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Colloid and Polymer Science

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17.08.2020 | Original Contribution

Synthesis of polyHIPEs through high internal phase emulsions of β-myrcene

verfasst von: E. Hilal Mert, Burcu Kekevi

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2020

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Abstract

PolyHIPEs are an important class of porous polymers with well-defined hierarchical porosity and tunable morphology. However, the insufficient mechanical properties arise due to high volume of voids bringing difficulties in applications. In this study, polyHIPEs with tailored morphological and mechanical properties were prepared by using a monoterpene for the first time. In this respect, copolymerization of β-myrcene with several comonomers within water-in-oil (w/o) high internal phase emulsions (HIPEs) has been extensively investigated. Accordingly, combining β-myrcene and ethylene glycol dimethacrylate (EGDMA) in polyHIPE structure was demonstrated as a successful approach for tailoring the morphology, as well as the mechanical strength. PolyHIPEs with cavities between 1.09 and 3.55 μm were obtained by changing the ratio of β-myrcene in the continuous phase of HIPEs. Moreover, resulting polyHIPEs have found to have improved mechanical strength. The highest compressive modulus achieved for the obtained monoliths was determined to be 38.8 MPa.

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Vorheriger Artikel Alkanediyl-α,ω–type gemini micelles–catalyzed study between ninhydrin and [Ni(II)-Trp]+ complex

Nächster Artikel Design and fabrication of novel core-shell nanoparticles for theranostic applications

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Titel: Synthesis of polyHIPEs through high internal phase emulsions of β-myrcene
verfasst von: E. Hilal Mert
Burcu Kekevi
Publikationsdatum: 17.08.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 10/2020
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-020-04730-4

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