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Journal of Polymer Research

Erschienen in:

01.09.2022 | Original Paper

The effect of partial replacement of maleic anhydride by itaconic acid in sebacic acid-based unsaturated polyester on its various properties

verfasst von: P. B. Bamane, K. K. Wadgaonkar, K. K. Srivastava, R. N. Jagtap

Erschienen in: Journal of Polymer Research | Ausgabe 9/2022

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Abstract

Unsaturated Polyester Resin (UPR) is widely synthesized using non-renewable resources. However, the use of bio-based material is a need in today’s world to ensure sustainable development. The presented investigation defines the use of bio-based itaconic acid (IA) as a replacement of conventional maleic anhydride (MAn) in UPR. The reactions of IA and MAn at varying ratios in the presence of sebacic acid (SA) and neopentyl glycol (NPG) were carried out. The objective was to investigate the effects of such replacement to bring more insight into structure–property relations. The synthesized resins were characterized by Fourier Transforms Infrared Spectroscopy (FTIR), Rheology, Gel Permeation Chromatography (GPC),Thermo-mechanical and other physical properties including viscosity and density. The addition of IA as a complete replacement to MAn increased the peak exotherm to 50⁰C as opposed to 38⁰C for polyester based on MAn alone. This led to quicker gelation and curing. Molecular weight Mn and Mw were found to be reduced to around 66% and 47% respectively leading to reduced viscosity.

Vorheriger Artikel A study on the synthesis of various polyesters from glycerol

Nächster Artikel Preparation and characterization of biobased hybrid nanocomposite of Polyvinyl chloride/thermoplastic starch with Mg–Al layered double hydroxide and waste rice husk ash

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Titel: The effect of partial replacement of maleic anhydride by itaconic acid in sebacic acid-based unsaturated polyester on its various properties
verfasst von: P. B. Bamane
K. K. Wadgaonkar
K. K. Srivastava
R. N. Jagtap
Publikationsdatum: 01.09.2022
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 9/2022
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-022-03166-4

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