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05.09.2021 | Original Research

Pretreatment of corn stover by acidic and basic choline chloride solutions for enzymatic hydrolysis

verfasst von: Benkun Qi, Zhenwu Wang, Jianquan Luo, Yinhua Wan

Erschienen in: Cellulose | Ausgabe 16/2021

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Abstract

As a cheap, biodegradable, and nontoxic chemical, choline chloride (ChCl) is widely used in animal feed. In this study, acid and alkali catalyzed ChCl pretreatments of corn stover (CS) were investigated. Compared with single aqueous ChCl pretreatment, H₂SO₄ acidified aqueous ChCl pretreatment was more effective in removing lignin (69.5%) and xylan (84.9%). NaOH alkalified aqueous ChCl pretreatment demonstrated better performance of delignification (76.8%) but weaker capability of removing xylan (46.2%) than acidified aqueous ChCl pretreatment. Following enzymatic digestibility of pretreated CS, glucose yield from acidified ChCl pretreatment was 72.1%, significantly lower than that of alkalified ChCl pretreatment (89.4%). However, the highest glucose yield of 98.6% resulted from solitary alkali pretreatment. Correlation studies between change in physico-chemical properties of pretreated solids and corresponding enzymatic digestibility indicated high delignification and bigger cellulose crystallite size were mainly responsible for high enzymatic hydrolysis efficiency. Additionally, the properties of extracted lignin from single and combined pretreatments with ChCl and alkali or acid were analyzed. Acidified ChCl pretreatment increased, whereas alkaline ChCl pretreatment decreased molecular weight and phenolic hydroxyl groups of separated lignin in comparison to individual acid and alkali pretreatment. These findings would provide useful information in understanding biomass pretreatments with aqueous ChCl.

Vorheriger Artikel Non-freezing water sorbed on microcrystalline cellulose studied by high-resolution thermogravimetric analysis

Nächster Artikel On the role of N-methylmorpholine-N-oxide (NMMO) in the generation of elemental transition metal precipitates in cellulosic materials

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Titel: Pretreatment of corn stover by acidic and basic choline chloride solutions for enzymatic hydrolysis
verfasst von: Benkun Qi
Zhenwu Wang
Jianquan Luo
Yinhua Wan
Publikationsdatum: 05.09.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 16/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04163-4

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