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Erschienen in: Journal of Materials Science: Materials in Electronics 10/2024

01.04.2024

Reduced graphene oxide correlated electrochemical energy storage behavior of La2MnFeO6/rGO composite microspheres

verfasst von: Renu Dhahiya, Neetika Chauhan, Ashok Kumar

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 10/2024

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Abstract

The study focuses on the microstructural and electrochemical properties of pristine La2MnFeO6 (LMFO) and La2MnFeO6/rGO composite. The powder X-ray diffraction (XRD) of LMFO microspheres revealed an orthorhombic structure with space group Pnma. The estimated lattice parameters are a = 5.57 Å, b = 7.80 Å, and c = 5.54 Å with α = β = γ = 90°. The LMFO/rGO composite showed an identical XRD pattern to LMFO. The scanning electron microscopy revealed the existence of microspheres with agglomerated crystallites in both LMFO and LMFO/rGO samples. Brunauer–Emmett–Teller analysis revealed that the composite LMFO/rGO (~ 23.43 mg−1) has slightly higher surface area than pristine LMFO (~ 21.26 mg−1) due to the presence of porous reduced graphene oxide (rGO). The oxidation states of constituent elements, La3+, Fe3+, Mn2+/Mn3+, and O2−, were confirmed through X-ray photoelectron spectroscopy. The specific capacitance values for pristine LMFO and composite LMFO/rGO are found to be 320.7 Fg−1 and 416.2 Fg−1, respectively at the current density of 1 Ag−1.

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Metadaten
Titel
Reduced graphene oxide correlated electrochemical energy storage behavior of La2MnFeO6/rGO composite microspheres
verfasst von
Renu Dhahiya
Neetika Chauhan
Ashok Kumar
Publikationsdatum
01.04.2024
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 10/2024
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-024-12435-5

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