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Rheologica Acta

Erschienen in:

16.06.2017 | Original Contribution

Rheological behavior of suspensions of modified and unmodified cellulose nanocrystals in dimethyl sulfoxide

verfasst von: Helia Sojoudiasli, Marie-Claude Heuzey, Pierre J. Carreau, Bernard Riedl

Erschienen in: Rheologica Acta | Ausgabe 7-8/2017

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Abstract

The rheological behavior of cellulose nanocrystal (CNC) and modified CNC (mCNC) suspensions in dimethyl sulfoxide (DMSO) was investigated. The efficiency of the surface modification of CNCs by grafting an organic acid chloride to produce hydrophobic CNCs has been verified by X-ray photoelectron spectroscopy (XPS). The thermal degradation temperature of the mCNCs was found to be 165 versus 275 °C for CNCs. The CNC suspensions in DMSO at 70 °C underwent gelation at very low concentration (1 wt%) after 1 day. The network formation was temperature sensitive and did not occur at room temperature. For gels containing 3 wt% CNCs, the complex viscosity at 70 °C increased by almost four decades after 1 day. For the mCNCs in DMSO, a weak gel was formed from the first day and temperature did not affect the gelation. Finally, the effect of adding 10 wt% of polylactide (PLA) to the solvent on the rheological properties of CNC and mCNC suspensions was investigated. The properties of suspensions containing 1.9 wt% CNCs and mCNCs increased during the first and second days, and PLA did not prevent gel formation. However, the reduced viscosity and storage modulus of the CNC and mCNC gels with PLA were lower than those of samples without PLA.

Vorheriger Artikel Small-diameter parallel plate rheometry: a simple technique for measuring rheological properties of glass-forming liquids in shear

Nächster Artikel Drag reduction behavior of hydrolyzed polyacrylamide/polysaccharide mixed polymer solutions—effect of solution salinity and polymer concentration

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Titel: Rheological behavior of suspensions of modified and unmodified cellulose nanocrystals in dimethyl sulfoxide
verfasst von: Helia Sojoudiasli
Marie-Claude Heuzey
Pierre J. Carreau
Bernard Riedl
Publikationsdatum: 16.06.2017
Verlag: Springer Berlin Heidelberg
Erschienen in: Rheologica Acta / Ausgabe 7-8/2017
Print ISSN: 0035-4511
Elektronische ISSN: 1435-1528
DOI: https://doi.org/10.1007/s00397-017-1022-3

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