour-reinforced high-density polyethene, low-density polyethene, polypropylene, and polyvinyl chloride nanocomposite. J Thermoplast Compos Mater. https://doi.org/10.1177/0892705720935968CrossRef

Mandal M, Gogoi G, Dutta N, Maji TK (2021) Development of biobased wood polymer nanocomposites: industrial applications, market, and future trends. Handb Polym Nanocomposites Ind Appl 587–615. https://doi.org/10.1016/B978-0-12-821497-8.00022-8CrossRef

Ray D, Sain S (2017) Thermosetting bioresins as matrix for biocomposites. In Biocomposites for High-Performance Applications: Current Barriers and Future Needs Towards Industrial Development. Elsevier Inc., pp 57–80

Chindaprasirt P, Kanchanda P, Sathonsaowaphak A, Cao HT (2007) Sulfate resistance of blended cements containing fly ash and rice husk ash. Constr Build Mater 21:1356–1361. https://doi.org/10.1016/J.CONBUILDMAT.2005.10.005CrossRef

Chindaprasirt P, Homwuttiwong S, Jaturapitakkul C (2007) Strength and water permeability of concrete containing palm oil fuel ash and rice husk–bark ash. Constr Build Mater 21:1492–1499. https://doi.org/10.1016/J.CONBUILDMAT.2006.06.015CrossRef

He J, Jie Y, Zhang J et al (2013) Synthesis and characterization of red mud and rice husk ash-based geopolymer composites. Cem Concr Compos 37:108–118. https://doi.org/10.1016/J.CEMCONCOMP.2012.11.010CrossRef

Kord B (2011) Nanofiller reinforcement effects on the thermal, dynamic mechanical, and morphological behavior of HDPE/rice husk flour composites. BioResources 6:1351–1358. https://doi.org/10.15376/biores.6.2.1351-1358CrossRef

Vlaev L, Turmanova S (2008) Dimitrova A (2008) Kinetics and thermodynamics of water adsorption onto rice husks ash filled polypropene composites during soaking. J Polym Res 162(16):151–164. https://doi.org/10.1007/S10965-008-9213-3CrossRef

Stefani PM, Cyras V, Tejeira Barchi A, Vazquez A (2006) Mechanical properties and thermal stability of rice husk ash filled epoxy foams. J Appl Polym Sci 99:2957–2965. https://doi.org/10.1002/app.23001CrossRef

10.

Zhang Z, Yang F, Liu JC, Wang S (2020) Eco-friendly high strength, high ductility engineered cementitious composites (ECC) with substitution of fly ash by rice husk ash. Cem Concr Res 137:106200. https://doi.org/10.1016/j.cemconres.2020.106200CrossRef

11.

Zhou S, Qian Y, Chen X (2018) Li L (2018) In situ synthesis of layered double hydroxides-silicon dioxide hybrids and its flame retardancy in EVA composites. J Therm Anal Calorim 1342(134):1071–1082. https://doi.org/10.1007/S10973-018-7331-7CrossRef

12.

Kainuma K (1984) Starch oligosaccharides: linear, branched, and cyclic. Starch chem Technol 125–152. https://doi.org/10.1016/b978-0-12-746270-7.50011-2CrossRef

13.

González K, Retegi A, González A et al (2015) Starch and cellulose nanocrystals together into thermoplastic starch bionanocomposites. Carbohydr Polym 117:83–90. https://doi.org/10.1016/J.CARBPOL.2014.09.055CrossRefPubMed

14.

Sundum T, Szécsényi KM, Kaewtatip K (2018) Preparation and characterization of thermoplastic starch composites with fly ash modified by planetary ball milling. Carbohydr Polym 191:198–204. https://doi.org/10.1016/J.CARBPOL.2018.03.009CrossRefPubMed

15.

Balakrishnan P, Gopi S, MS S, Thomas S (2018) UV resistant transparent bionanocomposite films based on potato starch/cellulose for sustainable packaging. Starch - Stärke 70:1700139. https://doi.org/10.1002/STAR.201700139CrossRef

16.

Sadat-Shojai M, Bakhshandeh GR (2011) Recycling of PVC wastes. Polym Degrad Stab 96:404–415. https://doi.org/10.1016/J.POLYMDEGRADSTAB.2010.12.001CrossRef

17.

Bacaloglu R, Fisch M (1994) Degradation and stabilization of poly(vinyl chloride). I. Kinetics of the thermal degradation of poly(vinyl chloride). Polym Degrad Stab 45:301–313. https://doi.org/10.1016/0141-3910(94)90200-3CrossRef

18.

