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23.08.2020 | Original Contribution

Preparation of metal and metal oxide doped silica hollow spheres and the evaluation of their catalytic performance

verfasst von: Aurel Diacon, Edina Rusen, Adrian Trifan, Raluca Șomoghi, Oana Tutunaru, Gabriel Crăciun, Cristina Busuioc, Georgeta Voicu

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2020

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Abstract

The aim of this study was the synthesis of silica hollow spheres-based materials doped with metal nanoparticles or metal oxides. Two different strategies based on the use of polymer colloids and cetyltrimethylammonium bromide (CTAB) as dual templates were developed. The first strategy involves the use of soap-free emulsion polymerization for the trapping of metal nanoparticles (Ag and Ni) and in the polymer structure. The second strategy exploited carboxyl groups present on the surface of the polymer particles for the adsorption of metal salts (Ni and Fe). A complete porous SiO₂ shell was generated around the polymer colloids using a Stöber method and CTAB to guide the silica shell growth. The obtained silica hollow sphere displayed either yolk-shell distribution of the doping elements or a uniform oxide deposit on the interior surface of the silica capsules. The versatility of the synthesis method and the catalytic performance of the materials were demonstrated in the case of Fe@SiO₂ for a Fischer-Tropsch process.

Vorheriger Artikel Comparison of the properties of perfluoroalkyl polyoxyethylene ether and alkyl polyoxyethylene ether

Nächster Artikel Alkanediyl-α,ω–type gemini micelles–catalyzed study between ninhydrin and [Ni(II)-Trp]+ complex

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Titel: Preparation of metal and metal oxide doped silica hollow spheres and the evaluation of their catalytic performance
verfasst von: Aurel Diacon
Edina Rusen
Adrian Trifan
Raluca Șomoghi
Oana Tutunaru
Gabriel Crăciun
Cristina Busuioc
Georgeta Voicu
Publikationsdatum: 23.08.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 10/2020
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-020-04722-4

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