Shnawa HA, Khalaf MN, Shnawa HA et al (2015) Efficient thermal stabilization of polyvinyl chloride with tannin-ca complex as bio-based thermal stabilizer. Mater Sci Appl 6:360–372. https://doi.org/10.4236/msa.2015.65042CrossRef

19.

Dutta N, Maji TK (2020) Synergic effect of montmorillonite and microcrystalline cellulose on the physicochemical properties of rice husk/PVC composite. SN Appl Sci 2:1–10. https://doi.org/10.1007/s42452-020-2255-9CrossRef

20.

Wu Y, Tang M, Wang N et al (2018) Preparation and investigation on morphology, thermal stability and crystallization behavior of HDPE/EVA/Organo-modified layered double hydroxide nanocomposites. Polym Compos 39:E1849–E1857. https://doi.org/10.1002/pc.24834CrossRef

21.

Zhang M, Ding P, Qu B (2009) Flammable, thermal, and mechanical properties of intumescent flame retardant PP/LDH nanocomposites with different divalent cations. Polym Compos 30:1000–1006. https://doi.org/10.1002/PC.20648CrossRef

22.

Zhang G, Ding P, Zhang M, Qu B (2007) Synergistic effects of layered double hydroxide with hyperfine magnesium hydroxide in halogen-free flame retardant EVA/HFMH/LDH nanocomposites. Polym Degrad Stab 92:1715–1720. https://doi.org/10.1016/J.POLYMDEGRADSTAB.2007.06.004CrossRef

23.

Prasad K, Nikzad M, Sbarski I (2018) Permeability control in polymeric systems: a review. J Polym Res 25:1–20. https://doi.org/10.1007/S10965-018-1636-X/FIGURES/13CrossRef

24.

Imtiaz S, Siddiq M, Kausar A et al (2017) A review featuring fabrication, properties and applications of carbon nanotubes (CNTs) reinforced polymer and epoxy nanocomposites. Chinese J Polym Sci 364(36):445–461. https://doi.org/10.1007/S10118-018-2045-7CrossRef

25.

Chen YF, Tan YJ, Li J et al (2018) Graphene oxide-assisted dispersion of multi-walled carbon nanotubes in biodegradable Poly(ε-caprolactone) for mechanical and electrically conductive enhancement. Polym Test 65:387–397. https://doi.org/10.1016/J.POLYMERTESTING.2017.12.019CrossRef

26.

Pu S, Hao YB, Dai XX et al (2017) Morphological, rheological, crystalline and mechanical properties of ethylene-vinyl acetate copolymer/linear low-density polyethylene/amphiphilic graphene oxide nanocomposites. Polym Test 63:289–297. https://doi.org/10.1016/J.POLYMERTESTING.2017.08.028CrossRef

27.

Mishra G, Dash B, Pandey S (2018) Layered double hydroxides: A brief review from fundamentals to application as evolving biomaterials. Appl Clay Sci 153:172–186. https://doi.org/10.1016/J.CLAY.2017.12.021CrossRef

28.

Wang Q, O’Hare D (2012) Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets. Chem Rev 112:4124–4155. https://doi.org/10.1021/CR200434VCrossRefPubMed

29.

Gomez NAG, Wypych F (2019) Nanocomposites of polyethylene and ternary (Mg + Zn/Al) layered double hydroxide modified with an organic UV absorber. J Polym Res 26:1–10. https://doi.org/10.1007/S10965-019-1868-4/TABLES/3CrossRef

30.

Wang Q, Gao Y, Zhang Z et al (2013) Synthesis and characterization of high surface area flower-like Ca-containing layered double hydroxides Mg3-xCaxAl1-NO3. Sci Adv Mater 5:411–420. https://doi.org/10.1166/SAM.2013.1527CrossRef

31.

Manzi-Nshuti C, Songtipya P, Manias E et al (2009) Polymer nanocomposites using zinc aluminum and magnesium aluminum oleate layered double hydroxides: Effects of LDH divalent metals on dispersion, thermal, mechanical and fire performance in various polymers. Polymer (Guildf) 50:3564–3574. https://doi.org/10.1016/J.POLYMER.2009.06.014CrossRef

32.

Yang J-H, Zhang W, Ryu H et al (2015) Influence of anionic surface modifiers on the thermal stability and mechanical properties of layered double hydroxide/polypropylene nanocomposites. J Mater Chem A 3:22730–22738. https://doi.org/10.1039/C5TA06271CCrossRef

33.

Guo B, Liu Y, Zhang Q et al (2017) Efficient flame-retardant and smoke-suppression properties of Mg–Al-Layered double-hydroxide nanostructures on wood substrate. ACS Appl Mater Interfaces 9:23039–23047. https://doi.org/10.1021/ACSAMI.7B06803CrossRefPubMed

34.

Chiu CW, Huang TK, Wang YC et al (2014) Intercalation strategies in clay/polymer hybrids. Prog Polym Sci 39:443–485. https://doi.org/10.1016/J.PROGPOLYMSCI.2013.07.002CrossRef

35.

Liu J, Chen G, Yang J (2008) Preparation and characterization of poly(vinyl chloride)/layered double hydroxide nanocomposites with enhanced thermal stability. Polymer (Guildf) 49:3923–3927. https://doi.org/10.1016/j.polymer.2008.07.014CrossRef

36.

Guo X, Tang M, Wang N et al (2019) The synthesis of organically modified layered double hydroxide and its effect on the structure and physical properties of low-density polyethylene/ethylene–vinyl acetate blends. 27:287–298. https://doi.org/10.1177/0967391119846218

37.

Dutta N, Maji TK (2019) Valorization of waste rice husk by preparing nanocomposite with polyvinyl chloride and montmorillonite clay. J Thermoplast Compos Mater. https://doi.org/10.1177/0892705719854495CrossRef

38.

Gogoi K, Phukan MM, Dutta N et al (2014) Valorization and miscellaneous prospects of waste musa balbisiana colla pseudostem. J Waste Manag. https://doi.org/10.1155/2014/412156CrossRef

39.

Busacca AC, Stivala S, Curcio L, Livreri P (2012) Random quasi-phase matching in congruent lithium tantalate waveguides by proton exchange. Electron Lett 48:783. https://doi.org/10.1016/j.compositesa.2011.02.009CrossRef

40.

Sain MM, Kokta BV, Imbert C (1994) Structure-property relationships of wood fiber-filled polypropylene composite. Polym Plast Technol Eng 33:89–104. https://doi.org/10.1080/03602559408010733CrossRef

41.

Pracella M, Chionna D, Ishak R, Galeski A (2004) Recycling of PET and polyolefin based packaging materials by reactive blending. Polym - Plast Technol Eng 43:1711–1722. https://doi.org/10.1081/PPT-200040075CrossRef

42.

Garcia-Campo MJ, Quiles-Carrillo L, Masia J et al (2017) Environmentally friendly compatibilizers from soybean oil for ternary blends of poly(lactic acid)-PLA, poly(ε-caprolactone)-PCL and poly(3-hydroxybutyrate)-PHB. Mater 10:1339. https://doi.org/10.3390/MA10111339CrossRef

43.

Dutta N, Hazarika S, Maji TK (2021) Study on the role of tannic acid–calcium oxide adduct as a green heat stabilizer as well as reinforcing filler in the bio-based hybrid polyvinyl chloride–thermoplastic starch polymer composite. Polym Eng Sci 61:2339–2348. https://doi.org/10.1002/PEN.25761CrossRef

44.

Singh M, Somvanshi D, Singh RK et al (2020) Functionalized polyvinyl chloride/layered double hydroxide nanocomposites and its thermal and mechanical properties. J Appl Polym Sci. https://doi.org/10.1002/APP.48894CrossRef

45.

Deka BK, Maji TK (2012) Effect of silica nanopowder on the properties of wood flour/polymer composite. Polym Eng Sci 52:1516–1523. https://doi.org/10.1002/pen.23097CrossRef

46.

Dinari M, Mallakpour S (2015) Exfoliation and dispersion of nano-sized modified-LDH particles in poly(amide-imide)s containing N-trimellitylimido-l-methionine and 3,5-diamino-N-(pyridin-3-yl)benzamide linkages. Polym Bull 72:977–991. https://doi.org/10.1007/s00289-015-1318-3CrossRef

47.

Li H, Tripp CP (2002) Spectroscopic identification and dynamics of adsorbed cetyltrimethylammonium bromide structures on TiO2 surfaces. Langmuir 18:9441–9446. https://doi.org/10.1021/la026071oCrossRef

48.

Osman AF, Ashafee AMTL, Adnan SA, Alakrach A (2020) Influence of hybrid cellulose/bentonite fillers on structure, ambient, and low temperature tensile properties of thermoplastic starch composites. Polym Eng Sci 60:810–822. https://doi.org/10.1002/PEN.25340CrossRef

49.

Mor S, Chhoden K, Ravindra K (2016) Application of agro-waste rice husk ash for the removal of phosphate from the wastewater. J Clean Prod. Elsevier

50.

Dinari M, Roghani N (2021) Effect of triazine based silane coupling agent modified LDH on the thermal and mechanical properties of PVC based nanocomposites. J Polym Res 1:3. https://doi.org/10.1007/s10965-021-02686-9

51.

Geng Z, Zhen W, Song Z, Wang X (2018) Structure and performance of poly (lactic acid)/amide ethylenediamine tetraacetic acid disodium salt intercalation layered double hydroxides nanocomposites. J Polym Res 25:1–16. https://doi.org/10.1007/S10965-018-1482-X/FIGURES/14CrossRef

52.

Dutta N, Bhadra B, Gogoi G, Kumar Maji T (2021) Development of polyvinyl chloride/waste rice husk ash/modified montmorillonite nanocomposite using epoxidized soybean oil as green additive substituting synthetic plasticizer and compatibiliser. Clean Mater 2:100033. https://doi.org/10.1016/J.CLEMA.2021.100033CrossRef

53.

Fu M, Li D, Liu H et al (2016) Synergistic effects of zinc-mannitol alkoxide with calcium/zinc stearates and with β-diketone on thermal stability of rigid poly(vinyl chloride). J Polym Res 23:1–13. https://doi.org/10.1007/S10965-015-0901-5/SCHEMES/3CrossRef

54.

Pang MM, Pun MY, Ishak ZAM (2014) Thermal, mechanical, and morphological characterization of biobased thermoplastic starch from agricultural waste/polypropylene blends. Polym Eng Sci 54:1357–1365. https://doi.org/10.1002/pen.23684CrossRef

55.

Dutta N, Maji TK (2022) Development of waste rice husk/PVC/GO nanocomposite using TA–CaO adduct and ESO as green additives. J Thermoplast Compos Mater

56.

Bahari SA, Grigsby WJ, Krause A (2017) Flexural properties of PVC/Bamboo composites under static and dynamic-thermal conditions: effects of composition and water absorption. Int J Polym Sci. https://doi.org/10.1155/2017/2717848CrossRef

57.

Guo X, Tang M, Wang N et al (2019) The synthesis of organically modified layered double hydroxide and its effect on the structure and physical properties of low-density polyethylene/ethylene-vinyl acetate blends. Polym Polym Compos 27:287–298. https://doi.org/10.1177/0967391119846218CrossRef

58.

Pradhan B, Srivastava SK, Bhowmick AK, Saxena A (2012) Effect of bilayered stearate ion-modified Mg-Al layered double hydroxide on the thermal and mechanical properties of silicone rubber nanocomposites. Polym Int 61:458–465. https://doi.org/10.1002/PI.3218CrossRef

59.

Kameshima Y, Yoshizaki H, Nakajima A, Okada K (2006) Preparation of sodium oleate/layered double hydroxide composites with acid-resistant properties. J Colloid Interface Sci 298:624–628. https://doi.org/10.1016/J.JCIS.2006.01.033CrossRefPubMed

60.

Yang Z, Shi K, Jin Z et al (2022) Biodegradable layered double hydroxide/polymer films for efficient oxygen and water vapor barriers. Ind Eng Chem Res 61:1367–1374CrossRef

61.

Dinari M, Roghani N (2021) Effect of triazine based silane coupling agent modified LDH on the thermal and mechanical properties of PVC based nanocomposites. J Polym Res 28:1–8. https://doi.org/10.1007/S10965-021-02686-9/FIGURES/10CrossRef

Titel: Preparation and characterization of biobased hybrid nanocomposite of Polyvinyl chloride/thermoplastic starch with Mg–Al layered double hydroxide and waste rice husk ash
verfasst von: Nipu Dutta
Pradip Newar
Manaj Narzary
Tarun Kumar Maji
Publikationsdatum: 01.09.2022
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 9/2022
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-022-03226-9

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 9/2022

Interpenetrating networks of bacterial cellulose and poly (ethylene glycol) diacrylate as potential cephalexin carriers in wound therapy

Synthesis of diethylene glycol-based aliphatic polyester polyol and effect of glycerin crosslinker on its properties

Electrothermally actuated artificial muscles from the silver-polyethylene-terephthalate core–shell structure

Effects of plasticizers on the properties of breathable cellulose diacetate films

Correction to: Electrospun cellulose Nano fibril reinforced PLA/PBS composite scaffold for vascular tissue engineering

A study on the synthesis of various polyesters from glycerol

Premium Partner

Marktübersichten